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Gadolinium-rich nickel-based alloy material for reactor spent fuel storage and preparation method thereof

A nickel-based alloy and spent fuel technology, applied in the fields of nickel-based neutron absorption materials and preparation, nickel-based alloy materials and preparation fields, can solve the limitations of the application and development of neutron absorption materials, the complex process of radiation resistance, hot ductility It can reduce problems such as reducing the cost of raw materials, and achieve the effect of excellent processability, corrosion resistance and thermal processing performance, and reduced raw material costs.

Active Publication Date: 2019-09-24
SHANGHAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the solubility of boron in stainless steel is low, and excessive boron addition will precipitate borides (Fe, Cr) 2 B, resulting in greatly reduced hot ductility, and it is very difficult to prepare boron steel with higher boron content
B 4 C / Al neutron absorbing material has complex process, B 4 The serious interface reaction between C and Al, corrosion resistance, radiation resistance, and aging during use limit the application and development of neutron absorbing materials.

Method used

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  • Gadolinium-rich nickel-based alloy material for reactor spent fuel storage and preparation method thereof
  • Gadolinium-rich nickel-based alloy material for reactor spent fuel storage and preparation method thereof
  • Gadolinium-rich nickel-based alloy material for reactor spent fuel storage and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0027] In this embodiment, a method for preparing a gadolinium-rich nickel-based alloy material for reactor spent fuel storage includes the following steps:

[0028] a. The vacuum induction smelting process is adopted, and when the raw materials are batched, the raw material ingredients used are composed according to the following mass percentage (%) for raw material batching:

[0029]

[0030]

[0031] Vacuum induction melting is carried out on all raw materials weighed after batching to obtain alloy melt;

[0032] b. Casting the alloy melt prepared in the step a, and then going through the hot forging, hot rolling and annealing heat treatment process of the alloy ingot obtained by casting, and finally obtaining the gadolinium-rich nickel-based alloy material for reactor spent fuel storage bar.

[0033] This embodiment adopts the vacuum induction smelting process, and the (Ni, Cr) 5 After Gd, casting and forming, hot forging, hot rolling, annealing and other processes...

Embodiment 2

[0035] This embodiment is basically the same as Embodiment 1, especially in that:

[0036] In this embodiment, a method for preparing a gadolinium-rich nickel-based alloy material for reactor spent fuel storage includes the following steps:

[0037] a. The vacuum induction smelting process is adopted, and when the raw materials are batched, the raw material ingredients used are composed according to the following mass percentage (%) for raw material batching:

[0038]

[0039] Vacuum induction melting is carried out on all raw materials weighed after batching to obtain alloy melt;

[0040] b. This step is the same as in Embodiment 1.

[0041] After experimental testing, the test results show that the room temperature tensile breaking strength of the special steel-based alloy material bar prepared in this embodiment is greater than 700 MPa, and the breaking elongation is greater than 45.0%. The mechanics and corrosion resistance of the special steel base alloy material prepa...

Embodiment 3

[0043] This embodiment is basically the same as the previous embodiment, and the special features are:

[0044] In this embodiment, a method for preparing a special steel-based alloy material for reactor spent fuel storage includes the following steps:

[0045] a. The vacuum induction smelting process is adopted, and when the raw materials are batched, the raw material ingredients used are composed according to the following mass percentage (%) for raw material batching:

[0046]

[0047] Vacuum induction melting is carried out on all raw materials weighed after batching to obtain alloy melt;

[0048] b. This step is the same as in Embodiment 1.

[0049] After experimental testing, the test results show that the room temperature tensile breaking strength of the special steel-based alloy material bar prepared in this embodiment is greater than 650 MPa, and the breaking elongation is greater than 45.0%. The mechanics and corrosion resistance of the special steel base alloy ...

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Abstract

The invention discloses a gadolinium-rich nickel-based alloy material for reactor spent fuel storage. The material is mainly prepared from the following components in percentage by mass: less than or equal to 0.03% of C, less than or equal to 0.02% of N, less than or equal to 0.01% of S, less than or equal to 0.03% of P, 18.0-35.0% of Cr, 0.5-5.0% of Gd, 0-10.0% of Fe, and the balance Ni and inevitable impurities. An alloy melt is obtained through batching and vacuum induction melting; and casting, hot forging, hot rolling, annealing treatment and other processes are carried out to obtain the gadolinium-rich nickel-based alloy material bar or plate for reactor spent fuel storage finally. The gadolinium-rich nickel-based alloy material has the advantages of high strength, low cost, excellent corrosion resistance, excellent processing formability and the like.

Description

technical field [0001] The invention relates to a nickel-based alloy material and a preparation method, in particular to a nickel-based neutron absorbing material and a preparation method, which are applied in the technical field of nuclear functional iron and steel alloy materials. Background technique [0002] As an efficient and clean energy source, nuclear energy is hailed as one of the three major inventions of mankind in the 20th century, which has brought mankind into a new world of using physical atomic energy to change life. In the core of a nuclear reactor, when the concentration of fissile isotopes drops to the point where the given power cannot be maintained, the fuel in the core becomes spent fuel and needs to be unloaded. As most of the spent fuel is unloaded by nuclear power plants due to the expiration of the working life, the capacity of the reactor storage pool is becoming saturated, so the problem of the whereabouts of spent fuel has become a global proble...

Claims

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Application Information

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IPC IPC(8): C22C19/05C22C1/02G21F1/08
CPCC22C19/058C22C1/023G21F1/085
Inventor 肖学山武昭妤费翔
Owner SHANGHAI UNIV
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