Mesoporous Ru-MIL-125-NH2 catalyst prepared from supercutical fluid
A ru-mil-125-nh2, supercritical fluid technology, applied in the field of materials, can solve the problem of small pore size and achieve the effect of improving reactivity and visible light absorption capacity
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Embodiment 1
[0032] The high mesoporous Ru-MIL-125-NH of the present embodiment 2 The synthesis method is as follows:
[0033] Synthesis of highly mesoporous Ru-MIL-125-NH 2 The metal salt precursor used is RuCl 3 ·xH 2 O, MOFs material is MIL-125-NH 2 .
[0034] MIL-125-NH 2 with RuCl 3 ·xH 2 O was added to the reaction kettle according to the mass ratio of 100:5, stirred at room temperature until uniformly mixed, then filled with carbon dioxide at a certain pressure (5.58MPa), reacted for 5 hours at a reaction temperature of 200°C, and cooled to room temperature , remove the carbon dioxide in the reactor by pressure relief, centrifuge to obtain a solid precipitate, wash the obtained precipitate with DMF and methanol, and then place it in a vacuum drying oven to remove the remaining solvent molecules, the drying temperature is 80 ° C, Ru-MIL-125-NH was obtained after drying for 12 hours 2 .
[0035] MIL-125-NH 2 And the obtained high mesoporous Ru-MIL-125-NH of this embodiment ...
Embodiment 2
[0039] Mesoporous Ru-MIL-125-NH of the present embodiment 2 The synthesis method is as follows:
[0040] Synthesis of Mesoporous Ru-MIL-125-NH 2 The metal salt precursor used is RuCl3 ·xH 2 O, MOFs material is MIL-125-NH 2 .
[0041] MIL-125-NH 2 with RuCl 3 ·xH 2 O is added to the reaction kettle according to the mass ratio of 100:5, stirred at room temperature until uniformly mixed, then filled with carbon dioxide at a certain pressure (5.58MPa), and reacted for 1 hour at a reaction temperature of 200°C, then cooled to room temperature , remove the carbon dioxide in the reactor by pressure relief, centrifuge to obtain a solid precipitate, wash the obtained precipitate with DMF and methanol, and then place it in a vacuum drying oven to remove the remaining solvent molecules, the drying temperature is 80 ° C, Ru-MIL-125-NH was obtained after drying for 12 hours 2 .
[0042] The resulting Ru-MIL-125-NH 2 Scanning, transmission electron microscopy, X-ray diffraction (X...
Embodiment 4
[0044] Mesoporous Ru-MIL-125-NH of the present embodiment 2 The synthesis method is as follows:
[0045] Synthesis of Mesoporous Ru-MIL-125-NH 2 The metal salt precursor used is RuCl 3 ·xH 2 O, MOFs material is MIL-125-NH 2 .
[0046] MIL-125-NH 2 with RuCl 3 ·xH 2 O was added to the reaction kettle according to the mass ratio of 100:5, stirred at room temperature until uniformly mixed, then filled with carbon dioxide at a certain pressure (5.58MPa), reacted for 3 hours at a reaction temperature of 200°C, and cooled to room temperature , remove the carbon dioxide in the reactor by pressure relief, centrifuge to obtain a solid precipitate, wash the obtained precipitate with DMF and methanol, and then place it in a vacuum drying oven to remove the remaining solvent molecules, the drying temperature is 80 ° C, Ru-MIL-125-NH was obtained after drying for 12 hours 2 .
[0047] The resulting Ru-MIL-125-NH 2 Scanning, transmission electron microscopy, X-ray diffraction (XR...
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