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Roll-type lead-acid storage battery, preparation method thereof and application thereof

A lead-acid battery, roll-type technology, applied in the direction of lead-acid battery, lead-acid battery electrode, lead-acid battery construction, etc., can solve the problems of low energy utilization efficiency, lower product sales price, inactivation of active materials, etc.

Active Publication Date: 2019-12-20
NANYANG NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

You must produce as much as you want and sell as much as you want, otherwise, you will have to charge and protect the lead battery from time to time, wasting power resources and reducing the sales price of the product
[0023] In summary, the irreversible degeneration of lead batteries caused by the special self-discharge and "float charge" of lead batteries is the result of the inactivation of active materials, increased internal resistance, low energy utilization efficiency, safety hazards and end-of-life of traditional lead batteries. root cause, and its course cannot be changed by "fair use"

Method used

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  • Roll-type lead-acid storage battery, preparation method thereof and application thereof
  • Roll-type lead-acid storage battery, preparation method thereof and application thereof
  • Roll-type lead-acid storage battery, preparation method thereof and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0095] Example 1 (the metal barium plate accounts for 10% in the composite plate C, the lead-barium alloy plate containing 1% barium accounts for 90%, the barium element in the pole plate accounts for 10.9%, and the number of winding layers in the inner core of the single cell battery is n=60)

[0096] (1) 107.50g of analytically pure barium granules were smelted and poured to obtain a barium bar with a specification of 20mm×4mm×40mm and containing 99.95% of barium; 9.68g of analytically pure barium granules were mixed with 957.8g of analytically pure lead granules, melted and casted to obtain The specification is 20mm × 4mm × 40mm, and the lead-barium alloy bar containing 1% barium; under nitrogen atmosphere, the barium bar containing 99.95% barium is rolled into a 0.2mm thick metal barium plate with a boron glass material pressure roller, and A is obtained. Plate, the lead-barium alloy strip containing 1% barium is rolled into a lead-barium alloy plate with a thickness of 0.1...

Embodiment 2

[0110] Example 2 (the metal barium plate accounts for 5% in the composite plate C, the lead-barium alloy plate containing 1% barium accounts for 95%, the barium element accounts for 5.95% in the pole plate, and the number of layers of the inner core of the single cell battery n=60)

[0111] (1) Melting and pouring 50.90g of analytically pure barium particles to obtain a barium bar with a specification of 20mm×4mm×40mm and containing 99.95% of barium; mixing 9.67g of analytically pure barium particles with 957.43 of analytically pure lead particles, melting and pouring, to obtain specifications 20mm×4mm×40mm, lead-barium alloy strip containing 1% barium; under nitrogen atmosphere, roll the barium strip containing 99.95% barium into a 0.14mm thick metal barium plate with a boron glass material pressure roller to obtain A plate , the lead-barium alloy strip containing 1% barium is rolled into a lead-barium alloy plate with a thickness of 0.32mm, the same width as that of plate A, ...

Embodiment 3

[0119] Example 3 (the metal barium plate accounts for 3% in the composite plate C, the lead-barium alloy plate containing 1% barium accounts for 97%, the barium element accounts for 3.97% in the pole plate, and the number of negative plates of the single cell battery is n=60)

[0120] (1) 29.91g of analytically pure barium granules were smelted and poured to obtain a barium bar with a specification of 20mm×4mm×40mm containing 99.95% of barium; 9.67g of analytically pure barium granules were mixed with 957.43g of analytically pure lead granules, melted and casted to obtain The specification is 20mm × 4mm × 40mm, and the lead-barium alloy bar containing 1% barium; under nitrogen atmosphere, the barium bar containing 99.95% barium is rolled into a 0.1mm thick metal barium plate with a boron glass material pressure roller, and A is obtained. Roll the lead-barium alloy strip containing 1% barium into a lead-barium alloy plate with a thickness of 0.55 mm, the same width as plate A, a...

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Abstract

The invention belongs to the field of electric energy storage and particularly relates to a roll-type lead-acid storage battery, a preparation method and application thereof. According to the invention, an inert material metal barium, a lead-barium alloy and a sulfuric acid solution are used as raw materials, generated lead sulfate is extruded into a barium metal plate through rolling, so that thelead sulfate is separated, and meanwhile, and the metal barium forms a stable and reliable conductive network. Then, a diboron trioxide-silicon dioxide colloid layer is applied, lead sulfate particles are subjected to closed isolation further, the colloid layer does not hinder the transmission of sulfate ions and hydrogen ions, then a polar plate is obtained, the polar plate is assembled with other assemblies, and the roll-type lead-acid storage battery is obtained. According to the invention, the irreversibility of a traditional lead-acid storage battery in a using process is effectively overcome, a polar plate conductive network can be kept stable for a long time, active substances are separated in micro grids of the conductive network, almost all the active substances can participate in charging and discharging circulation repeatedly, and therefore, the lead-acid storage battery can achieve a long service life.

Description

technical field [0001] The invention belongs to the field of electric energy storage, and in particular relates to a roll-type lead-acid storage battery and its preparation method and application. Background technique [0002] Among the secondary power sources, lead-acid batteries (hereinafter referred to as lead batteries) account for more than 90% of the total storage capacity (excluding fuel cells) in terms of electric energy storage capacity. Compared with lithium batteries, although its weight specific energy is lower, it has the advantages of abundant raw material sources, relatively safe, easy maintenance and regeneration, and high current discharge. However, there are currently five major drawbacks to maintenance-free lead batteries. [0003] First, the service life is generally 2 to 3 years, and some are even less than 2 years. In the technical research field of lead batteries, the current research mainly focuses on the "carbon doping" of the positive and negative...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/12H01M4/66H01M4/68H01M4/73H01M4/14H01M4/16H01M10/06
CPCH01M4/14H01M4/16H01M4/662H01M4/667H01M4/68H01M4/685H01M4/73H01M10/06H01M10/125Y02E60/10Y02P70/50
Inventor 李波吴卫丽李森兰王利亚
Owner NANYANG NORMAL UNIV
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