Corrosion-resistant zero-shrinkage flame-retardant cable material

A flame-retardant cable and corrosion-resistant technology, used in the field of corrosion-resistant zero-shrinkage flame-retardant cable materials, can solve the problems affecting insulation life and performance, cable fatigue, and increased shrinkage, so as to increase corrosion resistance and insulation performance, enhance Corrosion resistance, enhanced micro-thickness effect

Inactive Publication Date: 2019-10-01
湖南华菱线缆股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the improvement of fire protection requirements, for some important places (such as nuclear power plants), it has been clearly required to use flame-retardant cables, and typical PVC-resistant cables release a large amount of gas when heated, and the overall performance shows severe expansion and foaming effects , the porous carbon layer formed by expansion has the function of heat insulation and oxygen insulation, which makes the ignition process more complicated
[0003] During the use of the cable, frequent power on-off switching will cause the temperature to fluctuate greatly. Due to the frequent changes in temperature, the stress and strain of the cable material are called temperature self-stress and temperature self-strain. From a mechanical point of view, it belongs to compressive stress and compression. The strain property is mainly due to the constraints of the terminal and joint space, which will lead to cable fatigue, increased plastic deformation, and increased shrinkage. Unlike ordinary "thermal expansion and contraction", thermal contraction is an irreversible process, so It will affect the insulation life and performance. The temperature change of the sheath material is smaller than that of the insulation sheath, but the fatigue creep will also affect the cable protection life to a certain extent.
[0004] At

Method used

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  • Corrosion-resistant zero-shrinkage flame-retardant cable material

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Experimental program
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Effect test

Embodiment 1

[0047] A corrosion-resistant zero-shrinkage flame-retardant cable material provided by the present invention comprises the following components in parts by weight:

[0048] 30 parts of chlorosulfonated polyethylene rubber;

[0049] 30 parts of polyethylene glycol propylene rubber;

[0050] 15 parts of polybenzoxazine;

[0051] 10 parts of hydroxyl epoxidized polybutadiene;

[0052] 12 parts of modified graphene oxide-polypyrrole composite;

[0053] 5 parts polyurea grease;

[0054] 3 parts of polymer initiator 4,4'-azobis(4-cyanovaleric acid), polymer initiator 2,2'-azobis[2-(2-imidazolin-2-yl)propane ]3 copies;

[0055] Nano (Mg-Co) / (Ga-Cr) polyelectrolyte layer embeds 5 parts of mercaptobenzothiazole sodium corrosion inhibitor;

[0056] 6 parts of sisal cellulose;

[0057] Reinforced Nanosphere B 4 C3 copies;

[0058] 3 parts of flame retardant magnesium hydroxide.

[0059] Wherein, the preparation method of modified graphene oxide-polypyrrole compound is:

[0060...

Embodiment 2

[0070] A corrosion-resistant zero-shrinkage flame-retardant cable material provided by the present invention comprises the following components in parts by weight:

[0071] 36 parts of chlorosulfonated polyethylene rubber;

[0072] 34 parts of polyethylene glycol propylene rubber;

[0073] 18 parts of polybenzoxazine;

[0074] 12.4 parts of hydroxyl epoxidized polybutadiene;

[0075] 15.5 parts of modified graphene oxide-polypyrrole composite;

[0076] 7.45 parts of polyurea grease;

[0077] 8.7 parts of polymer initiator 2,2'-azobis(N-butyl-2-methylpropionamide);

[0078] Nano-Ni / Ce polyelectrolyte layer embeds 6.5 parts of sodium 1-aminocyclopropanecarboxylate corrosion inhibitor;

[0079] Sisal cellulose 7.69 parts;

[0080] Reinforced nanospheres of TiC and ZrO 2 4 parts, including 1 part of TiC, ZrO 2 3 copies;

[0081] 5.02 parts of flame retardant calcium hydroxide.

[0082] Wherein, the preparation method of modified graphene oxide-polypyrrole compound is:

...

Embodiment 3

[0093] A corrosion-resistant zero-shrinkage flame-retardant cable material provided by the present invention comprises the following components in parts by weight:

[0094]40 parts of chlorosulfonated polyethylene rubber;

[0095] 40 parts of polyethylene glycol propylene rubber;

[0096] 20 parts of polybenzoxazine;

[0097] 15 parts of hydroxyl epoxidized polybutadiene;

[0098] 18 parts of modified graphene oxide-polypyrrole composite;

[0099] 10 parts of polyurea grease;

[0100] 10 parts of polymer initiator 1,1'-azobis(cyclohexane-1-carbonitrile);

[0101] Nano (Zn-Ca) / Al polyelectrolyte layer embeds 8 parts of sodium pyrovanadate corrosion inhibitor;

[0102] 9 parts of sisal cellulose;

[0103] Reinforced nanosphere TiB 2 5 copies;

[0104] 5 parts of flame retardant aluminum hydroxide.

[0105] Wherein, the preparation method of modified graphene oxide-polypyrrole compound is:

[0106] S1: Ultrasonicate 0.25g graphene oxide in 250ml distilled water until it...

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Abstract

The invention discloses a corrosion-resistant zero-shrinkage flame-retardant cable material, which is characterized by comprising the following components in parts by weight: 30-40 parts of chlorosulfonated polyethylene rubber; 30 to 40 parts of poly ethylene-propylene methylene rubber; 15-20 parts of polybenzoxazine; 10-15 parts of hydroxyl epoxidized polybutadiene; 12 to 18 parts of a modified graphene oxide- polypyrrole compound; 5-10 parts of polyurea grease; 6-10 parts of a polymer initiator; 5-8 parts of a nano polyelectrolyte layer embedding corrosion inhibitor; 6-9 parts of sisal cellulose; 3-5 parts of reinforced nano microspheres and 3-5 parts of a flame retardant. The cable material has the characteristics of good heat resistance and corrosion resistance, high antistatic performance and high flame retardance with zero deformation, reduces the risk of arc effect and short-circuit fire caused by the cable material, prolongs the service life, and improves the insulation safetyperformance.

Description

technical field [0001] The invention relates to the technical field of cable materials, in particular to a corrosion-resistant zero-shrinkage flame-retardant cable material. Background technique [0002] Wires and cables used for power transmission and information transmission are widely used in industrialization and information society. A large number of wires and cables are produced and put into use in my country every year. Since the preparation materials of the cable sheath layer and insulating layer are mostly organic polymers, which carry a large amount of fire load, once the interconnected cables catch fire due to electrical faults such as arcs and short circuits, the poisonous gas and heat released will seriously endanger people. health, and cable fires are also highly contagious. With the improvement of fire protection requirements, for some important places (such as nuclear power plants), it has been clearly required to use flame-retardant cables, and typical PVC-...

Claims

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Application Information

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IPC IPC(8): C08L23/34C08L23/16C08L61/34C08L47/00C08L79/04C08L75/02C08L1/02C08K13/06C08K9/00C08K3/04C08K9/10C08K5/47C08K3/38C08K3/22C08K3/14C08K5/17C08K3/24
CPCC08K2003/2206C08K2003/2224C08K2003/2227C08K2003/2244C08K2201/011C08L23/16C08L23/34C08L2201/02C08L2201/04C08L2201/08C08L2203/202C08L2205/035C08L61/34C08L47/00C08L79/04C08L75/02C08L1/02C08K13/06C08K9/00C08K3/042C08K9/10C08K5/47C08K3/38C08K3/22C08K5/175C08K3/14C08K3/24
Inventor 马辽林李华斌孙二杰胡湘华余雄
Owner 湖南华菱线缆股份有限公司
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