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Hafnium zirconium titanium reinforced austenitic stainless steel and preparation method thereof

A technology of austenitic stainless steel and stainless steel, which is applied in the field of austenitic stainless steel, can solve the problems of low mechanical properties such as radiation resistance and corrosion resistance, and achieve improved radiation resistance, increased strength, and strong process controllability Effect

Active Publication Date: 2019-12-24
NANJING YOUTIAN METAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Purpose of the invention: Aiming at the problems of the existing austenitic stainless steels such as radiation resistance, corrosion resistance and low mechanical properties, the present invention provides a hafnium-zirconium-titanium reinforced austenitic stainless steel and an austenitic stainless steel The preparation method of body stainless steel

Method used

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  • Hafnium zirconium titanium reinforced austenitic stainless steel and preparation method thereof
  • Hafnium zirconium titanium reinforced austenitic stainless steel and preparation method thereof
  • Hafnium zirconium titanium reinforced austenitic stainless steel and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0029] Select pure iron, metal chromium, metal nickel, metal manganese, metal hafnium, metal zirconium, metal titanium, iron-silicon, iron-carbon block raw materials, the composition of the prepared austenitic stainless steel is as follows: C=0.05, Ni=11, Cr=20 , Ti=0.1, Hf=0.05, Zr=0.1, Mn=2, Si=1, P≤0.035, S≤0.030, Fe=balance.

[0030] Cast alloy ingots by arc melting or induction melting; smelting is carried out in vacuum or argon protection, and magnetic stirring technology is used to mix the metal solution evenly during the melting process; protection casting is carried out under vacuum or argon protection, and the size is cast into square or round ingot;

[0031] The ingot is hot-rolled by a rolling mill. The hot-rolling plan is to heat the billet to 1200±10°C, heat it for 24 hours and then roll it out of the furnace. The hot-rolling start temperature is 1180±20°C, the final rolling temperature is ≥950°C, and the plate is hot-rolled. The total amount of betting ≥ 60%; ...

Embodiment 2

[0036] Select pure iron, metal chromium, metal nickel, metal manganese, metal hafnium, metal zirconium, metal titanium, iron-silicon, iron-carbon block raw materials, the composition of the prepared austenitic stainless steel is as follows: C=0.05, Ni=11, Cr=20 , Ti=0.1, Hf=0.2, Zr=0.1, Mn=2, Si=1, P≤0.035, S≤0.030, Fe=balance.

[0037] Cast alloy ingots by arc melting or induction melting; smelting is carried out in vacuum or argon protection, and magnetic stirring technology is used to mix the metal solution evenly during the melting process; protection casting is carried out under vacuum or argon protection, and the size is cast into square or round ingot;

[0038] The ingot is hot-rolled by a rolling mill. The hot-rolling plan is to heat the billet to 1250±10°C, heat it for 10 hours and then roll it out of the furnace. The hot-rolling start temperature is 1240±20°C, the final rolling temperature is ≥950°C, and the plate is hot-rolled The total amount of betting ≥ 60%;

...

Embodiment 3

[0043] Select pure iron, metal chromium, metal nickel, metal manganese, metal hafnium, metal zirconium, metal titanium, iron-silicon, iron-carbon block raw materials, the composition of the prepared austenitic stainless steel is as follows: C=0.05, Ni=11, Cr=20 , Ti=0.1, Hf=0.4, Zr=0.1, Mn=2, Si=1, P≤0.035, S≤0.030, Fe=balance.

[0044] Cast alloy ingots by arc melting or induction melting; smelting is carried out in vacuum or argon protection, and magnetic stirring technology is used to mix the metal solution evenly during the melting process; protection casting is carried out under vacuum or argon protection, and the size is cast into square or round ingot;

[0045] The ingot is hot-rolled by a rolling mill to open the billet. The hot-rolling plan is to heat the billet to 1150±10°C, heat it for 24 hours and then roll it out of the furnace. The hot-rolling start temperature is 1140±20°C, and the final rolling temperature is ≥950°C. The total amount of betting ≥ 60%;

[0046...

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Abstract

The invention discloses hafnium zirconium titanium reinforced austenitic stainless steel and a preparation method thereof. The austenitic stainless steel comprises the following elements of, in percentage by mass, less than or equal to 0.05 of C, 8.0-13.0 of Ni, 18.0-22.0 of Cr, less than or equal to 0.1 of Ti, less than or equal to 0.4 and larger than or equal to 0.05 of Hf, less than or equal to0.3 and larger than or equal to 0.05 of Zr, less than or equal to 2.0 of Mn, less than or equal to 1.0 of Si, less than or equal to 0.035 of P, less than or equal to 0.030 of S, and the balance Fe. The preparation method comprises the following steps of (1), smelting and casting stainless steel; (2), hot rolling the blanking; (3), cold rolling deformation; and (4), carrying out high-temperature heat treatment. According to the preparation method, zirconium, hafnium and titanium are added into the stainless steel, not only can the strength be improved, but also the irradiation resistance of the austenitic stainless steel can be improved, and at the H2SO4 electrolyte at the temperature of 80 DEG C for 0.5 mol / L, the austenitic stainless steel has a corrosion rate of 20.3 to 32. 7microampere / square centimetre, the plasticity of the austenitic stainless steel is higher than 49%, and the tensile strength is higher than 730 MPa.

Description

technical field [0001] The invention relates to a hafnium-zirconium-titanium reinforced austenitic stainless steel and a preparation method thereof, belonging to the field of austenitic stainless steel. Background technique [0002] Facing the current increasingly severe resource, energy and environmental problems, the sustainable development of energy has become particularly important. Nuclear power is one of the important sources of large-scale sustainable supply of electric energy in the world today. A nuclear power plant is a new type of power station that uses the energy in the nucleus of an atom to generate electricity on a large scale. Nuclear power currently accounts for approximately 16% of the world's total electricity generation. Austenitic stainless steel is widely used in the field of nuclear power because of its excellent corrosion resistance, but it is also very susceptible to corrosion by aggressive ions, stress corrosion and pitting, and under high-dose ir...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/50C22C38/58C22C38/02C22C38/04C22C33/06C21D8/00
CPCC21D8/005C22C33/06C22C38/002C22C38/02C22C38/04C22C38/50C22C38/58
Inventor 张中武李俊澎
Owner NANJING YOUTIAN METAL TECH