Preparation method of in-situ ternary nanoparticle reinforced aluminum-based composite material
A nanoparticle and composite material technology, applied in the field of aluminum matrix composite material preparation, can solve the problems of low yield of binary nanoparticles, difficult to control the morphology of reinforcement phase, small size of nanoparticles, etc., and achieve good physical and chemical properties. , dimensional stability, good stability effect
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Embodiment 1
[0027] Preparation of 1vol.% ZrB 2 +1vol.%Al 2 o 3 +1wt.%TiB 2 Nanoparticles Reinforced Aluminum Matrix Composites
[0028] A two-step melt reaction method was used. The first step is to prepare 5wt.% TiB 2 Aluminum matrix composites with reinforced particles, using K 2 BF 6 and K 2 TiF 6 The powder is used as the reactant, and the reactant is dried in a drying oven to remove crystal water, the drying temperature is 200°C, and the drying time is 120 minutes. Then follow the Nano TiB 2 The particle mass fraction is 5% for composition design. Weigh 254.91 g of dried potassium fluoroborate and 246.10 g of potassium fluorotitanate, mix them evenly and wrap them in aluminum foil for use. Heat 886.25g of commercially pure aluminum to 850°C in a high-frequency induction heating furnace, press the mixed reaction salt into the melt with a graphite bell jar for reaction, and start the acoustic-magnetic coupling field at the same time, where the excitation current is 200A, th...
Embodiment 2
[0032] Preparation of 2vol.% ZrB 2 +2vol.%Al 2 o 3 +2wt.%TiB 2 Nanoparticles Reinforced Aluminum Matrix Composites
[0033] A two-step melt reaction method was used. The first step is to prepare 5wt.% TiB 2 Aluminum Matrix Composites with Reinforced Particles, in accordance with Nano TiB 2 The particle mass fraction is 5% for composition design. This composite material was used as a nanoparticle master alloy. The second step preparation preparation (ZrB 2 +Al 2 o 3 ) Nanoparticles reinforced AA6111-based composites: According to the nanoparticle (ZrB 2 +Al 2 o 3 ) volume fraction is 2% for composition design. Weigh AA6111 aluminum alloy 1218.64g, borax (Na 2 B 4 o 7 10H 2 O) 96.31g, potassium fluozirconate (K 2 ZrF 6 ) 224.89 g. Heat the weighed AA6111 aluminum alloy to 850°C in a high-frequency induction heating furnace to melt, and the weighed K 2 ZrF 6 Add small amounts of borax to the aluminum melt in multiple batches, and then turn on the acoustic-ma...
Embodiment 3
[0037] Preparation of 3vol% ZrB 2 +3vol%Al 2 o 3 +2wt%TiB 2 Nanoparticles Reinforced Aluminum Matrix Composites
[0038] A two-step melt reaction method was used. The first step is to prepare 5wt.% TiB 2 Aluminum Matrix Composites with Reinforced Particles, in accordance with Nano TiB 2 The particle mass fraction is 5% for composition design. This composite material was used as a nanoparticle master alloy. The second step preparation preparation (ZrB 2 +Al 2 o 3 ) Nanoparticles reinforced AA6111-based composites: According to the nanoparticle (ZrB 2 +Al 2 o 3) volume fraction is 3% for composition design. Weigh 1354.62g of AA6111 aluminum alloy, borax (Na 2 B 4 o 7 10H 2 O) 159.87g, potassium fluozirconate (K 2 ZrF 6 ) 373.30g. Heat the weighed AA6111 aluminum alloy to 850°C in a high-frequency induction heating furnace to melt, and the weighed K 2 ZrF 6 Add small amounts of borax and multiple batches to the aluminum melt, and then turn on the acousto-mag...
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