Fully-degradable material for shopping bags, mulching films and greenhouse films and preparation method of fully-degradable material
A fully degradable, shopping bag technology, applied in the field of film production, can solve the problems of toughness and transparency hindering the application of degradable greenhouse films, difficulties in popularization and application, and poor toughness of materials, so as to reduce material costs, reduce white pollution, and strong tensile strength Effect
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Embodiment 1
[0033] Example 1 (very small, corn starch, PVA0588), 7.7KgPVA0588, 7Kg water, 1.15Kg ethylene glycol, 1.15Kg magnesium nitrate were added to the high-speed mixer, the mass ratio of PVA0588: water: ethylene glycol: magnesium nitrate was 1 : 0.9: 0.15: 0.15, stirred at 80°C for 10 minutes, at a stirring rate of 480 rpm, and then granulated by a twin-screw machine at 180°C to obtain modified polyvinyl alcohol;
[0034] Add 40Kg cornstarch, 36Kg water, 16Kg polyethylene glycol PEG200, 4Kg formamide into the high-speed mixer, the mass ratio of cornstarch: water: polyethylene glycol PEG200: formamide is: 1:0.9:0.4:0.1; The ratio of diol PEG200 to formamide is 8:2, stirred at 80°C for 10min, and the stirring speed is 480 rpm to obtain a modified cornstarch solution;
[0035] Mix the modified polyvinyl alcohol and the modified cornstarch solution evenly, wherein the weight of the modified polyvinyl alcohol is 10Kg, the weight of the modified cornstarch solute is 60Kg, add 1Kg of cross...
Embodiment 2
[0036] Embodiment 2 (intermediate value, hydroxyethyl cellulose HEC, PVA1797, calcium chloride): 20KgPVA1797, 18Kg water, 4Kg polyethylene glycol PEG200, 4Kg calcium chloride are added in the high-speed mixer, PVA1797: water: polyethylene The mass ratio of diol PEG200: calcium chloride is 1:0.9:0.2:0.2, stirred at 80°C for 10 minutes, the stirring rate is 480 rpm, and then granulated by a twin-screw machine at 180°C to obtain modified polyvinyl alcohol;
[0037] Add 50Kg hydroxyethyl cellulose HEC, 45Kg water, 24Kg propylene glycol, and 6Kg formamide into a high-speed mixer. The mass ratio of hydroxyethyl cellulose HEC: water: propylene glycol: formamide is 1:0.9:0.48:0.12, propylene glycol and The ratio of formamide is 8:2, stir at 80°C for 10 minutes, and the stirring speed is 480 rpm to obtain the modified vegetable gum solution;
[0038] The modified polyvinyl alcohol and the modified vegetable gum solution are mixed uniformly, wherein the weight portion of the modified po...
Embodiment 3
[0039] Example 3 (great pullulan polysaccharide PVA2499 magnesium chloride), 26.7KgPVA2499, 24Kg water, 6.67Kg polyethylene glycol PEG200, 6.67Kg magnesium nitrate were added to the high-speed mixer, PVA2499: water: polyethylene glycol PEG200: magnesium chloride The mass ratio is 1:0.9:0.25:0.25, stirred at 80°C for 10 minutes, the stirring rate is 480 rpm, and then granulated by a twin-screw machine at 180°C to obtain modified polyvinyl alcohol;
[0040] Add 56Kg of pullulan, 50Kg of water, 28Kg of polyethylene glycol PEG200, and 6.2Kg of formamide into a high-speed mixer. The mass ratio of pullulan: water: polyethylene glycol PEG200: formamide is: 1:0.9:0.5 : 0.11, the ratio of polyethylene glycol PEG200 to formamide is 9:2, stirred at 80°C for 10min, and the stirring speed is 480 rpm to obtain a modified pullulan solution;
[0041] Mix the modified polyvinyl alcohol and the modified pullulan solution evenly, wherein the weight of the modified polyvinyl alcohol is 40Kg, the ...
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