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A kind of radiation self-cooling functional fiber fabric and preparation method thereof

A technology of functional fibers and fiber fabrics, applied in fiber processing, fiber types, building components, etc., can solve the problems of difficult radiation self-cooling effect, low reflectivity, high requirements, etc., achieve high-efficiency radiation self-cooling function, and have a wide range of applications Effect

Active Publication Date: 2021-10-29
NANJING TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Judging from the existing public reports, under the condition of no sunlight, the radiation cooling mechanism can be used to achieve self-cooling of objects, but the radiation self-cooling performance of radiation cooling materials under daylight conditions has not yet met the practical requirements.
The preparation of existing radiation self-cooling materials mainly includes the following methods: (1) Using nanometer photolithography and plasma deposition technology to construct a radiation cooler with a nano-micro-scale structure. Although the self-cooling performance of the radiation cooler is good, its manufacturing The process is complicated, difficult, and demanding, and it is difficult to produce on a large scale and at low cost
In addition, there are deficiencies such as low structural strength and easy damage; (2) uniformly mix inorganic functional substances such as anatase titanium dioxide micropowder and glass microspheres with polymer resin, and compound a certain thickness on one side of the surface High-reflective metal aluminum or silver film is used to make radiation self-cooling device, but because the selected inorganic functional materials such as titanium dioxide micropowder and glass microspheres have weak selective absorption radiation performance in the infrared spectrum region, it is difficult to make the radiation self-cooling device. Obtain a more ideal radiation self-cooling effect
[0004] At present, the common radiation self-cooling materials are mostly radiation self-cooling coatings, which have high requirements for the coating substrate, and some objects with rough surfaces and low reflectivity are difficult to effectively apply

Method used

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  • A kind of radiation self-cooling functional fiber fabric and preparation method thereof
  • A kind of radiation self-cooling functional fiber fabric and preparation method thereof
  • A kind of radiation self-cooling functional fiber fabric and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0029] A kind of radiation self-cooling functional fiber fabric, its preparation method comprises the following steps:

[0030] 1) According to the mass ratio of the nano-functional composition 1:1:1, weigh 30g of nano-silicon dioxide (infrared absorption / radiation spectrum as shown in figure 1 shown), 30g rare earth silicate compound SiO 2 -La 2 o 3 -0.5Na 2 O(infrared absorption / radiation spectrum such as figure 2 shown) and 30g calcium molybdate CaMoO 4 Powder (infrared absorption / radiation spectrum such as image 3 shown), and 0.045g of silane coupling agent HK560 (the quality is 0.05% of the nano-functional composition), were added together in the high-speed grinding disperser, and were processed at 300 rpm for 6 hours to obtain an active nano-functional composition.

[0031]2) According to the mass ratio of 60% mass ratio of fluororesin solid content in infrared strong selective absorption / radiation coating, take by weighing 50g of the active nano functional compo...

Embodiment 2

[0034] A kind of radiation self-cooling functional fiber fabric, its preparation method comprises the following steps:

[0035] 1) According to the mass ratio of nano-functional composition 1:1.5:0.5, weigh 30g nano-silicon dioxide, 45g rare earth silicate compound SiO 2 -0.5La 2 o 3 -1.0Na 2 O and 15 g magnesium molybdate MgMoO 4 The powder, and 0.09g of silane coupling agent HK560 (0.1% by mass of the nano-functional composition), were added together into a high-speed grinding disperser, and treated at 400 rpm for 2 hours to obtain an active nano-functional composition.

[0036] 2) According to the 40% mass ratio of fluororesin solid content in the infrared strong selective absorption / radiation coating, the 90g active nano functional composition and 100g PTFE fluoropolymer resin solution prepared in step (1) are added together In the nano-grinding disperser, the radiation self-cooling fluorine-containing polymer functional coating required for the preparation of the infr...

Embodiment 3

[0039] A kind of radiation self-cooling functional fiber fabric, its preparation method comprises the following steps:

[0040] 1) According to the mass ratio of the nano functional composition 1:0.5:1, weigh 20g of nano silicon dioxide, 10g of rare earth silicate compound SiO 2 -0.5La 2 o 3 -0.1Gd 2 o 3 -0.5Na 2 O and 20 g calcium molybdate CaMoO 4 The powder, and 0.05 g of silane coupling agent HK560 (0.1% by mass of the nano-functional composition), were added together into a high-speed grinding disperser, and treated at 350 rpm for 4 hours to obtain an active nano-functional composition.

[0041] 2) According to the mass ratio of 70% mass ratio of fluororesin solid content in the infrared strong selective absorption / radiation coating, the active nano functional composition prepared in 45g step (1) and 105g P(VDF-HFP) fluoropolymer resin solution, and added together to a nano-grinding disperser, and ground and dispersed at 400 rpm for 3 hours to obtain the radiation s...

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Abstract

The invention relates to a radiation self-cooling functional fiber fabric and a preparation method thereof, which is characterized in that the surface of the functional fiber fabric is coated with a high-reflection aluminum-silver layer and an 8-14 μm infrared strong selective absorption radiation coating in sequence; 8 ~14μm infrared strong selective absorption radiation coating is composed of active nano functional composition and fluoropolymer resin solution, wherein said active nano functional composition is composed of nano silicon dioxide, rare earth silicate compound and molybdate compound According to the mass ratio of 1:(0.5~2):(0.5~2), it is mixed and modified by silane coupling agent; the solid component mass of fluoropolymer resin solution accounts for 8~14μm infrared strong selective absorption radiation coating 10% to 80% of the layer quality. The functional fiber fabric provided by the invention can exert an efficient radiation self-cooling function under sunlight and no light environment, and can be widely used in the fields of buildings, high-power equipment outer layers or in the manufacture of self-cooling tents and functional clothing.

Description

technical field [0001] The invention relates to a radiation self-cooling functional fiber fabric and a preparation method thereof, belonging to the technical field of functional composite fiber fabric and heat radiation. Background technique [0002] With the continuous development of the global economy, the energy demand faced by human society is increasing. The development of new energy-saving materials and technologies to minimize energy consumption and reduce environmental load has important economic and social value. Radiative self-cooling is a physical mechanism in which ground objects transfer heat to outer space through infrared atmospheric windows, thereby reducing their own temperature. Under the condition of sunlight, the reduction of the surface temperature of the object is mainly related to several aspects: first, the absorption of sunlight energy requires the surface of the object to have as high reflection as possible for 0.3-2.5μm sunlight; second, The absor...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06N3/04D06N3/00D06M11/83D06M101/32D06M101/34D06M101/30
CPCD06M11/83D06M2101/30D06M2101/32D06M2101/34D06N3/0061D06N3/0063D06N3/047D06N2211/06D06N2211/10D06N2211/125
Inventor 陆春华倪亚茹房正刚寇佳慧胡欣方亮许仲梓
Owner NANJING TECH UNIV
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