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A kind of odorless antistatic PVC composite material and preparation method thereof

A composite material and antistatic technology, applied in the ABS field, can solve problems such as poor heat resistance, easy deformation, and easy cracking, and achieve high toughening efficiency and rigid performance improvement

Active Publication Date: 2021-12-31
广东祺龙科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, PVC resin has the following defects: (1) poor heat resistance
PVC begins to thermally decompose at 120-130°C, releasing HCl gas, and the product is easy to soften and deform under the action of external force, which is not as stable as silica gel; (2) The impact resistance is poor
It is extremely brittle when impacted, and is far inferior to silicone in terms of softness and feel
Especially when PVC is used as a packaging material for electronic products, due to better requirements for odorlessness and antistatic properties, there are relatively large restrictions on the use of plasticizers and other agents that can improve mechanical properties

Method used

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  • A kind of odorless antistatic PVC composite material and preparation method thereof
  • A kind of odorless antistatic PVC composite material and preparation method thereof
  • A kind of odorless antistatic PVC composite material and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0027] An odorless, antistatic PVC composite material, comprising the following raw materials in parts by weight:

[0028]

[0029] The method of preparing the modifier comprises the steps of:

[0030] (1) 10 parts by weight of nano silica, 12 parts by weight of methyl methacrylate, 4 parts by weight of acrylic acid and 1 parts by weight 50 parts by weight and OP10 water emulsion were mixed to obtain a seed emulsion;

[0031] (2) To the seed emulsion were added 0.1 parts by weight of an initiator, heated to 70 ℃, the reaction incubated 40min, to obtain a polymerization solution;

[0032] (3) To the polymerization solution were added a 10 parts by weight of styrene, 5 parts by weight of butyl acrylate and 0.1 parts by weight of an initiator, heated to 70 ℃, the reaction incubated 40min, to give the secondary polymerization solution;

[0033] (4) To the polymerization solution was added the secondary breaking magnesium sulfate, washed, filtered and dried, to obtain the modifier.

...

Embodiment 2

[0045] An odorless, antistatic PVC composite material, comprising the following raw materials in parts by weight:

[0046]

[0047] The method of preparing the modifier comprises the steps of:

[0048] (1) 10 parts by weight of nano silica, 12 parts by weight of methyl methacrylate, 4 parts by weight of acrylic acid and 1 parts by weight 50 parts by weight and OP10 water emulsion were mixed to obtain a seed emulsion;

[0049] (2) To the seed emulsion were added 0.1 parts by weight of an initiator, heated to 60 ℃, the reaction incubated 30min, to obtain a polymerization solution;

[0050] (3) To the polymerization solution were added a 10 parts by weight of styrene, 5 parts by weight of butyl acrylate and 0.1 parts by weight of an initiator, heated to 60 ℃, the reaction incubated 30min, to give the secondary polymerization solution;

[0051] (4) To the polymerization solution was added the secondary breaking magnesium sulfate, washed, filtered and dried, to obtain the modifier.

...

Embodiment 3

[0063] An odorless, antistatic PVC composite material, comprising the following raw materials in parts by weight:

[0064]

[0065]

[0066] The method of preparing the modifier comprises the steps of:

[0067] (1) 10 parts by weight of nano silica, 12 parts by weight of methyl methacrylate, 4 parts by weight of acrylic acid and 1 parts by weight 50 parts by weight and OP10 water emulsion were mixed to obtain a seed emulsion;

[0068] (2) To the seed emulsion were added 0.1 parts by weight of an initiator, heated to 80 ℃, the reaction incubated 50min, to obtain a polymerization solution;

[0069] (3) To the polymerization solution were added a 10 parts by weight of styrene, 5 parts by weight of butyl acrylate and 0.1 parts by weight of an initiator, heated to 80 ℃, the reaction incubated 50min, to give the secondary polymerization solution;

[0070] (4) To the polymerization solution was added the secondary breaking magnesium sulfate, washed, filtered and dried, to obtain the ...

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Abstract

The invention relates to the technical field of nylon, in particular to an odorless antistatic PVC composite material and a preparation method thereof. The odorless antistatic PVC composite material comprises the following raw materials in parts by weight: PVC, odorless plasticizer, modifier, heat stabilizer , lubricants, antistatic agents, flame retardants, antifungal agents and antioxidants. The present invention prepares a core-shell particle modifier with nano-silica as the core, polymethyl methacrylate as the middle layer, and polystyrene as the outer shell through the emulsion polymerization method, which not only effectively solves the dispersion problem of nano-silica At the same time, taking advantage of the different properties of each layer of core-shell particles, when receiving impact, the layers are prone to deformation to different degrees to form cavities. Compared with MBS with a core-shell structure, it has a higher toughening efficiency, and With inorganic rigid particles as the core, PVC also has a better improvement in rigidity.

Description

Technical field [0001] Technical Field The present invention relates to ABS, PVC particularly relates to an odorless antistatic composite material and its preparation method. Background technique [0002] PVC was the world's largest output of general-purpose plastics, it is widely used. It is widely used in building materials, industrial products, daily necessities, floor coverings, tiles, leather, pipe, wire and cable, packaging films, bottles, foam materials, sealing materials, fibers and the like. As the industry widely used PVC resins having excellent physical and chemical properties, mainly in the following aspects: (1) corrosion resistance, chemical stability, in addition to the few solvents, at room temperature resistant PVC resin hydrochloric acid, 90% or less of sulfuric acid, 50-60% nitric acid and 20% caustic soda at any concentration; (2) excellent flame retardant properties and electrical insulation properties, pure PVC resin oxygen index up to 60%, are nonflammable ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08L51/10C08L23/06C08K13/02C08K5/19C08K5/20C08K5/098C08K3/32C08K3/22C08F292/00C08F220/14C08F285/00C08F212/08
CPCC08L27/06C08F292/00C08F285/00C08L2201/04C08L2205/06C08L2207/53C08L2205/03C08K2201/017C08K2003/323C08K2003/2227C08K2003/2224C08L51/10C08K13/02C08K5/19C08K5/20C08K5/098C08K3/32C08K3/22C08L23/06C08F220/14C08F212/08
Inventor 宁建华
Owner 广东祺龙科技有限公司