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Mesoporous Molecular Sieve Composite Laser Direct Structuring Materials and Its Application

A technology of laser direct structuring and mesoporous molecular sieve, which is applied in the compounding modification of laser direct structuring additives and the preparation of laser direct structuring materials. Achieve the effects of shortening the plating time, improving the bonding strength, and improving the carbon forming ability

Active Publication Date: 2021-03-09
无锡赢同新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the laser direct structuring additive is not properly selected, it may cause defects such as silver wires and pitting on the surface after injection molding, resulting in slow or even unplating of electroless plating in the later stage, and the failure of the 100-grid test; or the decline in mechanical properties after electroless plating Obviously, it cannot meet the requirements of material performance
[0005] At present, when traditional laser direct structuring additives are used for the production of LDS engineering plastic parts, there is such a contradiction: the increase in the amount of laser direct structuring additives often leads to a decrease in the physical properties of the substrate
However, when the amount of laser direct structuring additives is low, the electroless plating performance is often unsatisfactory, and the bonding strength between the coating and the substrate is also poor, which cannot meet the needs of various occasions

Method used

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  • Mesoporous Molecular Sieve Composite Laser Direct Structuring Materials and Its Application
  • Mesoporous Molecular Sieve Composite Laser Direct Structuring Materials and Its Application
  • Mesoporous Molecular Sieve Composite Laser Direct Structuring Materials and Its Application

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Effect test

Embodiment 1-4

[0051] First, dry the mesoporous molecular sieve MCM-41 (average pore size: 3.4nm; particle size: 200-1000nm) at 200°C and vacuum conditions of <0.1MPa for 2 hours, and at the same time, bisphenol A bis(diphenyl phosphate) 100°C for preheating. Under the vacuum condition of pressure<0.1MPa, mix 100 parts (parts by weight) of mesoporous molecular sieve and 15 parts (parts by weight) of bisphenol-A-diphenyl phosphate, heat up to 120°C and stir for 2 hours, and the obtained phosphoric acid ester / mesoporous molecular sieve hybrid material for use.

Embodiment 1

[0052] In embodiment 1, raw material total amount is 6kg, and by weight percentage, component is as follows:

[0053] Component weight percentage polycarbonate 90% Laser Direct Structuring Additive A 1% Phosphate ester / mesoporous molecular sieve hybrid materials 3% Toughener 5% other additives 1%

Embodiment 2

[0054] In embodiment 2, raw material total amount is 5.5kg, and by weight percentage, component is as follows:

[0055] Component weight percentage polycarbonate 88% Laser Direct Structuring Additive A 3% Phosphate ester / mesoporous molecular sieve hybrid materials 3% Toughener 5% other additives 1%

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Abstract

The invention discloses a mesoporous molecular sieve composite laser direct forming material, which comprises the following components in terms of weight percentage: 70-95% polycarbonate; 1-10% laser direct forming additive; 1-5wt% Phosphate ester / mesoporous molecular sieve hybrid material; 1-15wt% toughening agent; 0.5-5% other additives. The phosphate ester / mesoporous molecular sieve hybrid material is prepared from phosphate ester and mesoporous molecular sieve. The invention also discloses a phosphate / mesoporous molecular sieve hybrid material and a preparation method thereof. The beneficial effects of the present invention are: the phosphate / mesoporous molecular sieve hybrid material can promote the char formation in the laser activation process and help to shorten the plating time; at the same time, the special structure of the mesoporous molecular sieve is helpful for the metal to be deposited on the surface of the substrate. Adhesion, and can significantly improve the bonding strength between the coating and the substrate.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to compound modification of laser direct structuring additives and preparation and application of corresponding laser direct structuring materials. Background technique [0002] LDS, or Laser Direct Structuring, is a 3D-MID production technology with professional laser processing, injection and electroplating processes. Its principle is to endow ordinary plastic components / circuit boards with electrical interconnection functions, support component functions and plastic shells Support, protection and other functions, as well as the shielding and antenna functions produced by the combination of mechanical entities and conductive graphics, are suitable for the production of local thin lines. [0003] LDS can avoid environmental pollution and water consumption caused by traditional plastic electroplating process to a large extent, simplify the production process, and provide f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L69/00C08L51/04C08K13/04C08K3/22C08K3/24C08K7/24C08K5/523
CPCC08L69/00C08L51/04C08K13/04C08K3/22C08K3/24C08K7/24C08K5/523
Inventor 吴彤李莹
Owner 无锡赢同新材料科技有限公司
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