A hydrocracking method for producing chemical raw materials

A technology of hydrocracking and chemical raw materials, which is applied in the fields of hydroprocessing process, petroleum industry, hydrocarbon oil treatment products, etc., and can solve the problem that the yield of heavy naphtha is not enough to meet the product demand, and the yield of light naphtha or light hydrocarbons High quality, increased complexity of the device, etc., to achieve the effect of excellent tail oil quality, small device investment, and increased yield

Active Publication Date: 2021-12-17
CHINA PETROLEUM & CHEM CORP +1
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0015] (1) The yield of heavy naphtha under the one-pass process is not enough to meet the product demand of the enterprise;
[0016] (2) After ensuring that the yield of heavy naphtha meets the requirements of the enterprise, the yield of light naphtha or light hydrocarbons is relatively high;
[0018] (4) Circulating diesel oil or middle distillate oil to the second cracking reactor is equivalent to adding a section of hydrocracking unit, requiring additional reactors and circulating hydrogen systems, increasing the complexity of the device and increasing the investment

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A hydrocracking method for producing chemical raw materials
  • A hydrocracking method for producing chemical raw materials
  • A hydrocracking method for producing chemical raw materials

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] The raw materials in Table 1 are used as the feed, and the raw oil enters the hydrorefining reaction zone and the hydrocracking reaction zone successively for hydrogenation reaction in the presence of hydrogen, and the obtained reaction product is subjected to gas-liquid separation and fractionation to obtain pumice Naphtha fraction, heavy naphtha fraction, diesel oil fraction and tail oil fraction, the hydrofinishing reaction zone is filled with hydrofinishing catalyst RN-32V, and the hydrocracking reaction zone is filled with hydrocracking catalyst RHC-5. Process conditions, product distribution, and key product properties are listed in Tables 2 and 3.

[0054] As shown in Table 2 and Table 3, the hydrogen partial pressure in the hydrofinishing reaction zone is 15MPa, under the medium pressure of 11MPa hydrogen partial pressure in the hydrocracking reaction zone and the hydrocracking reaction temperature of 375°C, Middle East Wax After the oil is processed by the meth...

Embodiment 2

[0057] The raw materials in Table 1 are used as the feed, and the raw oil enters the hydrorefining reaction zone and the hydrocracking reaction zone successively for hydrogenation reaction in the presence of hydrogen, and the obtained reaction product is subjected to gas-liquid separation and fractionation to obtain pumice Naphtha fraction, heavy naphtha fraction, diesel oil fraction and tail oil fraction, the hydrofinishing reaction zone is filled with hydrofinishing catalyst RN-32V, and the hydrocracking reaction zone is filled with hydrocracking catalyst RHC-5. Process conditions, product distribution, and key product properties are listed in Tables 2 and 3.

[0058] As shown in Table 2 and Table 3, under the condition that the hydrogen partial pressure in the hydrocracking reaction zone is 8MPa and the hydrocracking reaction temperature is 375°C, after the Middle East wax oil is treated by the method in Example 2, the naphtha in the product+ The total yield of tail oil rea...

Embodiment 3

[0061] The raw materials in Table 1 are used as the feed, and the raw oil enters the hydrorefining reaction zone and the hydrocracking reaction zone successively for hydrogenation reaction in the presence of hydrogen, and the obtained reaction product is subjected to gas-liquid separation and fractionation to obtain pumice Naphtha fraction, heavy naphtha fraction, diesel oil fraction and tail oil fraction, the hydrofinishing reaction zone is filled with hydrofinishing catalyst RN-32V, and the hydrocracking reaction zone is filled with hydrocracking catalyst RHC-5. Process conditions, product distribution, and key product properties are listed in Tables 2 and 3.

[0062] As shown in Table 2 and Table 3, under the condition of low pressure of hydrogen partial pressure of 4MPa and cracking reaction temperature of 375°C in the hydrocracking reaction zone, after the Middle East wax oil is treated by the method in Example 3, naphtha+tail The total yield of oil reaches 67.6%, the sel...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

A hydrocracking method for producing chemical raw materials, the method comprising: in the presence of hydrogen, raw oil enters a hydrorefining reaction zone and a hydrocracking reaction zone successively for hydrogenation reaction, and the obtained reaction product is subjected to gas-liquid separation and After fractionation, light naphtha fraction, heavy naphtha fraction, diesel oil fraction and tail oil fraction are obtained, the hydrofinishing reaction zone is filled with a hydrofinishing catalyst, and the hydrocracking reaction zone is filled with a hydrocracking catalyst, wherein the The hydrogen partial pressure in the hydrocracking reaction zone is 20-80% of the hydrogen partial pressure in the hydrofinishing reaction zone, and the hydrogen partial pressure range in the hydrofinishing reaction zone is 12-20MPa. By adopting the method provided by the invention, the yield of heavy naphtha can be greatly increased, and at the same time, high-quality tail oil fractions can be produced.

Description

technical field [0001] The invention relates to the field of hydrocracking, in particular to a hydrocracking method for producing chemical raw materials. Background technique [0002] Ethylene is the basic raw material of petrochemical industry. With the development of the national economy, my country's ethylene production capacity has increased rapidly, but it still cannot meet the demand for ethylene in the domestic market, and about half of it depends on imports. Therefore, the development of petrochemical basic raw material olefin production increase technology is a direction of petrochemical industry development. [0003] Hydrocarbon steam cracking is the main means of producing ethylene. In the process of steam cracking to ethylene production, the cost of feedstock oil accounts for a large proportion of the total cost, generally more than 60%. Therefore, the optimal selection of feedstock oil is an important factor affecting the efficiency of ethylene plants. From a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C10G67/14
CPCC10G67/14C10G2300/70C10G2400/04
Inventor 赵阳赵广乐毛以朝龙湘云戴立顺
Owner CHINA PETROLEUM & CHEM CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products