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Out-of-the-box sapphire wafer cleaning process

A sapphire wafer and process technology, applied in the direction of cleaning methods using liquids, cleaning methods using tools, cleaning methods and utensils, etc., can solve the problem of affecting device luminous efficiency and life, high dislocation and defect density, height and size changes and other problems, to achieve the effect of eliminating secondary pollution, improving penetration, and preventing secondary adsorption

Active Publication Date: 2020-12-29
江苏京晶光电科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, sapphire has been widely used as the substrate material for making GaN-based LED chips on the market. However, due to the large lattice mismatch thermal expansion coefficient difference between nitride and sapphire, the nitride material grown on the substrate has dislocations and defects. The density is high, which affects the luminous efficiency and life of the device. The patterned substrate (PSS) technology can effectively reduce the dislocations and defects of epitaxial materials, and is widely used in the preparation of nitride devices.
[0003] In PSS production, if there is contamination or metal ions on the surface of the sapphire wafer, in the photolithography process, the impurities will cause uneven coating and poor wetting, resulting in unclear images, changes in height and size, and greatly reducing the quality of the finished product. Therefore, before the wafer is put into PSS patterned substrate production, it is necessary to add a pre-cleaning operation, and the cleaning quality of the sapphire wafer is particularly important.
[0004] The inventor found through investigation and research that when the sapphire wafers cleaned by the traditional cleaning process are used in PSS production, the yield rate of the finished product is only 70% at the highest. In order to improve the yield rate, it may need to be cleaned again

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] Step 1: Put the sapphire wafer that has been polished on one side into the process wafer box, and place the process wafer box with the wafer in the pure water tank;

[0059] Step 2: Put the sapphire wafer processed in step 1 into the first alkaline cleaning agent for cleaning, the concentration of the cleaning agent is 10wt%, the temperature in the tank is 55°C, and the wafer is rotated 90° after every ten times of throwing up and down before continuing Throwing, each cleaning time is 25min, a total of four times;

[0060] Step 3: Put the sapphire wafer processed in Step 2 into the first ultrapure water for ultrasonic rinsing, the temperature in the tank is 20°C, the ultrasonic intensity is 40KHz, and the cleaning time is 15 minutes;

[0061] Step 4: Put the sapphire wafer processed in Step 3 into the second cleaning agent solution for cleaning. The cleaning agent concentration is 10wt%, the temperature in the tank is 55°C, and the wafer is rotated 90° after every ten t...

Embodiment 2

[0071] Step 1: Put the sapphire wafer that has been polished on one side into the process wafer box, and place the process wafer box with the wafer in the pure water tank;

[0072] Step 2: Put the sapphire wafer processed in step 1 into the first alkaline cleaning agent for cleaning, the concentration of the cleaning agent is 20wt%, the temperature in the tank is 75°C, and the wafer is rotated 90° after every ten times of throwing up and down before continuing Throwing, each cleaning time is 15min, a total of four times;

[0073] Step 3: Put the sapphire wafer processed in Step 2 into the first ultrapure water for ultrasonic rinsing, the temperature in the tank is 30°C, the ultrasonic intensity is 40KHz, and the cleaning time is 35 minutes;

[0074] Step 4: Put the sapphire wafer processed in Step 3 into the second cleaning agent solution for cleaning. The cleaning agent concentration is 20wt%, the temperature in the tank is 75°C, and the wafer is rotated 90° after every ten t...

Embodiment 3

[0084] Step 1: Put the sapphire wafer that has been polished on one side into the process wafer box, and place the process wafer box with the wafer in the pure water tank;

[0085] Step 2: Put the sapphire wafer processed in step 1 into the first alkaline cleaning agent for cleaning, the concentration of the cleaning agent is 15wt%, the temperature in the tank is 65°C, and the wafer is rotated 90° after every ten times of throwing up and down before continuing Throwing, each cleaning time is 20min, a total of four times;

[0086] Step 3: Put the sapphire wafer processed in Step 2 into the first ultrapure water for ultrasonic rinsing, the temperature in the tank is 25°C, the ultrasonic intensity is 40KHz, and the cleaning time is 20 minutes;

[0087] Step 4: Put the sapphire wafer processed in step 3 into the second cleaning agent solution for cleaning. The cleaning agent concentration is 15wt%, the temperature in the tank is 65°C, and the wafer is rotated 90° after every ten t...

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PUM

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Abstract

The invention discloses a sapphire wafer cleaning process that can be used out of the box. It includes first using a cleaning agent and ultrapure water to ultrasonically wash the sapphire wafer multiple times to remove dirt and fine particles on the wafer surface; and secondly brushing the wafer to remove dirt and fine particles. Large particles on the surface of the wafer; then spray emulsifier on the wafer to control the adsorption state of the wafer surface; then use organic solvent to spray the wafer to avoid secondary adsorption of pollutants; finally use a spin dryer to dry the wafer, then let it stand and bake Dry. The invention can obtain a higher finished product yield by directly using the wafer during PSS production after cleaning the sapphire wafer.

Description

technical field [0001] The invention relates to the technical field of sapphire processing, in particular to a sapphire wafer cleaning process that can be used out of the box. Background technique [0002] At present, sapphire has been widely used as the substrate material for making GaN-based LED chips on the market. However, due to the large lattice mismatch thermal expansion coefficient difference between nitride and sapphire, the nitride material grown on the substrate has dislocations and defects. The high density affects the luminous efficiency and life of the device. The patterned substrate (PSS) technology can effectively reduce the dislocations and defects of epitaxial materials, and is widely used in the preparation of nitride devices. [0003] In PSS production, if there is contamination or metal ions on the surface of the sapphire wafer, in the photolithography process, the impurities will cause uneven coating and poor wetting, resulting in unclear images, change...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B08B3/08B08B3/12B08B3/02B08B1/00B08B7/04H01L21/02H01L33/00F26B11/02F26B3/30
CPCB08B3/08B08B3/12B08B3/02B08B7/04H01L21/02052H01L21/02041H01L33/007F26B11/02F26B3/30B08B1/12Y02P70/50
Inventor 高长有刘敏陈志敏张顼
Owner 江苏京晶光电科技有限公司
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