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Environmentally friendly silane-modified adhesive and its preparation method and application

A silane modification and adhesive technology, applied in the direction of adhesives, polyether adhesives, adhesive types, etc., can solve the problems of high TVOC value, unable to meet the technical requirements of lightweight automobiles, and not environmentally friendly.

Active Publication Date: 2021-10-22
HUBEI HUITIAN NEW MATERIALS STOCK CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These two glues have good adhesion to metal floors and wooden floors, but have no adhesion to PVC floors, PP floors and other (composite) material floors, and cannot meet the technical requirements of lightweight development of automobiles.
In addition, neoprene solvent and water-based acrylic white latex have high TVOC value and are not environmentally friendly

Method used

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  • Environmentally friendly silane-modified adhesive and its preparation method and application
  • Environmentally friendly silane-modified adhesive and its preparation method and application
  • Environmentally friendly silane-modified adhesive and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] This embodiment provides an environmentally friendly silane-modified adhesive, which is prepared from the following raw materials in parts by weight: 30 parts of silane-modified polymer S303H, 10 parts of diisononyl phthalate (DINP), 10 parts of calcium oxide, 45 parts of nano calcium carbonate, 0.5 parts of vinyl trimethoxysilane, 2 parts of propylene glycol block polyether (L64, HBL=13), 0.5 parts of γ-aminopropyl trimethoxysilane, 0.5 parts of N - β-aminoethyl-γ-aminopropyltrimethoxysilane, 0.2 part of light stabilizer TINUVIN 329, 0.2 part of UV absorber TINUVIN 770DF and 0.5 part of chelated tin.

[0050] The preparation method of the environment-friendly silane-modified adhesive of the present embodiment comprises the following steps:

[0051] S1. Weigh each raw material according to the composition of the environment-friendly silane-modified adhesive.

[0052]S2, add silane-modified polymer S303H, DINP, calcium oxide, propylene glycol block polyether L64, light ...

Embodiment 2

[0055] This embodiment provides an environmentally friendly silane-modified adhesive, which is prepared from the following raw materials in parts by weight: 20 parts of silane-modified polymer SAT350, 20 parts of polyether polyol, 30 parts of calcium oxide, 25 parts Nano-calcium carbonate, 0.2 parts of vinyltrimethoxysilane, 1 part of fatty alcohol polyoxyethylene ether (MOA-7, HLB=12-13), 1 part of N-β-aminoethyl-γ-aminopropyl trimethoxy base silane, 0.2 part of light stabilizer TINUVIN 329, 0.2 part of UV absorber TINUVIN 770DF and 0.5 part of chelated tin.

[0056] The preparation method of the environment-friendly silane-modified adhesive of the present embodiment comprises the following steps:

[0057] S1. Weigh each raw material according to the composition of the environment-friendly silane-modified adhesive.

[0058] S2, add silane-modified polymer SAT350, polyether polyol, calcium oxide, fatty alcohol polyoxyethylene ether (MOA-7), light stabilizer TINUVIN 329, and u...

Embodiment 3

[0061] This embodiment provides an environmentally friendly silane-modified adhesive, which is prepared from the following raw materials in parts by weight: 40 parts of silane-modified polymer 12000DS, 10 parts of phenyl sulfonate, 20 parts of calcium oxide, 25 parts of heavy calcium carbonate (particle size 800-3000 mesh), 0.1 part of p-toluenesulfonyl isocyanate, 3 parts of polyoxyethylene sorbitan monolaurate (T-20, HLB=15), 0.5 part of γ - Aminopropyltrimethoxysilane, 0.5 part of γ-(2,3-glycidoxy) propyltrimethoxysilane, 0.2 part of light stabilizer TINUVIN 329, 0.2 part of UV absorber TINUVIN 770DF and 0.5 part of di Butyl tin dilaurate.

[0062] The preparation method of the environment-friendly silane-modified adhesive of the present embodiment comprises the following steps:

[0063] S1. Weigh each raw material according to the composition of the environment-friendly silane-modified adhesive.

[0064] S2, the silane modified polymer 12000DS, alkyl sulfonate phenyl est...

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Abstract

The invention relates to an environment-friendly silane-modified adhesive and its preparation method and application. The environment-friendly silane-modified adhesive is mainly composed of a specific ratio of silane-modified polymer, plasticizer, calcium oxide, filler, It is prepared from nonionic surfactant, coupling agent and catalyst. The environment-friendly silane-modified adhesive has the characteristics of fast deep-layer curing speed, good water resistance and low TVOC value, and can meet the bonding requirements of PVC floor, PP floor and other (composite) material floors in the installation process as a whole. skills requirement.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to an environment-friendly silane-modified adhesive, a preparation method and application thereof. Background technique [0002] Lightweight has gradually become the mainstream trend of automobile development. Because wooden floor, PVC floor, PP floor and other (composite) material floors can effectively reduce the weight of the car body, and have good sound insulation, comfort, thermal insulation and other properties, they gradually replace metal floors and become the mainstream of car decoration. Faced with the increasingly abundant floor materials, how to achieve firm bonding of these materials has become a major problem in the development of lightweight automobiles. [0003] At present, neoprene solvent glue or water-based acrylic white latex is mainly used for bonding automobile floors and floor leather. These two glues have good adhesion to metal floors and wooden floors, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J175/04C09J171/02C09J11/04C09J11/06C09J11/08
CPCC08K2003/2206C08K2003/265C08K2201/003C08K2201/011C09J11/04C09J11/06C09J11/08C09J171/02C09J175/04C08L71/02C08K13/02C08K3/22C08K5/12C08K3/26C08K5/544C08K5/5425C08K5/43
Inventor 饶磊赵瑞王翠花明安顺赵勇刚章锋
Owner HUBEI HUITIAN NEW MATERIALS STOCK CO LTD
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