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Special lubricating grease for high-dropping-point extreme-pressure drill collar threads

A technology of lubricating grease and high dropping point, used in lubricating compositions, petroleum industry, etc., can solve the problems of easy separation, low extreme pressure and anti-wear properties, lack of thread protection, etc., and achieve good anti-wear and sealing properties , Enhance the effect of wear resistance and pressure bearing, excellent high and low temperature resistance

Inactive Publication Date: 2020-04-21
融润化工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] During the drilling of oil, natural gas and shale gas wells, the threaded joints of drill collars must be coated with a lubricating and protective material grease that can adapt to the depth of the well. With the exploration and exploitation of oil, natural gas and cleaner energy shale gas, The performance requirements of drill collar thread grease are mentioned to a higher level, so as to ensure that during the drilling process, the requirements for lubrication and protection performance of the drill collar thread parts can be met, and to ensure that the threaded joints have sufficient lubrication during drilling. Lubricity, extreme pressure, anti-wear, anti-oxidation, and anti-interference properties ensure that in the process of continuous high-pressure drilling, there will be no buckle due to poor protection, and ensure that the drill collar is dismantled after lifting the drill, and when the single piece is thrown, it will not stick Button to prolong the service life. At present, the drill collar thread grease commonly used in the domestic market has the following common features. First, all the drill collar thread grease is SY5198 drill thread grease, and the dropping point of SY5198 drill thread grease is low. At the same time, the standard stipulates that lithium lauryl stearate soap thickener has a dropping point of up to 200°C. Lithium soap grease is generally reversible and can only work below 120°C. It is not suitable for wells below 4000 meters, otherwise Oil and soap are easy to separate, the thread lacks protection, and it is easy to stick to the thread when pulling out the drill. Secondly, the evaporation rate of drill collar thread grease is low. GB / T7325 stipulates ≯2%, while SY5198≤4% is twice the difference, and the evaporation loss Large amount, low oil film retention, easy to stick when removing the drill collar, and the drill collar thread grease is mostly neutral, without inhibiting oxidation, free alkali after neutralizing the acidic body, low extreme pressure and wear resistance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A special lubricating grease for high dropping point extreme pressure drill collar threads, the weight percentage of each component of the special lubricating grease for high dropping point extreme pressure drill collar threads is as follows: 22% synthetic calcium sulfonate, 6% acetic acid, 4% dodecanoic acid , 1.5% micropowder boric acid, 1% calcium hydroxide, 28% refined paraffin base oil, 23.2% polyaolefin oil, 0.3% micropowder graphene, 6% antimony dialkyl dithiocarbamate, di-n-butyl disulfide Molybdenum oxysulfide carbamate 2%, zinc dialkyl dithiophosphate 2%, copper thiophosphate 4%, synthetic calcium sulfonate is a kind of synthetic calcium sulfonate with high alkali value, among them, synthetic calcium sulfonate is in Under the action of the acetic acid conversion agent, it is converted into calcium sulfonate and reacts with dodecanoic acid micropowder boric acid and calcium hydroxide to form calcium sulfonate salt, which increases the dropping point of grease an...

Embodiment 2

[0026] A special lubricating grease for high dropping point extreme pressure drill collar threads, the weight percentage of each component of the special lubricating grease for high dropping point extreme pressure drill collar threads is as follows: 27% synthetic calcium sulfonate, 4% acetic acid, 5% dodecanoic acid , micropowder boric acid 3%, calcium hydroxide 0.8%, refined paraffin base oil 26.1%, polyalkene oil 22%, micropowder graphene 0.1%, antimony dialkyl dithiocarbamate 3%, di-n-butyl disulfide Molybdenum oxysulfide carbamate 5%, zinc dialkyldithiophosphate 1%, copper thiophosphate 3%, synthetic calcium sulfonate is a synthetic calcium sulfonate with high alkalinity.

[0027] The present invention also provides a preparation method of high dropping point extreme pressure drill collar special lubricating grease: comprising the following steps:

[0028] S1): put all the high base value synthetic calcium sulfonate, part of the refined paraffin base oil and polyalpha olef...

Embodiment 3

[0033]A special lubricating grease for high dropping point extreme pressure drill collar threads, the weight percentage of each component of the special lubricating grease for high dropping point extreme pressure drill collar threads is as follows: 26.4% of synthetic calcium sulfonate, 5% of acetic acid, 3% of dodecanoic acid , micropowder boric acid 2%, calcium hydroxide 1.2%, refined paraffin base oil 23%, polyalkene oil 25%, micropowder graphene 0.4%, antimony dialkyl dithiocarbamate 5%, di-n-butyl disulfide Molybdenum oxysulfide carbamate 4%, zinc dialkyldithiophosphate 4%, copper thiophosphate 1%, synthetic calcium sulfonate is a synthetic calcium sulfonate with high alkalinity.

[0034] The present invention also provides a preparation method of special lubricating grease for high dropping point extreme pressure drill collar thread: comprising the following steps:

[0035] S1): put all the high base value synthetic calcium sulfonate, part of the refined paraffin base oil...

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Abstract

The invention provides special lubricating grease for high-dropping-point extreme-pressure drill collar threads. The special lubricating grease for the high-dropping-point extreme-pressure drill collar threads comprises the following components in percentage by weight: 22-27% of synthetic calcium sulfonate, 4-6% acetic acid, 3-5%of dodecanoic acid, 1.5-3% of micro-powder boric acid, 0.8-1.2% of calcium hydroxide, 23-28% of refined paraffin base oil, 22-25% of poly-alpha olefin oil, 0.1-0.4% of micro-powder graphene, 3-6% of antimony dialkyl dithiocarbamate, 2-5% of molybdenum oxysulfide di-n-butyldithiocarbamate, 1-4% of zinc dialkyl dithiophosphate and 1-4% of copper thiophosphate. The special lubricating grease for the high-dropping-point extreme-pressure drill collar threads has the advantages of extreme-pressure wear resistance, oxidation resistance, medium resistance, lubricating property and excellent protective performance, and can ensure the normal drilling requirement of a drill collar.

Description

technical field [0001] The invention relates to the technical field of lubricating materials, in particular to a special lubricating grease for high drop point extreme pressure drill collar threads. Background technique [0002] During the drilling of oil, natural gas and shale gas wells, the threaded joints of drill collars must be coated with a lubricating and protective material grease that can adapt to the depth of the well. With the exploration and exploitation of oil, natural gas and cleaner energy shale gas, The performance requirements of drill collar thread grease are mentioned to a higher level, so as to ensure that during the drilling process, the requirements for lubrication and protection performance of the drill collar thread parts can be met, and to ensure that the threaded joints have sufficient lubrication during drilling. Lubricity, extreme pressure, anti-wear, anti-oxidation, and anti-interference properties ensure that in the process of continuous high-pr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M169/04C10N30/06C10N30/10
CPCC10M169/044C10M2201/041C10M2201/062C10M2201/087C10M2205/0206C10M2205/183C10M2207/122C10M2207/128C10M2219/044C10M2219/068C10M2223/045
Inventor 郑奋勇
Owner 融润化工科技有限公司
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