The invention discloses a method for separating and enriching
lithium, aluminum and
silicon from
fly ash. The method comprises the following steps: (1) pretreating
fly ash; (2) carrying out low-temperature alkali dip reaction on the treated
fly ash, aids and a
sodium hydroxide solution, and filtering; (3) washing the filter residue, removing the impurities, filtering, and
drying to obtain
calcium silicate; (4) regulating the pH value of the filtrate to
alkalinity, separating the
lithium / aluminum-containing filtrate to obtain a
sodium metaaluminate concentrated solution and a
lithium-rich solution, carrying out
reverse osmosis on the lithium-rich solution to obtain a lithium concentrated solution, and mixing the
sodium metaaluminate concentrated solution with the lithium / aluminum-containing filtrate to obtain a refined solution; (5) precipitating the sodium metaaluminate refined solution, filtering to obtain aluminum
hydroxide, and calcining to obtain the aluminum
oxide finished product; (6) treating the lithium-rich solution to obtain a lithium-rich concentrated solution and
fresh water; and (7) carrying out carbonating
precipitation on the lithium-rich concentrated solution, filtering, and
drying to obtain the
lithium carbonate finished product. The method is a short-stage extraction process, reduces the lithium loss, and implements separation, enrichment and extraction of
calcium silicate, aluminum
oxide and
lithium carbonate.