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Preparation method of in-situ ternary nanoparticle reinforced aluminum-based composite material

A nanoparticle and composite material technology, applied in the field of aluminum matrix composite material preparation, can solve the problems of low yield of binary nanoparticles, difficult to control the morphology of reinforcement phase, small size of nanoparticles, etc., and achieve good physical and chemical properties. , dimensional stability, good stability effect

Active Publication Date: 2020-05-29
JIANGSU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this type of technology is not perfect at present, mainly in the following aspects: (1) There are few reaction systems, most of which are concentrated in the Al-Ti-x (Al-Ti-O, Al-Ti-B) system, and the reaction of the system Higher temperature not only makes it difficult to control the morphology of the reinforced phase synthesized by reaction, but also seriously deteriorates the molten aluminum.
(2) The size of nanoparticles is small, and the specific surface area effect is very obvious, which makes it easier for particles to agglomerate and is difficult to disperse in aluminum melt
(3) The wettability of particles and matrix is ​​poor, and the yield of binary nanoparticles is low
At present, the nanoparticle-reinforced phase prepared by in-situ reaction technology is mainly concentrated in the unit, but there are few relevant literatures reporting the preparation of multi-component nanoparticle-reinforced aluminum matrix composites by in-situ melt reaction, so it is urgent to develop a new reaction system and method. To solve the problem of multi-component nanoparticle reaction preparation and low particle yield

Method used

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  • Preparation method of in-situ ternary nanoparticle reinforced aluminum-based composite material

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Embodiment 1

[0027] Preparation of 1vol.% ZrB 2 +1vol.%Al 2 o 3 +1wt.%TiB 2 Nanoparticles Reinforced Aluminum Matrix Composites

[0028] A two-step melt reaction method was used. The first step is to prepare 5wt.% TiB 2 Aluminum matrix composites with reinforced particles, using K 2 BF 6 and K 2 TiF 6 The powder is used as the reactant, and the reactant is dried in a drying oven to remove crystal water, the drying temperature is 200°C, and the drying time is 120 minutes. Then follow the Nano TiB 2 The particle mass fraction is 5% for composition design. Weigh 254.91 g of dried potassium fluoroborate and 246.10 g of potassium fluorotitanate, mix them evenly and wrap them in aluminum foil for use. Heat 886.25g of commercially pure aluminum to 850°C in a high-frequency induction heating furnace, press the mixed reaction salt into the melt with a graphite bell jar for reaction, and start the acoustic-magnetic coupling field at the same time, where the excitation current is 200A, th...

Embodiment 2

[0032] Preparation of 2vol.% ZrB 2 +2vol.%Al 2 o 3 +2wt.%TiB 2 Nanoparticles Reinforced Aluminum Matrix Composites

[0033] A two-step melt reaction method was used. The first step is to prepare 5wt.% TiB 2 Aluminum Matrix Composites with Reinforced Particles, in accordance with Nano TiB 2 The particle mass fraction is 5% for composition design. This composite material was used as a nanoparticle master alloy. The second step preparation preparation (ZrB 2 +Al 2 o 3 ) Nanoparticles reinforced AA6111-based composites: According to the nanoparticle (ZrB 2 +Al 2 o 3 ) volume fraction is 2% for composition design. Weigh AA6111 aluminum alloy 1218.64g, borax (Na 2 B 4 o 7 10H 2 O) 96.31g, potassium fluozirconate (K 2 ZrF 6 ) 224.89 g. Heat the weighed AA6111 aluminum alloy to 850°C in a high-frequency induction heating furnace to melt, and the weighed K 2 ZrF 6 Add small amounts of borax to the aluminum melt in multiple batches, and then turn on the acoustic-ma...

Embodiment 3

[0037] Preparation of 3vol% ZrB 2 +3vol%Al 2 o 3 +2wt%TiB 2 Nanoparticles Reinforced Aluminum Matrix Composites

[0038] A two-step melt reaction method was used. The first step is to prepare 5wt.% TiB 2 Aluminum Matrix Composites with Reinforced Particles, in accordance with Nano TiB 2 The particle mass fraction is 5% for composition design. This composite material was used as a nanoparticle master alloy. The second step preparation preparation (ZrB 2 +Al 2 o 3 ) Nanoparticles reinforced AA6111-based composites: According to the nanoparticle (ZrB 2 +Al 2 o 3) volume fraction is 3% for composition design. Weigh 1354.62g of AA6111 aluminum alloy, borax (Na 2 B 4 o 7 10H 2 O) 159.87g, potassium fluozirconate (K 2 ZrF 6 ) 373.30g. Heat the weighed AA6111 aluminum alloy to 850°C in a high-frequency induction heating furnace to melt, and the weighed K 2 ZrF 6 Add small amounts of borax and multiple batches to the aluminum melt, and then turn on the acousto-mag...

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Abstract

The invention provides a preparation method of an in-situ ternary nanoparticle reinforced aluminum-based composite material. According to the method, an in-situ reaction generation technology is adopted, powder containing a generation reinforcing particle forming element is used as a reactant, a low-frequency rotating magnetic field / ultrasonic field control technology is combined, and a nano-particle intermediate alloy is remelted to prepare the aluminum-based composite material. According to the ternary nanoparticle reinforced AA6016-based composite material prepared by the invention, the average particle size is 65 nm, and a comparison unit and biphase nanoparticles have an obvious thinning phenomenon. The room temperature mechanical property test shows that compared with a matrix aluminum alloy, the tensile strength of the ternary nanoparticle reinforced AA6016-based composite material prepared by the invention is improved by 27.46%-33.5%, the elongation rate is increased by 23.56%-30.89%, and the ternary nanoparticle reinforced AA6016-based composite material has great application potential in the fields such as aviation, aerospace, advanced weapons, automotive industry, precision instruments and other civil industries.

Description

technical field [0001] The invention provides a method for preparing an in-situ ternary nanoparticle-reinforced aluminum-based composite material, which belongs to the technical field of aluminum-based composite material preparation. Background technique [0002] In recent years, with the increasingly prominent problems of environmental pollution, energy shortage, and the increasing demand for lightweight automobile manufacturing, high-tech fields such as aerospace, rail transit, and new energy vehicles have huge demand potential for in-situ aluminum matrix composites, and the demand for The requirements for its comprehensive performance are also getting higher and higher. Therefore, further improving the comprehensive mechanical properties and forming processability of in-situ aluminum matrix composites has become an urgent problem to be solved. [0003] In-situ particle-reinforced aluminum-based composites are formed by adding solid powder reaction salts containing reinfo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/10C22C1/02C22C21/00C22C32/00C22F1/04
CPCC22C1/1036C22C21/00C22C32/0005C22F1/04B22F2999/00C22C32/0073C22C1/1052C22C1/1047C22C21/08B22F2202/05B22F2202/06C22C1/1068C22C32/0047
Inventor 赵玉涛靳利伟钱炜怯喜周高旭
Owner JIANGSU UNIV
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