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A high-density nano-twinned high-performance nickel-aluminum-bronze alloy plate and its preparation method

A technology of alloy plate and nickel-aluminum-bronze, which is applied in the direction of metal rolling to achieve the effects of small grain size, rich application scenarios, and improved comprehensive mechanical properties

Active Publication Date: 2021-09-24
SHANGHAI JIAOTONG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, relying on deformation heat treatment to introduce high-density ultra-fine annealing twins to improve the comprehensive mechanical properties of materials is rarely used in nickel-aluminum-bronze alloys.

Method used

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  • A high-density nano-twinned high-performance nickel-aluminum-bronze alloy plate and its preparation method
  • A high-density nano-twinned high-performance nickel-aluminum-bronze alloy plate and its preparation method
  • A high-density nano-twinned high-performance nickel-aluminum-bronze alloy plate and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A kind of as-cast nickel-aluminum bronze is the step of preparing high-density nano-twinned high-performance nickel-aluminum bronze alloy plate as raw material as follows:

[0034] Step 1, high-temperature solution treatment: the as-cast nickel-aluminum-bronze alloy with an initial thickness of 30mm is placed in a heat treatment furnace at 930°C for 1 hour, and the heating medium is air. Obtain a homogeneous first semi-finished sheet, the resulting structure is Cu 3 Al-based β-phase solid solution and a small amount of fine k-precipitated phase;

[0035] Step 2, strong deformation symmetrical continuous hot rolling: the first semi-finished plate obtained after step 1 solution treatment is warmed in the air for 15 seconds, and then sent to a rolling mill for strong deformation symmetrical continuous hot rolling. The total reduction of symmetrical rolling is 24mm, which is divided into three passes, and the reductions of each pass are 15mm, 6mm and 3mm respectively. The...

Embodiment 2

[0039] The steps of preparing a high-density nano-twinned high-performance nickel-aluminum-bronze alloy sheet for corrosion-resistant working conditions are as follows:

[0040] Step 1, high-temperature solution treatment: place the as-cast nickel-aluminum-bronze alloy with an initial thickness of 60 mm in a heat treatment furnace at 950° C. for 40 minutes, and the heating medium is air. Obtain a homogeneous first semi-finished sheet, the resulting structure is Cu 3 Al-based β-phase solid solution;

[0041] Step 2, strong deformation symmetrical continuous hot rolling: the first semi-finished plate obtained after step 1 solution treatment is warmed in the air for 20 seconds, and then sent to a rolling mill for strong deformation symmetrical continuous hot rolling. The total reduction of symmetrical rolling is 48mm, which is divided into three passes, and the reductions of each pass are 30mm, 12mm and 6mm respectively. The initial temperature of the roll is room temperature, ...

Embodiment 3

[0045] A method for preparing a high-density nano-twinned high-performance nickel-aluminum-bronze alloy plate, the steps of which are basically the same as in Example 2, except that the time for the medium-temperature short-term heat treatment in step 4 is adjusted to 2.5 minutes. The tensile strength of the obtained board exceeds 1020MPa, the yield strength exceeds 890MPa, and the elongation at break exceeds 15%. The TEM microstructure of the high-density nanotwins obtained by the plate is shown in the attached figure 2 shown in .

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Abstract

The invention relates to a preparation method of nano-twinned high-performance nickel-aluminum bronze alloy. This method first carries out high-temperature solution treatment, and heat-preserves the original material of nickel-aluminum-bronze alloy at 920°C-950°C for 1-2h, and controls the high-temperature structure to be Cu 3 Al-based β phase solid solution and a small amount of fine k precipitated phase. Afterwards, carry out symmetrical continuous hot rolling with strong deformation, asymmetric medium temperature rolling with small deformation, and short-term heat treatment at 700°C to 800°C after deformation. After different heat treatment processes, the obtained structures are equiaxed face-centered cubic Cu-based solid solution α phase, Cu 3 Al-based martensite β'-phase dual-phase structure, and intermetallic compound k-phase dispersedly distributed. The ratio and grain size of each phase can be adjusted according to the rolling and heat treatment process to obtain mechanical properties and physical and chemical properties suitable for different working scenarios. The grain size of α phase and β' phase can be refined to about 300nm. In the α phase of the material, the annealed twin boundary accounts for 30% to 80% of the entire interface, and the width of the twin crystal layer is 30nm to 300nm. The material has a yield strength of not less than 800MPa, a tensile strength of up to 1150MPa, and an elongation at break of not less than 14%. Compared with the prior art, the method of the invention can greatly improve the comprehensive mechanical properties of the nickel-aluminum-bronze alloy, has simple process, is easy to implement, has low production cost, and can realize the preparation of bulk materials in large quantities.

Description

technical field [0001] The invention belongs to the technical field of copper alloy material processing, and in particular relates to a high-strength and high-plasticity nickel-aluminum bronze alloy plate and a preparation method thereof. Background technique [0002] Compared with the traditional binary aluminum bronze alloy, the strength, wear resistance and corrosion resistance of the nickel aluminum bronze alloy have been further improved due to the addition of alloying elements such as iron and nickel. As a copper-based alloy structural material, nickel-aluminum bronze has excellent performances that cannot be replaced by traditional steel materials in terms of electrical conductivity, thermal conductivity, and corrosion resistance. At present, nickel-aluminum-bronze alloys have been widely used in important parts such as propellers, propellers, and valves in the aviation industry and marine industry, and can also be used to make high-strength wear-resistant parts that ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22F1/08B21B1/26
CPCB21B1/26C22F1/002C22F1/08
Inventor 单爱党付立铭马硕
Owner SHANGHAI JIAOTONG UNIV
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