Thermally conductive carbon material and preparation method thereof
A technology of carbon materials and coal liquefied pitch, which is applied in the field of heat-conducting carbon materials and its preparation, can solve the problems of low compressive strength of products, high processing temperature, and easy expansion and cracking of molds, so as to reduce mold expansion and cracking rate, increase yield and Compressive strength, easy release effect
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preparation example Construction
[0021] The first aspect of the present invention provides a method for preparing a thermally conductive carbon material, wherein the method includes the following steps:
[0022] (1) Coal liquefied pitch is polymerized and ground to obtain coal liquefied pitch powder;
[0023] (2) Stabilizing the coal liquefaction pitch powder to obtain stabilized coal liquefaction pitch powder;
[0024] (3) Mixing 30-85% by weight of natural flake graphite and 15-70% by weight of the stabilized coal liquefied pitch powder, and performing hot pressing and demoulding to obtain a heat-conducting carbon material.
[0025] In the present invention, coal liquefaction pitch refers to the extract obtained after solvent extraction of coal liquefaction residue. Deashing (ash content) and desulfurization are carried out during the extraction process, which can effectively separate asphalt-like substances from ash and sulfur. Among them, the coal liquefaction residue is a by-product of the direct coal ...
Embodiment approach
[0026] According to an embodiment of the present invention, the softening point of the coal liquefaction pitch may be but not limited to 100-200°C, and the ash content may be but not limited to 0.02-2 wt%.
[0027] According to another embodiment of the present invention, the composition of the coal liquefied pitch contains 82-95% by weight of C element, 1-7% by weight of H element, 0.2-2% by weight of N element, 2-8% by weight % O element and 0.1-1 wt% S element.
[0028] According to the method of the present invention, the purpose of the polymerization conditions is to solidify the coal liquefied bitumen. The polymerization conditions may include but not limited to: the polymerization temperature is 350-460°C, and the polymerization time is 3-30h. In a preferred embodiment of the present invention, N 2 Protected against oxidation of coal liquefaction bitumen.
[0029] According to the method of the present invention, the particle size of the coal liquefaction pitch powde...
preparation example 1
[0042] The coal liquefaction residue is extracted with a medium oil extractant to obtain a coal liquefaction pitch, wherein the coal liquefaction pitch has a softening point of 150° C. and an ash content of 0.02% by weight.
[0043] The composition of the coal liquefied pitch contains 91% by weight of C elements, 6% by weight of H elements, 1.5% by weight of N elements, 1.1% by weight of O elements and 0.4% by weight of S elements.
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