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Method for jointly treating polluted sludge by electroosmosis and solidification

A combined treatment and electroosmotic treatment technology, applied in the direction of electrochemical sludge treatment, fixed/solidified sludge treatment, chemical instruments and methods, etc., can solve the problems of large amount of curing agent, long construction time, secondary pollution, etc. , to achieve the effect of low construction cost, good curing effect, and short time-consuming electroosmosis

Active Publication Date: 2019-08-16
NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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  • Summary
  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

Among the above-mentioned consolidation techniques, the heap loading and vacuum preloading methods usually require loads to be applied on the site. However, due to the relatively low initial strength of marine silt, conventional equipment cannot be erected on the shore, which limits the reinforcement to a certain extent. The effect of permeable marine silt loading is general; the vacuum preloading method is to lay a horizontal drainage sand cushion in the reinforcement area and insert a vertical drainage body, then seal the sand cushion with a sealing film, and vacuumize the soil Negative pressure is generated to draw out the pore water in the soil to consolidate the soil. Such vacuuming usually requires the vacuum pump to work for 2 to 5 months to maintain the vacuum at 80 to 90kPa, so the construction takes a long time
[0004] Curing agent is a commonly used chemical consolidation method, but the higher the moisture content of polluted sludge, the more curing agent is needed. For marine sludge, if the curing agent is used directly for treatment, the general dosage will reach 10-15wt%. The volume of marine silt is huge, so the amount of curing agent required is huge. For example, 1 ton of marine silt is mixed with 100-150kg of traditional curing agent. Such a large amount will undoubtedly increase the cost
The existing electroosmotic method, also known as electrokinetic repair technology or electrochemical method, generally adds some external dopants, such as acids or complexes, which can reduce the adsorption between Zn, Pd, Cu and other heavy metal ions and soil particles. Then the heavy metal ions detached from the soil particles can complete the migration with electromigration. The characteristic of using electrokinetic restoration technology is that the early effect is very good, but as the concentration of heavy metal ions decreases in the later stage, the required energy consumption is higher. The effect becomes worse, so it takes a long time, the cost is high, and there is also the problem of secondary pollution caused by external admixtures
Moreover, the devices required by the current electric repair technology need to have the function of adding additional solution, and the equipment must be sealed so that the solution will not leak out; but the cost of outdoor construction devices is too high, so most of them can only be carried out indoors and cannot be used on a large scale. scale application
[0005] CN102704463B discloses a vacuum preloading-electroosmosis combined reinforcement method for silt foundations. First, vacuum preloading is carried out to extract pore water in the soft soil, so that the soft soil can be consolidated and compressed, and its strength improved. After a period of vacuuming, the reinforcement effect When it can no longer be improved, start electroosmosis at the same time to further discharge part of the free water and weakly bound water that cannot be discharged by simple vacuum preloading; but the above method only has a good reinforcement effect on ultra-soft silt foundations, and it is not suitable for rivers containing heavy metal ions. Sludge is not universal, especially for the stable solidification of heavy metal ions does not have a significant effect

Method used

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  • Method for jointly treating polluted sludge by electroosmosis and solidification
  • Method for jointly treating polluted sludge by electroosmosis and solidification
  • Method for jointly treating polluted sludge by electroosmosis and solidification

Examples

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Embodiment 1

[0044] A method for electroosmotic solidification combined treatment of polluted sludge, it comprises the following steps:

[0045] 1) pull out the polluted sludge, filter and remove the water on the surface of the polluted sludge, and obtain the pretreated sludge;

[0046] 2) Fill the pretreated sludge into the electroosmotic device for electroosmotic treatment until the required water content is reached; the electroosmotic device includes a treatment pool 1, an electrode, a DC power supply 5 and wires, and the electrode includes a The cathode 2 on the side wall and the anode 3 located on the right side wall of the treatment tank 1, the cathode 2 and the anode 3 are respectively connected to the DC power supply 5 through wires; the electroosmosis treatment refers to turning on the DC power supply 5 to make the Water and heavy metal ions are transported from the anode 3 to the cathode 2; there is no need to use a water pump if there is no special need, and the drainage process...

Embodiment 2

[0053] A method for electroosmotic solidification combined treatment of polluted sludge, it comprises the following steps:

[0054] 1) pull out the polluted sludge, filter and remove the water on the surface of the polluted sludge, and obtain the pretreated sludge;

[0055] 2) Fill the pretreated sludge into the electroosmotic device for electroosmotic treatment until the required water content is reached; the electroosmotic device includes a treatment pool 1, an electrode, a DC power supply 5 and wires, and the electrode includes a The cathode 2 on the side wall and the anode 3 located on the right side wall of the treatment tank 1, the cathode 2 and the anode 3 are respectively connected to the DC power supply 5 through wires; the electroosmosis treatment refers to turning on the DC power supply 5 to make the Water and heavy metal ions move from the anode 3 to the cathode 2;

[0056] 3) Take out the electrodes of the electroosmosis device, add a curing agent into the treatm...

Embodiment 3

[0062] A method for electroosmotic solidification combined treatment of polluted sludge, the difference from Example 1 is that the curing agent is made of the following components in parts by weight: 30 parts of sulphoaluminate cement, 35 parts of sodium hydroxide , 20 parts of sodium silicate, 5 parts of hydrogen peroxide, and 1 part of triethanolamine. The dosage of the curing agent is 8% of the mass of the sludge after electroosmosis treatment.

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Abstract

The invention discloses a method for electro-osmosis solidification combined treatment of polluted sludge, which comprises the following steps: 1) fishing out the polluted sludge and filtering to remove water on the surface of the polluted sludge to obtain pretreated sludge; 2) filling the pretreated sludge into an electroosmosis device for electroosmosis treatment until the required water contentis reached; 3) taking out the electrode of the electroosmosis device, adding a curing agent into the treatment tank, and stirring to obtain solidified sludge. The above method is convenient to construct, and only requires a small amount of energy consumption and curing agent to achieve a good drainage consolidation effect.

Description

technical field [0001] The invention relates to the technical field of polluted sludge treatment, in particular to a method for electroosmotic solidification combined treatment of polluted sludge. Background technique [0002] Due to the unique geographical advantages of coastal countries, coastal cities, and areas with rich water resources such as rivers and rivers, the rapid economic development and the huge flow of people make commercial land and housing land very tight, but this brings land resources. In short supply. In order to alleviate this situation, there are sea reclamation projects all over the world, that is, sand and gravel are injected into the sea to make land or build artificial islands to increase land supply in the silted tidal flat section; however, the water content of marine silt is as high as 70wt%, and the rest is mostly sand, so the mud-water mixture blown up to the bank is in a fluid plastic state, and the formed blown fill foundation has extremely...

Claims

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Application Information

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IPC IPC(8): C02F11/15C02F11/145C02F11/12C02F11/00
CPCC02F11/006C02F11/008C02F11/12C02F11/14
Inventor 潘崇根谢新宇朱侠达朱大勇羊嘉文朱籽臻林伟
Owner NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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