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Foam enhancer for micro-foam drilling fluid as well as preparation method and application thereof

A drilling fluid and enhancer technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problem of insufficient stability and compression resistance of micro-bubble drilling fluid, affect the leak-proof performance of micro-bubble drilling fluid, and affect drilling To solve problems such as liquid construction safety, achieve the effects of increasing the arrangement density and microbubble wall thickness, improving air core sealing, enhancing stability and compression resistance

Active Publication Date: 2020-04-14
中石化石油工程技术服务有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, microbubbles must maintain a certain degree of compression resistance under high pressure conditions at the bottom of the well to prevent the foam wall from breaking, thereby affecting the leak-proof performance of microbubble drilling fluids
The microfoam drilling fluid system in the prior art all uses xanthan gum, LV-CMC and HV-PAC mixture and other substances with thickening effect to improve the stability of the microbubbles. Although it has a certain effect, the microbubble drilling fluid There are insufficient stability and compression resistance under high temperature and high pressure. Under the high pressure condition at the bottom of the well, the foam wall may rupture, causing air to diffuse out from the microbubbles, resulting in an increase in the density of the microbubble drilling fluid and a decrease in the leak-proof performance. Drilling Fluid Construction Safety

Method used

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  • Foam enhancer for micro-foam drilling fluid as well as preparation method and application thereof
  • Foam enhancer for micro-foam drilling fluid as well as preparation method and application thereof
  • Foam enhancer for micro-foam drilling fluid as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Dissolve 10g of dodecyldimethylallyl ammonium chloride in 100g of clear water for use, and dissolve 80g of acrylamide and 10g of 2-acrylamido-2-methylpropanesulfonic acid in 250g of clear water for use ; 1g of ammonium persulfate is dissolved in 50g of clear water for use;

[0049] Add 0.1 g of mercaptoacetic acid and the above dodecyldimethylallyl ammonium chloride solution, acrylamide and 2-acrylamido-2-methylpropanesulfonic acid solution into the reactor and raise the temperature to 60°C, Then the ammonium persulfate solution was added to the reaction system, the temperature of the system was raised to 90° C. for 1 hour, and the pH value of the solution was adjusted to 8 with NaOH to obtain a foam enhancer for microfoam drilling fluid with a solid content of 20%.

[0050] The structure of the foam enhancer for microfoam drilling fluid prepared in Example 1 of the present invention was tested for its structure. The test result showed that the structure of the foam enh...

Embodiment 2

[0060] Dissolve 5g of tetradecyldimethylallyl ammonium chloride in 50g of clear water for use; dissolve 70g of acrylic acid and 25g of 2-acryloyloxybutylsulfonic acid in 200g of clear water for use; dissolve 0.2g Potassium persulfate is dissolved in 50g of clear water for later use;

[0061] Add 0.5g of ferric chloride, the above tetradecyl dimethyl allyl ammonium chloride solution, the above acrylic acid and 2-acryloyloxybutyl sulfonic acid solution into the reaction vessel and raise the temperature to 50°C, and then add potassium persulfate The solution was added to the reaction system, the temperature of the system was raised to 95° C. and reacted for 2 hours, and the pH value of the solution was adjusted to 9 with NaOH to obtain a foam enhancer for microfoam drilling fluid with a solid phase content of 25%.

[0062] The foam enhancer for microfoam drilling fluid prepared in Example 2 of the present invention is tested for results, and the test result is that the structural...

Embodiment 3

[0066] Dissolve 20g of cetyldimethylallyl ammonium chloride solution in 100g of clear water for use; dissolve 40g of acrylic acid and 40g of 2-acrylamido-2-methylpropanesulfonic acid in 800g of clear water for use ; Dissolve 2g of ammonium persulfate in 100g of clear water for later use;

[0067] Add 0.03 g of dodecyl mercaptan, the above cetyl dimethyl allyl ammonium chloride solution, acrylic acid and 2-acrylamido-2-methylpropanesulfonic acid solution into the reaction vessel and heat up to 70 ℃, then the above ammonium persulfate solution was added to the reaction system, the system was heated to 100 ℃ for 0.5 hours, and the pH value of the solution was adjusted to 10 with NaOH to obtain a foam enhancer for microfoam drilling fluid with a solid phase content of 10%. .

[0068] Structural testing of the foam enhancer for microfoam drilling fluid prepared in Example 3 of the present invention is carried out, and the test result is that the structural formula of the foam enha...

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PUM

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Abstract

The invention provides a foam enhancer for a micro-foam drilling fluid. The foam enhancer comprises a compound with a structure shown in formula I, the foam enhancer provided by the invention is relatively low in relative molecular mass; the compound has good surface activity and relatively low steric hindrance; the synergistic effect of the compound with a surfactant in the drilling fluid can berealized; the arrangement density and the wall thickness of micro-bubbles of the surfactant are increased, the air core sealing performance in the micro-bubbles is improved, the stability and the compression resistance of the micro-bubbles under the conditions of high temperature and high pressure are enhanced, air is prevented from escaping from the micro-bubbles under the condition of high pressure at the bottom of a well, and the leakage-proof performance of the micro-foam drilling fluid is improved. The invention further provides a preparation method and application of the micro-foam drilling fluid foam enhancer.

Description

technical field [0001] The invention relates to the technical field of microfoam drilling fluid, in particular to a foam enhancer for microfoam drilling fluid and its preparation method and application. Background technique [0002] At present, during the drilling process of low-pressure and leaky formations such as gas storages in domestic oil fields, due to the low formation pressure coefficient, foam drilling fluid is often used to reduce the density of drilling fluid and reduce the loss of drilling fluid. However, in conventional foam drilling fluids, due to the relatively large foam particle size, it is easy to affect the water supply efficiency of the mud pump, and it requires supporting gas injection equipment such as a compressor, and the drilling cost is relatively high. In response to these problems, some oilfields in China have successively carried out research on recyclable microbubble drilling fluids used under near-equilibrium conditions. It can effectively pr...

Claims

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Application Information

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IPC IPC(8): C08F220/56C08F220/58C08F226/02C08F220/06C09K8/035C09K8/24C09K8/38
CPCC09K8/035C09K8/24C09K8/38C08F220/56C08F220/06
Inventor 谢建宇刘光成卢国林史沛谦王中华吕跃滨
Owner 中石化石油工程技术服务有限公司
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