Near-infrared light-emitting material and light-emitting device containing light-emitting material
A technology of light-emitting materials and light-emitting devices, applied in the directions of light-emitting materials, semiconductor devices, chemical instruments and methods, etc., can solve the problems of inability to achieve broad spectrum or multi-spectrum and adjustable, high technical difficulties, poor stability, etc., and achieve a wide range of applications. , The spectrum is adjustable and controllable, avoiding the effect of high cost
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Embodiment 1
[0036] The near-infrared luminescent material described in this embodiment comprises a compound whose composition formula is LaSc 2.9 (B 0.85 Ga 0.15 o 3 ) 4 : 0.1Cr.
[0037] According to the chemical formula LaSc 2.9 (B 0.85 Ga 0.15 o 3 ) 4 : 0.1Cr stoichiometric ratio, accurately weighed La 2 o 3 、Sc 2 o 3 , B 2 o 3 , Ga 2 o 3 and Cr 2 o 3 Mix to obtain a mixture; after the mixture is ground and mixed, it is calcined at 1300°C for 5 hours in an air atmosphere, and the roasted product is obtained after cooling down; the obtained roasted product is subjected to post-processing such as crushing, grinding, grading, and sieve washing, that is, Near-infrared phosphors are available.
[0038] The obtained near-infrared phosphor sample was subjected to an excitation test, and the excitation and emission spectra of the sample were obtained as attached figure 1 shown.
Embodiment 2
[0040] The near-infrared luminescent material described in this embodiment comprises a compound whose composition formula is LaSc 1.9999 Lu(B 0.85 Ga 0.15 o 3 ) 4 : 0.0001Cr.
[0041] According to the chemical formula LaSc 1.9999 Lu(B 0.85 Ga 0.15 o 3 ) 4 : 0.0001Cr stoichiometric ratio, accurately weighed La 2 o 3 、Sc 2 o 3 、Lu 2 o 3 , B 2 o 3 , Ga 2 o 3 and Cr 2 o 3 Mixing to obtain a mixture; mixing according to a selected stoichiometric ratio, adding a flux, growing a seed crystal by a molten salt method, and growing a transparent crystal by using a pulling method using the seed crystal.
Embodiment 3
[0043] The near-infrared luminescent material described in this embodiment comprises a compound whose composition formula is LaSc 2.999 (BO 3 ) 4 : 0.001Cr.
[0044] According to the chemical formula LaSc 2.999 (BO 3 ) 4 : 0.001Cr stoichiometric ratio, accurately weighed La 2 o 3 、Sc 2 o 3 , B 2 o 3 and Cr 2 o 3 Mix to obtain a mixture; after the mixture is ground and mixed, it is calcined at 1300°C for 5 hours in an air atmosphere, and the roasted product is obtained after cooling down; the obtained roasted product is subjected to post-processing such as crushing, grinding, grading, and sieve washing, that is, Near-infrared phosphors are available.
[0045] For the near-infrared luminescent material described in Examples 4-18 and the luminescent device containing the luminescent material, the composition formulas of the compounds are listed in Table 1 below. The preparation method of the material in each example is the same as in Example 1 or 2, except that Acco...
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