A kind of magnesium alloy material for oil and gas development and its preparation method and application

A technology of oil and gas exploitation and magnesium alloy, which is applied in the field of magnesium alloy materials and its preparation for oil and gas exploitation. It can solve the problems that the type and quantity of the second phase cannot be accurately predicted, prolong the supply cycle, and affect the progress of the project, so as to achieve uniform and accurate degradation. Controllable, improve efficiency and safety, ensure safety and efficiency

Active Publication Date: 2022-01-04
GRIMAT ENG INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are several problems: 1. The strength of non-rare earth magnesium alloys decreases rapidly or even softens at downhole temperatures, and the degradation rate cannot be precisely controlled; 2. Conventional rare earth magnesium alloys have high strength and high temperature resistance, but their production costs are high, and the addition of alloys The second phase generated by the elements has solid solubility in the matrix, and there is dissolution or precipitation during the preparation and deformation process. The type and quantity of the second phase cannot be accurately predicted, resulting in the degradation rate of the alloy cannot be accurately predicted and controlled; 3. In Oil and gas wells are prone to engineering accidents when fracturing tools are required to provide effective interlayer isolation due to low strength, softening or degrading too quickly to achieve effective isolation, or when fracturing tools are required to degrade quickly to achieve oil and gas production, due to strength High, the degradation is too slow and seriously affects the progress of the project
4. The above-mentioned fracturing tool materials are affected by the tissue composition, and it is impossible to establish accurate models of mechanical properties and degradation rates. They can only be used in a specific oil and gas environment. New oil and gas field environment applications require new test verification. The versatility is not strong, the delivery cycle is prolonged, the production efficiency is affected, and the production cost is increased

Method used

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  • A kind of magnesium alloy material for oil and gas development and its preparation method and application
  • A kind of magnesium alloy material for oil and gas development and its preparation method and application
  • A kind of magnesium alloy material for oil and gas development and its preparation method and application

Examples

Experimental program
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Effect test

Embodiment 1

[0047] A variety of as-cast Mg-MM-1%Sn alloys were prepared, and the prepared components are shown in Table 1. The preparation method is: using pure magnesium ingot, cerium-rich mixed rare earth, pure Sn powder, pure Ti powder, pure Cu powder, pure Ni powder, pure Fe powder as raw materials, pure Sn powder, pure Ti powder, pure Cu powder, pure Ni powder , pure Fe powder purity is greater than 99.99%, particle size is less than 10um, carries out material preparation respectively by the weight percent of the composition of the magnesium alloy of Table 1;

[0048] The magnesium ingot is completely melted under the protection of protective gas, and the temperature is controlled at 760°C; the cerium-rich mixed rare earth, cerium-rich mixed rare earth, pure Sn powder, pure Ti powder, pure Cu powder, pure Ni powder, pure Fe powder are mixed at 200 After 2 hours of heat preservation in the preheating furnace at ℃, the cerium-rich mixed rare earth is first added to the magnesium melt f...

Embodiment 2

[0059] According to the composition and method of the present invention, three kinds of ingots have been prepared, which are respectively: cerium-rich mixed rare earth (Ce: 45wt.%; La: 35wt.%; Nd: 10wt.%; Pr: 10wt.%): 5wt .%, Sn: 2wt.%, 0.5wt.% Ti, the balance Mg; cerium-rich mixed rare earth (Ce: 45wt.%; La: 35wt.%; Nd: 10wt.%; Pr: 10wt.%): 5wt .%, Sn: 1wt.%, 0.5wt.% Ti, the balance Mg; cerium-rich mixed rare earth (Ce: 45wt.%; La: 35wt.%; Nd: 10wt.%; Pr: 10wt.%): 5wt .%, 0.5wt.% Ti, balance Mg;

[0060] Pure magnesium ingot, cerium-rich mixed rare earth, pure Sn powder, pure Ti powder, pure Cu powder, pure Ni powder, pure Fe powder as raw materials, pure Sn powder, pure Ti powder, pure Cu powder, pure Ni powder, pure Fe powder The purity is greater than 99.99%, and the particle size is less than 10um, and the materials are prepared according to the weight percentage of the above-mentioned magnesium alloy composition;

[0061] The magnesium ingot is completely melted under ...

Embodiment 3

[0067] An oil field needs soluble bridge plugs, and the oil and gas well environment is: temperature 120°C, pressure 70Mpa, Cl - The ion content is 3%, the oil-water ratio is 80%, and the time difference between before and after the bridge plug is put into the well is about 36h. The strength of the bridge plug is required to be greater than 250MPa. Under this environment, the bridge plugs that are run first and then run into the well will degrade synchronously 12 hours after the last bridge plug is put into the well.

[0068] According to the oil field conditions and actual application requirements, ingots with alloy components of three components were prepared, respectively:

[0069] 1) Proportional Ce: 50wt.%; La: 30wt.%; Nd: 15wt.%; Pr: 5wt.%; mix the metal powder evenly to obtain cerium-rich mixed rare earth;

[0070] Using pure magnesium ingot, cerium-rich mixed rare earth, pure Sn powder, and pure Ni powder as raw materials, cerium-rich mixed rare earth: 4.5wt.%, Sn: 0.5...

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Abstract

The invention discloses a magnesium alloy material for oil and gas development, a preparation method and application thereof, which belong to the technical field of nonferrous metals. The composition content of the magnesium alloy material is: cerium-rich mixed rare earth: 0.5-25wt.%, Sn: 0-10wt.%; Fe: 0-10wt.%, Ti: 0-10wt.%; Ni: 0-10wt.% .%; Cu: 0~10wt.%; the balance is Mg. The tools made of the magnesium alloy material of the present invention can be used in oil wells, shale gas, and oil and gas wells for oil and gas production downhole operations, and the tools include soluble bridge plugs, soluble ball seats, fracturing balls, plugging balls, darts, etc. . The material can precisely control and predict the evolution of its mechanical properties and dissolution rate in the oil and gas well environment, establish an accurate prediction model, and directly select the most suitable composition and preparation and deformation methods for different shale oil and gas well environments, greatly shortening the delivery time cycle, ensure the safety and efficiency of oil and gas extraction, and reduce the risk and cost of production accidents.

Description

technical field [0001] The invention belongs to the technical field of nonferrous metals, and in particular relates to a magnesium alloy material for oil and gas development, a preparation method and application thereof. Background technique [0002] Because the standard electrode potential of magnesium is as low as -2.37V, the corrosion potential is also very low in other media (such as 0.5% NaCl solution, seawater, etc.), about -1.45V to -1.6V. In humid environment and Cl - Corrosion is highly susceptible to the conditions present, so degradation can be achieved in shale gas / oil environments. Fracturing tools such as bridge plugs, ball seats, and fracturing balls made of magnesium alloy materials can provide reliable interlayer isolation during fracturing operations such as shale oil and gas exploitation. Dissolution, no need for wellbore intervention, to achieve full-bore production of the wellbore. [0003] The oil well environment is relatively complex, including: te...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C23/06C22C1/02C22F1/06
CPCC22C23/06C22C1/02C22F1/06
Inventor 袁家伟李婷张奎李兴刚李永军马鸣龙石国梁穆桐
Owner GRIMAT ENG INST CO LTD
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