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An organic-inorganic composite sewage treatment agent and its preparation method

A sewage treatment agent, inorganic composite technology, applied in the fields of adsorption water/sewage treatment, flocculation/sedimentation water/sewage treatment, etc., can solve the problem of reducing the contact probability between flocculants and wastewater, difficulty in separating treatment agent and sewage, and reducing the use of flocculants. rate and other issues, to achieve good removal effect, significant removal effect, and easy packaging.

Active Publication Date: 2021-08-31
北水慧采(北京)科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The flocculation method is to add a flocculant to the sewage to achieve the purpose of flocculation and sedimentation of the pollutants in the sewage. However, the existing flocculation and sedimentation methods often have the following problems: First, the flocculant is usually used together with the coagulant aid, and the effect of using it alone is not good. Second, flocculants and coagulants are less effective in treating high-turbidity or heavily polluted wastewater, and it is difficult to separate the treatment agent from sewage; third, flocculants are mostly powdery, and on the one hand, they are difficult to process during packaging, transportation, and use. The loss is large, which is easy to cause dust pollution. On the other hand, after adding sewage, the powder is easy to aggregate, which reduces the contact probability between the flocculant and the waste water, and reduces the utilization rate of the flocculant. At the same time, the sewage treatment process is long and occupies an area. Large area, high operating cost, easy to cause secondary pollution to water quality

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  • An organic-inorganic composite sewage treatment agent and its preparation method

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Effect test

Embodiment 1

[0043] An organic-inorganic composite sewage treatment agent is prepared from the following raw materials in parts by weight: 6 parts of gelatin, 9 parts of cysteine, 9 parts of thioglycolic acid, 20 parts of sodium lignosulfonate, and 22 parts of carboxymethyl Chitosan, 12 parts of urea, 25 parts of limestone, 14 parts of sepiolite, 28 parts of bentonite, 50 parts of fly ash, 24 parts of quicklime, 13 parts of medical stone, 13 parts of aluminum sulfate, 15 parts of ferric chloride and 12 parts polyethyleneiminoxanthic acid.

[0044] Specific steps are as follows:

[0045] (1) Preparation of gelatin complex solution:

[0046] Add the gelatin in said parts by weight into a certain amount of deionized water, heat and dissolve at 55° C. to obtain a 5% gelatin solution, add a mixed solution of cysteine ​​and thioglycolic acid dropwise to it and stir for 0.5 h, Obtain a gelatin complex solution for use, wherein the mass percent concentration of cysteine ​​and thioglycolic acid i...

Embodiment 2

[0054] An organic-inorganic composite sewage treatment agent is prepared from the following raw materials in parts by weight: 7 parts of gelatin, 16.5 parts of cysteine, 16.5 parts of thioglycolic acid, 22 parts of sodium lignosulfonate, 24 parts of carboxymethyl Chitosan, 12.5 parts of urea, 26 parts of limestone, 15 parts of sepiolite, 29 parts of bentonite, 55 parts of fly ash, 26 parts of quicklime, 14 parts of medical stone, 14 parts of aluminum sulfate, 16 parts of ferric chloride and 13 parts parts polyethyleneiminoxanthic acid.

[0055] Specific steps are as follows:

[0056] (1) Preparation of gelatin complex solution:

[0057] Add the gelatin in said parts by weight to a certain amount of deionized water, heat and dissolve at 65°C to obtain a gelatin solution with a concentration of 12.5% ​​by mass, and add the mixed solution of cysteine ​​and thioglycolic acid dropwise to it and stir React for 75 minutes to obtain a gelatin complex solution, ready to use, wherein ...

Embodiment 3

[0065] An organic-inorganic composite sewage treatment agent is prepared from the following raw materials in parts by weight: 8 parts of gelatin, 24 parts of cysteine, 24 parts of thioglycolic acid, 24 parts of sodium lignosulfonate, 26 parts of carboxymethyl Chitosan, 13 parts of urea, 27 parts of limestone, 16 parts of sepiolite, 30 parts of bentonite, 60 parts of fly ash, 28 parts of quicklime, 15 parts of medical stone, 15 parts of aluminum sulfate, 17 parts of ferric chloride and 14 parts parts polyethyleneiminoxanthic acid.

[0066] Specific steps are as follows:

[0067] (1) Preparation of gelatin complex solution:

[0068] Add the gelatin in said parts by weight into a certain amount of deionized water, heat and dissolve at 75°C to obtain a 20% gelatin solution, add a mixed solution of cysteine ​​and thioglycolic acid dropwise to it and stir for 1 hour to obtain gelatin The complex solution is ready for use, wherein the mass percent concentration of cysteine ​​and th...

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Abstract

The invention discloses an organic-inorganic composite sewage treatment agent and a preparation method thereof. The composite treatment agent is prepared from the following raw materials in parts by weight: 6-8 parts of gelatin, 9-24 parts of cysteine, 9 ‑24 parts thioglycolic acid, 20‑24 parts sodium lignosulfonate, 22‑26 parts carboxymethyl chitosan, 12‑13 parts urea, 25‑27 parts limestone, 14‑16 parts meerschaum, 28‑30 parts Bentonite, 25‑30 parts of fly ash, 24‑28 parts of quicklime, 13‑15 parts of medical stone, 13‑15 parts of aluminum sulfate, 15‑17 parts of ferric chloride and 12‑14 parts of polyethyleneimine xanthic acid . The composite treatment agent of the present invention combines the advantages of inorganic mineral adsorbents and organic biopolymer flocculants, and the removal rates of heavy metals, COD, SS, TP, and TN in heavily polluted sewage have respectively reached more than 95%. The contents of heavy metals, COD, SS, TP, and TN in the river sewage are in line with the provisions of Category IV in Table 1 of the National Standard of the People's Republic of China, Surface Water Environmental Quality Standard GB3838‑2002.

Description

technical field [0001] The invention relates to the field of sewage treatment, in particular to an organic-inorganic composite sewage treatment agent and a preparation method thereof. Background technique [0002] With the acceleration of industrialization and the improvement of human living standards, the discharge of industrial wastewater and domestic sewage is increasing, and the problem of water pollution is becoming more and more serious, which makes people pay a heavy price. Due to the complex sources of industrial wastewater and domestic sewage, such as the different components of factory wastewater, it is necessary to research and develop a technology suitable for the treatment of various pollutants. [0003] The current sewage treatment methods can be divided into physical methods, chemical methods and biological methods according to their mechanism of action: physical methods mainly use physical effects to separate insoluble substances in sewage, and do not change ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/28C02F1/56
Inventor 刘华
Owner 北水慧采(北京)科技有限公司