Electric-enhanced zero-valent-iron anaerobic water treatment device and method

A treatment device and zero-valent iron technology, applied in anaerobic digestion treatment, water/sludge/sewage treatment, chemical instruments and methods, etc., can solve problems such as decreased reaction efficiency, increased pH value, and compaction of packed beds. Reach the effect of reducing catalytic time, reducing sludge loss and improving removal efficiency

Pending Publication Date: 2019-06-11
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above reaction of zero-valent iron will lead to an increase in pH value, and the reaction efficiency will drop significantly after the corrosion layer is formed on the surface
When zero-valent iron is packed in a fixed-bed reactor as a filler, the packed bed may be hardened due to surface corrosion, and it is difficult to perform the purification function stably for a long time

Method used

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  • Electric-enhanced zero-valent-iron anaerobic water treatment device and method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] The above-mentioned electric anaerobic zero-valent iron anaerobic water treatment device is started and acclimatized with synthetic glucose wastewater. Under the condition of no voltage, the COD removal rate is basically lower than 60% when the influent COD concentration is 1000 to 2000mg / L in the first 20 days after the device is started. On the 21st day, the external voltage was applied to the treatment device, and the sewage treatment efficiency was rapidly increased to over 90%. When it runs for 36 days, the influent COD is 7000mg / L, and the COD removal rate reaches over 95%, which realizes the rapid start-up of the treatment device.

Embodiment 2

[0041]The treatment device treats synthetic printing and dyeing wastewater under the condition of applied voltage, and maintains stable operation during the period. When the influent COD concentration is about 5000mg / L, when the dye concentration reaches 800mg / L, the COD removal rate remains above 85%, and the average color The degree of removal rate remains above 80%.

Embodiment 3

[0043] With the operation of the treatment device for 40 days, the particle size of the sludge in the treatment device increased significantly, indicating that the electro-enhanced anaerobic reactor had a significant effect on the granulation of the sludge. At this time, the sedimentation rate of the sludge reached 50m / h, and the iron The content is around 4.5%.

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Abstract

The invention discloses an electric-enhanced zero-valent-iron anaerobic water treatment device. The device comprises an up-flow anaerobic bioreactor, wherein an electric enhanced zero-valent-iron system is arranged in the middle of a barrel of the up-flow anaerobic bioreactor; the electric enhanced zero-valent-iron system comprises 2N electrodes formed by anodes and cathodes which are periodicallyarranged at intervals in the axial direction, wherein N is a positive integer; the anodes and the cathodes are connected with a direct-current power source outside the barrel through wires; and the space between every two adjacent electrodes are filled with a zero-valent-iron layer. According to the invention, on the basis of a zero-valent-iron coupling anaerobic reactor, a plurality of series orparallel electrodes are added, so that the over potential of a reaction is reduced, the electron obtaining rate of cathode microorganisms is accelerated, and the reduction reaction is promoted to berapidly carried out. An electric field is added, so that activity of the microorganisms can be stimulated, electron transfer between the electrodes and the microorganisms on the surface of the electrodes is facilitated, and the reaction rate of anaerobic zero-valent iron is enhanced to a greater extent.

Description

technical field [0001] The invention belongs to the technical field of sewage treatment and relates to an electrically enhanced zero-valent iron anaerobic water treatment device and method. Background technique [0002] Anaerobic digestion is one of the most effective and practical methods for treating medium and high concentration organic wastewater. It combines sewage treatment with energy, and has been widely concerned and applied at home and abroad. The anaerobic digestion process mainly includes three stages: hydrolytic acidification, acetic acidification and methanation. Methanogens have slow metabolism and are sensitive to environmental conditions, which can easily cause an imbalance between acid production and methanation. The increase of influent organic load or the large fluctuation of water quality will easily lead to the enhancement of organic acid accumulation, the decrease of pH, the inhibition of methanation, and even the failure of anaerobic process. Theref...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F3/28C02F101/30
Inventor 朱云庆张玉杰
Owner SHAANXI UNIV OF SCI & TECH
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