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Organic laser based on holographic polymer dispersed liquid crystal grating

An organic laser, disperse liquid crystal technology, applied in lasers, laser parts, phonon exciters, etc., can solve the problems of limiting the development of DFB lasers, poor parameter controllability, poor flexibility, etc., to achieve wide application value, low cost, High-efficiency preparation

Inactive Publication Date: 2020-04-10
QUFU NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The existing distributed feedback cavity is mainly prepared by nanoimprinting, UV embossing, electron beam etching and ion etching, etc., which has the disadvantages of complex process, poor flexibility and poor controllability of parameters, which limits the application of DFB lasers. Further development

Method used

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  • Organic laser based on holographic polymer dispersed liquid crystal grating
  • Organic laser based on holographic polymer dispersed liquid crystal grating
  • Organic laser based on holographic polymer dispersed liquid crystal grating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The preparation steps of an organic laser based on a holographic polymer dispersed liquid crystal grating are as follows:

[0035] (1) Add 6 mg of MEH-PPV into 1 mL of xylene and stir to dissolve completely, and prepare a mixed solution of 6 mg / mL of MEH-PPV;

[0036] (2) Select glass with ITO film as the substrate (25 mm in length, 20 mm in width, and 2 mm in thickness), and spin-coat the MEH-PPV mixed solution into a film with a thickness of about 80 nm;

[0037] (3) The glass substrate coated with MEH-PPV film and another clean glass substrate are prepared into a liquid crystal cell, and the thickness of the cell is controlled by a spacer to 6 ;

[0038] (4) 30 wt.% photosensitive monomer diethylene glycol diacrylate (PDDA), 30 wt.% dipentaerythritol hydroxypentaacrylate (DPHPA), 28 wt.% nematic liquid crystal TEB30A, 10 Wt.% crosslinker N-vinylpyrrolidone (NVP), 1.5 wt.% co-initiator N-phenylglycine (NPG), 0.5 wt.% photoinitiator Rose Bengal mixed evenly to make ...

Embodiment 2

[0042] Prepare the liquid crystal cell filled with the prepolymer solution according to the preparation steps (1) to (4) in Case 1.

[0043] The liquid crystal cell injected with the prepolymer solution was exposed for 10 minutes in the interference field formed by two continuous laser beams (532 nm), and the included angle of the interference light was changed to prepare holographic polymer dispersed liquid crystal gratings with different periods.

[0044] A Nd:YAG frequency-doubled pulsed laser (532 nm, 8 ns, 2 Hz.) was used as the pump source to excite the prepared samples. The grating period was different and the wavelength of the emitted laser light was different, such as Figure 4 shown.

Embodiment 3

[0046] Prepare the liquid crystal cell according to the preparation steps (1) to (3) in Case 1.

[0047] 60 wt.% photosensitive monomer diethylene glycol diacrylate (PDDA), 28 wt.% nematic liquid crystal TEB30A, 10 wt.% cross-linking agent N-vinylpyrrolidone (NVP), 1.5 wt. % co-initiator N-phenylglycine (NPG) and 0.5 wt.% photoinitiator Rose Bengal were mixed evenly to make a prepolymer mixed solution, and the prepolymer mixed solution was injected into the above-mentioned liquid crystal cell in a dark room.

[0048] The liquid crystal cell injected with the prepolymer solution was exposed for 10 minutes in the interference field formed by two continuous laser beams (532 nm). The angle between the two beams of interference light was 86°, and the period of the holographic polymer dispersed liquid crystal grating was 390 nm. The intensity of each beam of interference light is 4.5 mW / cm 2 .

[0049] A Nd:YAG frequency-doubled pulsed laser (532 nm, 8 ns, 3 Hz.) was used as the p...

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Abstract

The invention discloses an organic laser based on a holographic polymer dispersed liquid crystal grating and a preparation method thereof, and the preparation method comprises the following steps: (1)dissolving an organic luminescent material in an organic solvent to prepare an organic solution; (2) carrying out vacuum evaporation or spin-coating on the organic solution onto a transparent substrate to obtain an organic light-emitting film; (3) stacking the transparent substrate with the organic light-emitting film and another clean transparent substrate, separating the transparent substrate from the other clean transparent substrate by spacers at four corners of the substrate, and sealing the edges by curing adhesive to prepare a liquid crystal box; (4) uniformly mixing a photosensitive monomer, liquid crystal, a photoinitiator, a co-initiator and a cross-linking agent in a darkroom, and injecting the mixture into the liquid crystal box; and (5) exposing the liquid crystal box under two beams of coherent light to form an interference pattern, and curing to obtain the organic laser based on the holographic polymer dispersed liquid crystal grating. The holographic polymer dispersedliquid crystal grating is a resonant cavity of the laser, and the organic light-emitting film is a gain medium of the laser.

Description

technical field [0001] The invention relates to an organic laser based on a holographic polymer dispersed liquid crystal grating and a preparation method thereof, belonging to the technical field of lasers. Background technique [0002] The wavelength range of organic laser light can cover the entire visible light band, and the cost is low and the integration is convenient. Therefore, it has important application value in the fields of safety inspection, detection, spectroscopy, integrated optoelectronics, information display and communication. [0003] Organic luminescent materials have obtained laser emission in a variety of resonant cavities. These resonant cavities can be conventional Fabry-Perot cavities, or some novel mesoscopic cavities, such as whispering gallery nanosphere cavities, organic microcavities , nano-ring cavity, etc., among which the distributed feedback (DFB) cavity has been the most widely studied. [0004] DFB laser has the advantages of narrow linew...

Claims

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Application Information

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IPC IPC(8): H01S3/08
CPCH01S3/08H01S3/08009
Inventor 刘丽娟孔晓波
Owner QUFU NORMAL UNIV