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Stain-resistant and weather-resistant polyurethane acrylate coating material and preparation method thereof

A urethane acrylate and weather resistance technology, which is applied in the field of urethane acrylate, can solve the problems that UV-curable coatings need to be further improved, and achieve the effects of improving weather resistance, maintaining stain resistance, and improving stain resistance

Inactive Publication Date: 2020-01-24
上海翰飞新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, many properties of UV-curable coatings prepared by polyurethane acrylate still need to be further improved.

Method used

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  • Stain-resistant and weather-resistant polyurethane acrylate coating material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A stain-resistant, weather-resistant polyurethane acrylate paint, comprising the following raw materials in parts by weight:

[0023] 50 parts of polyurethane acrylate, 40 parts of pentaerythritol triacrylate, 15 parts of nano-SiO2 with an average particle size of about 30 nm, 3 parts of 1-hydroxycyclohexyl phenyl ketone and 8 parts of nano-titanium dioxide with an average particle size of about 20 nm.

[0024] A kind of preparation method of described dirt-resistant, weather-resistant polyurethane acrylate paint, comprises the steps:

[0025] (1) Add urethane acrylate and pentaerythritol triacrylate in the reaction vessel and stir to obtain the first mixture;

[0026] (2) Slowly add nano-SiO2 and 1-hydroxycyclohexyl phenyl ketone to the first mixture under stirring, heat to 50° C., and stir for 20 minutes to obtain a second mixture;

[0027] (3) filtering the second mixture with a 300-mesh filter cloth to obtain the first filtrate;

[0028] (4) Slowly add nano-titani...

Embodiment 2

[0031] A stain-resistant, weather-resistant polyurethane acrylate paint, comprising the following raw materials in parts by weight:

[0032] 40 parts of polyurethane acrylate, 30 parts of a mixture of trimethylolpropane tetraacrylate and propoxylated multifunctional acrylate, 10 parts of nano-SiO2 with a particle size of about 10nm, 2,4,6-trimethyl 1 part of ethyl benzoyl phenyl phosphonate and methyl benzoyl formate mixture and 5 parts of nano titanium dioxide with a particle size of about 1 nm.

[0033] A kind of preparation method of described dirt-resistant, weather-resistant polyurethane acrylate paint, comprises the steps:

[0034] (1) Add a mixture of urethane acrylate, trimethylolpropane tetraacrylate and propoxylated polyfunctional acrylate in the reaction vessel and stir to obtain the first mixture;

[0035] (2) Slowly add nano-SiO2, ethyl 2,4,6-trimethylbenzoylphenylphosphonate and methyl benzoylformate mixture to the first mixture under stirring, and heat to 40°C ...

Embodiment 3

[0039] A stain-resistant, weather-resistant polyurethane acrylate paint, comprising the following raw materials in parts by weight:

[0040] 60 parts of polyurethane acrylate, 50 parts of a mixture of pentaerythritol tetraacrylate and trimethylolpropane tetraacrylate, 20 parts of nano-SiO2 with a particle size of about 50nm, 2-methyl-2-(4-morpholinyl) -5 parts of 1-[4-(methylthio)phenyl]-1-propanone and ethyl 2,4,6-trimethylbenzoylphenylphosphonate and 10 parts of nano-titanium dioxide with a particle size of about 30nm share.

[0041] A kind of preparation method of described dirt-resistant, weather-resistant polyurethane acrylate paint, comprises the steps:

[0042] (1) Add urethane acrylate, pentaerythritol tetraacrylate and trimethylolpropane tetraacrylate mixture in the reaction vessel and stir to obtain the first mixture;

[0043] (2) Slowly add nano-SiO2, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio)phenyl]-1- A mixture of acetone and ethyl 2,4,6-trimethylbenzoylpheny...

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Abstract

The invention discloses a stain-resistant and weather-resistant polyurethane acrylate coating material and a preparation method thereof, and relates to the technical field of polyurethane acrylate, wherein the coating material comprises the following raw materials by weight: 40-60 parts of polyurethane acrylate, 30-50 parts of an active diluent, 10-20 parts of nanometer SiO2, 1-5 parts of a photoinitiator and 5-10 parts of nanometer titanium dioxide. According to the invention, by adding the nanometer SiO2, the energy storage modulus of the polyurethane acrylate coating material can be improved, and the weather resistance of the polyurethane acrylate coating material can be remarkably improved; the stain-resistant and weather-resistant polyurethane acrylate coating material is low in toxicity and environment-friendly, and does not affect people or animals contacting the product; and the polyurethane acrylate and the nanometer SiO2 can effectively form a channel to firmly lock the nanometer titanium dioxide with small particle size in the channel, so that the stain resistance of the coating material is improved, and the stain resistance effect of the coating material can be kept fora long time.

Description

technical field [0001] The invention relates to the technical field of polyurethane acrylate, in particular to a stain-resistant and weather-resistant polyurethane acrylate coating and a preparation method thereof. Background technique [0002] In recent years, with people's increasing requirements for environmental protection, solvent-free fast-curing environmentally friendly coatings have attracted more and more attention, and have been widely used in the fields of electronics, automobiles and precision instruments. [0003] Urethane acrylate, as the main ingredient of UV-curable coatings, can undergo physical and chemical changes in a short period of time after being irradiated with ultraviolet light. However, many properties of UV-curable coatings prepared from polyurethane acrylate still need to be further improved. [0004] Among the inorganic nanoparticles, nano-SiO2 particles appeared first. The application of nano-SiO2 in coatings can not only improve the scratch r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D5/16C09D7/61C09D7/63
CPCC08K2003/2241C08K2201/011C09D5/1662C09D5/1687C09D175/14C08K3/22C08K3/36
Inventor 蒋东其陈跃军谭卫兴
Owner 上海翰飞新材料科技有限公司