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Preparation method of wear-resistant colored pencil lead material

A pencil core and color pigment technology, applied in the field of pen core materials, can solve the problems of poor wear resistance, difficult to color the paper surface, light color, etc., to achieve the effect of improving hardness and wear resistance, and bright appearance

Pending Publication Date: 2019-10-08
张裕刚
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The main technical problem to be solved by the present invention is to provide a preparation method of wear-resistant colored pencil core materials for the defects that the current insoluble color pencil core materials have poor wear resistance, are not easy to color on the surface of paper, and have relatively light colors

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0030] Preparation of mixed slurry:

[0031] In a three-necked flask equipped with a thermometer, a stirrer, and a reflux device, add palm oil and diethanolamine at a mass ratio of 1:2, react at a temperature of 150°C for 2 hours, then lower the temperature to 70°C, and add palm oil with a content of 1.0 Double the diethanolamine, continue to react for 3h, obtain brown viscous transparent liquid, obtain white solid after natural cooling;

[0032] In parts by weight, under a nitrogen atmosphere, take 40 parts of the above-mentioned white solid, 1 part of stearic acid and 0.5 part of ethylene glycol, place them in a four-necked flask, heat up to 160 ° C, and stir at a speed of 600 r / min Mix and react for 4 hours to prepare a lubricating dispersant. Put 8 parts of colored enamel glaze, 30 parts of albite feldspar, 20 parts of potassium feldspar, and 40 parts of hydroxyl silicone oil emulsion with a mass fraction of 20% in a mixer at 100r / min After stirring at a rotating speed of...

example 2

[0040] Preparation of mixed slurry:

[0041] In a three-necked flask equipped with a thermometer, a stirrer, and a reflux device, add palm oil and diethanolamine at a mass ratio of 1:2, react at a temperature of 160°C for 2.5 hours, then cool down to 75°C, and add palm oil content 1.2 times of diethanolamine, continue to react for 3.5h, obtain brown viscous transparent liquid, obtain white solid after natural cooling;

[0042] In parts by weight, under a nitrogen atmosphere, take 45 parts of the above-mentioned white solid, 2 parts of stearic acid and 2.0 parts of ethylene glycol, place them in a four-necked flask, heat up to 190 ° C, and stir at a stirring speed of 700 r / min Mix and react for 4.5 hours to prepare a lubricating dispersant. Put 9 parts of colored enamel glaze, 35 parts of albite feldspar, 25 parts of potassium feldspar, and 45 parts of hydroxyl silicone oil emulsion with a mass fraction of 20% in a mixer at 110r / After stirring at a rotating speed of 35min for...

example 3

[0050] Preparation of mixed slurry:

[0051] In a three-necked flask equipped with a thermometer, a stirrer, and a reflux device, add palm oil and diethanolamine at a mass ratio of 1:2, react at a temperature of 170°C for 3 hours, then lower the temperature to 80°C, and add palm oil with a content of 1.5 Double the diethanolamine, continue to react for 4h, obtain brown viscous transparent liquid, obtain white solid after natural cooling;

[0052] In parts by weight, under a nitrogen atmosphere, take 50 parts of the above-mentioned white solid, 5 parts of stearic acid and 4.0 parts of ethylene glycol, place them in a four-necked flask, heat up to 220°C, and stir at a speed of 800r / min Mix and react for 5 hours to prepare a lubricating dispersant. Put 10 parts of colored enamel glaze, 40 parts of albite feldspar, 30 parts of potassium feldspar, and 50 parts of hydroxyl silicone oil emulsion with a mass fraction of 20% in a mixer at 120r / min After stirring at a rotating speed of...

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Abstract

The invention discloses a preparation method of a wear-resistant colored pencil lead material, and belongs to the technical field of pencil lead materials. Palm oil serves as a raw material for preparing palm oil alkanolamide with a lipophilic group and a hydrophilic group, surface active groups of the palm oil alkanolamide can be esterified by the aid of saturated fatty acid and polyols to prepare lubricating dispersants, and the color of the pencil lead material can be enhanced. Polyacrylate ink is doped into a pencil lead base material, a polyacrylate film can be formed on the surface of the pencil lead material after extrusion, nano-silver nitrate powder in the pencil lead base material is reduced to obtain elementary silver under high-heat blending materials to form 'refraction', thecrystallinity of the polyacrylate film is improved by doping modification of inorganic heavy metallic salt in colored glaze, so that the brightness, the wear resistance and the toughness of the polyacrylate film are improved, carried carboxyl can be dehydrated and condensed with hydroxyl in paper fibers, the coloring effect of writing marks is improved, and the preparation method has a wide application prospect.

Description

technical field [0001] The invention discloses a preparation method of a wear-resistant colored pencil lead material, which belongs to the technical field of lead materials. Background technique [0002] Colored pencil refills are pencil refills that use colorants as colorants. It is an easy-to-master coloring tool, and the drawing effect is similar to that of a pencil. There are a variety of colors, and the effect of painting is lighter, fresh and simple, and most of them are easy to be erased by an eraser. It is made with professionally selected, high-grade microparticle pigments. With transparency and color, smooth drawing, the pen core is not easy to fall off from the core groove. [0003] Colored pencils are also divided into two types, one is water-soluble colored pencils (soluble in water), and the other is insoluble colored pencils (insoluble in water). Insoluble colored pencils can be divided into dry and oily. Generally, most of the insoluble colored pencils on...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D13/00
CPCC09D13/00
Inventor 张裕刚
Owner 张裕刚