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Asphalt modifier based on petrochemical industrial waste catalyst and preparation method

A technology of asphalt modifier and waste catalyst, which is applied in the direction of building components, building insulation materials, buildings, etc., can solve the problems that restrict the large-scale utilization of FCC waste catalyst, the safety risk of heavy metal seepage, and the low recycling rate, so as to avoid Exudation of heavy metals, improvement of road performance, simple effect

Pending Publication Date: 2019-12-24
北京新桥技术发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The physical separation method mainly uses the magnetic separation method, and a small number of catalysts with short cycle time, light pollution (low magnetic agent), good performance, and continued use are screened out by physical methods. However, those catalysts that have been significantly deactivated can only be used traditional method
[0003] At present, the main way to deal with spent FCC catalysts is to regenerate them. The method is to process them through chemical regeneration and magnetic separation technology to make the spent catalysts active again and participate in the catalytic reaction of the petrochemical industry again. However, the recycling rate of this method is relatively low. Low, generally between 20% and 50%
In addition, researchers have used Al, Si and other elements in FCC waste catalysts to mix them into cement production. Although the recycling rate is 100%, for cement production lines, the daily output of FCC waste catalysts is very small, and The change of raw materials will inevitably require the adjustment of the production parameters of the cement production line, which will cause difficulties in actual production and restrict the large-scale utilization of FCC spent catalysts
As an adsorbent, FCC waste catalyst can be used for water deacidification by taking advantage of its porous properties, but there will be a safety risk of heavy metal leaching

Method used

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  • Asphalt modifier based on petrochemical industrial waste catalyst and preparation method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A kind of asphalt modifier based on petrochemical industry waste catalyst of the present embodiment includes: asphalt mixture, ore powder and FCC waste catalyst, wherein,

[0028] The weight components of asphalt mixture according to the largest particle size include:

[0029] 0-3mm 31 parts, 3-5mm 16 parts,

[0030] 5-10mm 35 parts, 10-15mm 15 parts;

[0031] 4 parts mineral powder;

[0032] FCC waste catalyst 0.4 parts.

[0033] The preparation method of the asphalt modifier based on petrochemical industrial waste catalyst of the present embodiment comprises:

[0034] Place the asphalt mixture, mineral powder and FCC waste catalyst at 105°C Dry in an oven at 5°C to constant weight;

[0035] The dried coarse and fine aggregates, as well as ore powder and FCC waste catalyst are weighed out according to the quality of gradation design, wherein,

[0036] The weight components of asphalt mixture according to the largest particle size include:

[0037] 0-3mm 31 part...

Embodiment 2

[0049] A kind of asphalt modifier based on petrochemical industry waste catalyst of the present embodiment includes: asphalt mixture, ore powder and FCC waste catalyst, wherein,

[0050] The weight components of asphalt mixture according to the largest particle size include:

[0051] 0-3mm 35 parts, 3-5mm 19 parts,

[0052] 5-10mm 39 parts, 10-15mm 19 parts;

[0053] 7 parts of mineral powder;

[0054] FCC spent catalyst 0.7 parts.

[0055] The preparation method of the asphalt modifier based on petrochemical industrial waste catalyst of the present embodiment comprises:

[0056] Put the asphalt mixture, mineral powder and FCC waste catalyst at 105°C Dry in an oven at 5°C to constant weight;

[0057] The dried coarse and fine aggregates, as well as ore powder and FCC waste catalyst are weighed out according to the quality of gradation design, wherein,

[0058] Asphalt mixture, according to the largest particle size, includes by weight:

[0059] 0-3mm 35 parts, 3-5mm 19...

Embodiment 3

[0071] A kind of asphalt modifier based on petrochemical industry waste catalyst of the present embodiment includes: asphalt mixture, ore powder and FCC waste catalyst, wherein,

[0072] The weight components of asphalt mixture according to the largest particle size include:

[0073] 0-3mm 33 parts, 3-5mm 18 parts,

[0074] 5-10mm 37 parts, 10-15mm 17 parts;

[0075] Mineral powder 6 parts;

[0076] FCC waste catalyst 0.4-0.6 parts.

[0077] The preparation method of the asphalt modifier based on petrochemical industrial waste catalyst of the present embodiment comprises:

[0078] Place the asphalt mixture, mineral powder and FCC waste catalyst at 105°C Dry in an oven at 5°C to constant weight;

[0079] The dried coarse and fine aggregates, as well as ore powder and FCC waste catalyst are weighed out according to the quality of gradation design, wherein,

[0080] The weight components of asphalt mixture according to the largest particle size include:

[0081] 0-3mm 33 ...

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Abstract

The invention discloses an asphalt modifier based on a petrochemical industrial waste catalyst and a preparation method. The asphalt modifier is prepared from an asphalt mixture, mineral powder and anFCC waste catalyst, and has the advantages that the implementation is simple, and the FCC waste catalyst is comprehensively used for an asphalt mixture, so that the 100% utilization of the FCC wastecatalyst is realized. The FCC waste catalyst is porous and large in specific surface area, so that the water stability and high-temperature stability of the asphalt mixture can be improved, and the pavement performance is improved. Meanwhile, the asphalt is used for a lower surface layer or a middle surface layer of a pavement, and the asphalt is used for wrapping the waste catalyst, so that the safety risk of heavy metal seepage can be effectively avoided.

Description

technical field [0001] The invention relates to an asphalt modifier based on petrochemical industry waste catalyst and a preparation method. Background technique [0002] As of the end of 2016, the annual production of FCC (Fluid Catalytic Cracking) spent catalysts in my country has reached 100,000 tons, and FCC spent catalysts have been included in the national hazardous waste list, which will definitely increase the treatment cost of FCC spent catalysts. The FCC catalyst is made by beating alumina sol, pseudo-boehmite, silica sol and adhesive (clay) with acid to obtain slurry, spray drying, and then ion exchange, loaded with rare earth RE 2 o 3 Ionic, fluidized catalyst prepared by calcination. FCC catalysts are composed of zeolites (molecular sieves) based on Al 2 o 3 and SiO 2 It is a crystalline silicon-aluminum salt with a lattice structure as the main component, and has a large specific surface area and pore volume. Although the spent FCC catalyst has lost i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L95/00C08K7/26C08K3/34
CPCC08L95/00C08L2205/025
Inventor 张阳浦立娜宋平
Owner 北京新桥技术发展有限公司