The invention relates to a method for preparing high-density
lithium ferric phosphate, which comprises the following steps of: adding a
lithium salt, a
ferric salt, a
phosphorus-containing compound and
doping metal-containing elements into a dispersing agent by the conventional method, and performing
ball mill twice; performing
drying and predecomposition for 3 to 10 hours; crushing, adding at least one of
lithium dihydrogen
phosphate or
potassium dihydrogen
phosphate as a bonding agent in an amount which is 1 to 5 percent based on the weight of a predecomposition product, performing
ball mill for 1 to 5 hours, and
processing according to the prior art to obtain the high-density lithium
ferric phosphate. In the method, the
ball mill is performed twice in the first step, so that granules are fine; the grain size can be controlled within the range of between 300 and 2,000 nanometers, so that raw materials are mixed uniformly; more importantly, due to the addition of the bonding agent, the bonding among the granules is enhanced, the stacking density of products is improved, and contact
conductivity among the granules is reduced; and the prepared products have good
crystallization, simple structure and uniform grain
fineness distribution and do not contain impure phases, the tap density is between 1.4 and 1.8 g / cm<3>, the specific surface area is between 5 and 11m<2> / g, the compaction density of pole pieces is between 2.4 and 2.8 g / cm<3>, and the specific capacity of first discharging at the
room temperature is between 140 and 160 mAh / g.