Gradient titanium-magnesium composite material implant for inducing bone growth and forming method thereof
A composite material and implant technology, which is applied in the field of functional bone implant manufacturing, can solve the problems of weak biological activity and weak bone tissue binding ability, and achieve the effect of enhancing biological activity, meeting pathological needs, and enhancing bonding strength
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Embodiment 1
[0043] (1) Spherical medical titanium alloy powder is formed into titanium alloy porous structure implants by selective laser melting technology;
[0044](2) Under the protection of high-purity argon, mix the Mg-Zn alloy and nano-hydroxyapatite powder with a mass ratio of 10:1 in a high-energy ball milling process with a rotation speed of 40 rpm to obtain a uniformly mixed composite material powder;
[0045] (3) Wrap the titanium alloy porous implant in step (1) with the mixed powder in step (2), put it into the ceramic extrusion cylinder of the hydrostatic extrusion testing machine, and then vacuumize to 5×10 -3 Pa, heat the extrusion cylinder at 650°C until the Mg-Zn alloy powder is melted and keep it warm for 10 minutes, and apply a 0.05T magnetic field to the outer ring of the extrusion cylinder to promote the uniform composition of the Mg-Zn alloy melt in the cylinder;
[0046] (4) cyclically apply a compressive stress of 0.5 MPa on both sides of the extrusion cylinder, a...
Embodiment 2
[0049] (1) Spherical medical titanium alloy powder is formed into titanium alloy porous structure implants by selective laser melting technology;
[0050] (2) Under the protection of high-purity argon, the Mg-Ca alloy with a mass ratio of 30:1 and nano-hydroxyapatite powder are mixed in a high-energy ball milling process with a rotation speed of 80 rpm to obtain a uniformly mixed composite material powder;
[0051] (3) Wrap the titanium alloy porous implant in step (1) with the mixed powder in step (2), put it into the ceramic extrusion cylinder of the hydrostatic extrusion testing machine, and then vacuumize to 3×10 -3 Pa, heat the extrusion cylinder at 700°C until the Mg-Ca alloy powder melts and keep it warm for 20 minutes, and apply a 0.1T magnetic field to the outer ring of the extrusion cylinder to promote the uniform composition of the Mg-Ca alloy melt in the cylinder;
[0052] (4) cyclically apply a compressive stress of 3 MPa on both sides of the extrusion cylinder, s...
Embodiment 3
[0056] (1) Spherical medical titanium alloy powder adopts selective laser melting technology to form a titanium alloy porous structure implant, the titanium alloy powder is Ti-Nb alloy powder, and the mass fraction of Ti in the Ti-Nb alloy powder is 65%. , the mass fraction of Nb is 35%;
[0057] (2) Under the protection of high-purity argon, the Mg-Zr alloy with a mass ratio of 50:1 and nano-hydroxyapatite powder are mixed in a high-energy ball milling process with a rotation speed of 100 rpm to obtain a uniformly mixed composite material powder;
[0058] (3) Wrap the titanium alloy porous implant in step (1) with the mixed powder in step (2), put it into the ceramic extrusion cylinder of the hydrostatic extrusion testing machine, and then evacuate to 1×10 -3 Pa, heat the extrusion cylinder at 750°C until the Mg-Zr alloy powder is melted and keep it warm for 20 minutes, and apply a 0.2T magnetic field to the outer ring of the extrusion cylinder to promote the uniform composit...
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