Micro-foaming flame-retardant polypropylene (PP) composite material and preparation method thereof

A flame-retardant polypropylene and composite material technology, applied in the field of engineering plastics, can solve the problems of the quality of polypropylene foaming materials cannot meet the requirements, the polypropylene foaming temperature range is narrow, and the foaming process is difficult to control, etc. , The effect of low equipment requirements and uniform distribution of cells

Inactive Publication Date: 2019-09-27
SUZHOU HECHANG POLYMERIC MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the prior art, the foaming process of polypropylene generally adopts the gas foaming process, but the foaming temperature range of polypropylene is very narrow, the foaming process is difficult to control, and problems such as gas escape and uneven cell distribution are prone to occur
The existing raw materials for the preparation of polypropylene foam materials and the foaming process have problems such as high cost, high requirements for equipment, and difficulty in controlling the foaming process, and the quality of the prepared polypropylene foam materials cannot meet the requirements.

Method used

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  • Micro-foaming flame-retardant polypropylene (PP) composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A kind of micro-foaming flame-retardant polypropylene material, its preparation raw material comprises the following components by mass percentage: polypropylene 50%, core-shell silicone rubber particles 20%, hollow glass microspheres 15%, foaming agent masterbatch 10% % and flame retardant 5%. Foaming agent masterbatch is composed of foaming agent expanded graphite, nucleating agent ultra-fine calcium carbonate, elastomer ethylene-vinyl acetate copolymer and PE resin according to the mass ratio of 10:30:20:40 through blending extrusion granulation be made of. Wherein, the extrusion temperature is 120° C., and the rotation speed of the screw of the extruder is 40 r / min. The core-shell silicone rubber particles in the preparation raw materials have a core-shell structure with silicone rubber as the core and polymethyl butyl acrylate as the shell.

[0027] The preparation method of the above-mentioned microfoaming flame-retardant polypropylene material comprises the fol...

Embodiment 2

[0031] A micro-foaming flame-retardant polypropylene material, the raw materials for its preparation include the following components in terms of mass percentage: 70% polypropylene, 10% core-shell silicone rubber particles, 10% hollow glass microspheres, and 7% foaming agent masterbatch % and flame retardant 3%. Foaming agent masterbatch is made of foaming agent expanded graphite, nucleating agent talc powder, elastomer ethylene-vinyl acetate copolymer and PE resin by blending and extrusion granulation according to the mass ratio of 15:35:15:35 . Wherein, the extrusion temperature is 130° C., and the rotation speed of the screw of the extruder is 50 r / min. The core-shell silicone rubber particles in the preparation raw materials have a core-shell structure with silicone rubber as the core and polymethyl butyl acrylate as the shell.

[0032] The preparation method of the above-mentioned microfoaming flame-retardant polypropylene material is the same as that in Example 1.

Embodiment 3

[0034] A micro-foaming flame-retardant polypropylene material, the preparation raw materials include the following components in terms of mass percentage: 65% of polypropylene, 15% of core-shell silicone rubber particles, 13% of hollow glass microspheres, and 5% of foaming agent masterbatch % and flame retardant 2%. Foaming agent masterbatch is made of foaming agent expanded graphite, nucleating agent talc powder, elastomer ethylene-vinyl acetate copolymer and PE resin by blending and extrusion granulation according to the mass ratio of 12:28:22:38 . Wherein, the extrusion temperature is 140° C., and the rotation speed of the screw of the extruder is 60 r / min. The core-shell silicone rubber particles in the preparation raw materials have a core-shell structure with silicone rubber as the core and polymethyl butyl acrylate as the shell.

[0035] The preparation method of the above-mentioned microfoaming flame-retardant polypropylene material is the same as that in Example 1. ...

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Abstract

The invention discloses a micro-foaming flame-retardant polypropylene (PP) material, and the preparation raw materials of the micro-foaming flame-retardant polypropylene material comprise the following components in mass percentage: 50% to 70% of polypropylene, 10% to 20% of core-shell silicone rubber particles, 10% to 15% of hollow glass beads, 5% to 10% of foaming agent masterbatches and 2% to 5% of a flame retardant, wherein the foaming agent masterbatches are prepared from a foaming agent, a nucleating agent, an elastomer and carrier resin, and the foaming agent is expanded graphite. The invention also discloses a preparation method of the micro-foaming flame-retardant polypropylene material. The micro-foamed flame-retardant polypropylene material has excellent mechanical properties and flame retardance, high strength, good toughness, good dimensional stability, uniform cells, good foaming quality, and low production cost, and equipment requirements in the production process are low.

Description

technical field [0001] The invention belongs to the technical field of engineering plastics, in particular to a microfoaming flame-retardant polypropylene material and a preparation method thereof. Background technique [0002] As the requirements for energy consumption and manufacturing costs are getting higher and higher, the metal materials used in traditional mechanical parts are becoming more and more difficult to meet the requirements. As high-performance plastics for construction and mechanical parts, engineering plastics have the advantages of light weight, low manufacturing cost, easy lubrication, low noise, corrosion resistance, stable chemical properties, shock absorption, simple manufacturing process, and strong designability. It has been widely concerned and successfully applied in the field of automobile industry. [0003] Foaming materials in engineering plastics is a way to promote the lightweight of automobiles. The micro-foaming injection molding process ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L83/04C08L33/10C08L23/08C08K13/04C08K7/28C08K3/26C08K3/34C08J9/12
CPCC08J9/0061C08J9/0066C08J9/12C08J2203/22C08J2323/12C08J2423/08C08J2433/10C08J2483/04C08K3/34C08K3/346C08K7/28C08K13/04C08K2003/265
Inventor 金闪魏佳伟周威徐祥严建华
Owner SUZHOU HECHANG POLYMERIC MATERIALS
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