Antistatic water-based adhesive for vulcanized shoes and preparation method thereof
A technology of water-based adhesives and antistatic agents, which is applied in the directions of non-polymer organic compound adhesives, polymer adhesive additives, non-polymer adhesive additives, etc. Low, poor antistatic properties, etc., to achieve the effect of expanding the application field, good adhesion strength, and not easy to crack
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Embodiment 1
[0030] A kind of antistatic water-based adhesive for vulcanized shoes
[0031] Prepared by:
[0032] S10, dry 1.2kg of soybean fiber at a temperature of 105°C for 3.5h, then crush it to 100 mesh, then mix it with 3.0kg of tapioca starch, and add 2.2kg of isobutyl dicyanoacrylate at a rate of 1000r / min Stir magnetically for 5 minutes, and then sonicate for 30 minutes at a temperature of 65°C to obtain composition A;
[0033] S20, dissolve 1.22kg of aluminum sulfate in 20kg of deionized water, then add 6.5kg of water-based polyurethane dispersion, stir and disperse at a rate of 250r / min for 10min at a temperature of 80°C, then add S10 composition A and 0.75kg of polyurethane Ethylene glycol and 0.25kg sodium carboxymethylcellulose were stirred at a speed of 850r / min for 15min to obtain composition B;
[0034] Among them, aluminum sulfate is octadecahydrate.
[0035] Add 0.34kg diaminodiphenylmethane, 0.15kg vinyl triamine and 0.08kg antistatic agent to composition B in S30 an...
Embodiment 2
[0039] A kind of antistatic water-based adhesive for vulcanized shoes
[0040] Prepared by:
[0041] S10, 1.8kg of soybean fiber was dried at 135°C for 4.5h, then crushed to 200 mesh, then mixed with 3.8kg of tapioca starch, and 2.6kg of isobutyl dicyanoacrylate was added at a rate of 2000r / min Stir magnetically for 8 minutes, and then sonicate for 30 minutes at a temperature of 85°C to obtain composition A;
[0042] S20, dissolve 1.44kg of aluminum sulfate in 40kg of deionized water, then add 8.5kg of water-based polyurethane dispersion, stir and disperse at a speed of 450r / min for 15min at a temperature of 85°C, and then add S10 composition A and 1.05kg of polyurethane dispersion Ethylene glycol and 0.45kg sodium carboxymethylcellulose were stirred at a speed of 1250r / min for 20min to obtain composition B;
[0043] Among them, aluminum sulfate is octadecahydrate.
[0044] Add 0.44kg diaminodiphenylmethane, 0.25kg vinyltriamine and 0.20kg antistatic agent to composition B in...
Embodiment 3
[0048] A kind of antistatic water-based adhesive for vulcanized shoes
[0049] Prepared by:
[0050] S10, 1.3kg of soybean fiber was dried at 109°C for 4.5h, then crushed to 120 mesh, then mixed with 3.2kg of tapioca starch, and 2.3kg of isobutyl dicyanoacrylate was added at a rate of 1200r / min Stir magnetically for 6 minutes, then sonicate for 30 minutes at a temperature of 70°C to obtain composition A;
[0051] S20, dissolve 1.28kg of aluminum sulfate in 24kg of deionized water, then add 6.9kg of water-based polyurethane dispersion, stir and disperse at a speed of 300r / min for 11min at a temperature of 81°C, then add S10 composition A and 0.81kg of polyurethane Ethylene glycol and 0.29kg sodium carboxymethylcellulose were stirred at a rate of 950r / min for 16min to obtain composition B;
[0052] Among them, aluminum sulfate is octadecahydrate.
[0053] Add 0.38kg of diaminodiphenylmethane, 0.19kg of ethylenetriamine and 0.10kg of antistatic agent to composition B in S30 an...
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