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Nickel hydroxide/cobalt disulfide composite material and preparation method and application thereof

A technology of cobalt disulfide and nickel hydroxide, which is applied in the manufacture of hybrid/electric double layer capacitors and electrodes of hybrid capacitors, can solve the problems of unsatisfactory electrochemical properties and flexible comprehensive effects of electrode materials, and achieve excellent electrochemical properties, Good application value, high conductivity effect

Active Publication Date: 2020-07-10
HARBIN INSTITUTE OF TECHNOLOGY SHENZHEN (INSTITUTE OF SCIENCE AND TECHNOLOGY INNOVATION HARBIN INSTITUTE OF TECHNOLOGY SHENZHEN)
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of the present invention is to provide a nickel hydroxide / cobalt disulfide composite material and its preparation method and application, aiming to solve the technical problem that the electrochemical performance and flexible comprehensive effect of the existing electrode materials are not ideal

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  • Nickel hydroxide/cobalt disulfide composite material and preparation method and application thereof
  • Nickel hydroxide/cobalt disulfide composite material and preparation method and application thereof
  • Nickel hydroxide/cobalt disulfide composite material and preparation method and application thereof

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preparation example Construction

[0022] On the one hand, the embodiment of the present invention provides a kind of preparation method of nickel hydroxide / cobalt disulfide composite material, and this preparation method comprises the following steps:

[0023] S01: providing carbon cloth, and growing cobalt-based metal-organic framework materials on the surface of the carbon cloth;

[0024] S02: placing the carbon grown with the cobalt-based metal-organic framework material in an alcohol solution containing a sulfur source, and performing heat treatment to generate cobalt disulfide nanorods on the surface of the carbon cloth;

[0025] S03: Deposit nickel hydroxide on the surface of the cobalt disulfide nanorods to obtain the nickel hydroxide / cobalt disulfide composite material.

[0026] The preparation method of the nickel hydroxide / cobalt disulfide composite material provided by the embodiment of the present invention uses carbon cloth as a carrier, first grows a cobalt-based metal-organic framework material ...

Embodiment 1

[0043] (1) Materials and reagents

[0044] Carbon cloth (WOS1009) was purchased from Taiwan Carbon Energy Co., Ltd., 2-methylimidazole, cobalt nitrate hexahydrate, thioacetamide (TAA), ethanol, etc. were of analytical grade and purchased from Aladdin Reagents.

[0045] (2) Instruments and equipment

[0046] S-4800 field emission scanning electron microscope, Hitachi, Japan; KO-600BD CNC ultrasonic cleaner, Kunshan Ultrasonic Instrument Co., Ltd.; CHI 760E electrochemical workstation, Shanghai Chenhua Co., Ltd. DZF-6051 vacuum drying oven, Shanghai Jinghong Test Equipment Co., Ltd.

[0047] (3) Nickel hydroxide / cobalt disulfide composite (CoS 2 @Ni(OH) 2 )Synthesis

[0048] 1. Dissolve 0.4mol of 2-methylimidazole aqueous solution in 40mL of deionized water, dissolve 0.25mol of cobalt nitrate hexahydrate in 40ml of deionized water, mix the two evenly to obtain a mixed solution, and put a piece of clean carbon Put the cloth (1cm*2cm) in the above mixed solution, let it stand...

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Abstract

The invention belongs to the technical field of capacitor materials, and particularly relates to a nickel hydroxide / cobalt disulfide composite material and a preparation method and application thereof. The preparation method of the nickel hydroxide / cobalt disulfide composite material comprises the following steps: providing carbon cloth, and growing a cobalt-based metal organic framework materialon the surface of the carbon cloth; putting the carbon cloth on which the cobalt-based metal organic framework material grows into an alcoholic solution containing a sulfur source, and carrying out heating treatment to generate cobalt disulfide nanorods on the surface of the carbon cloth; and then depositing nickel hydroxide on the surface of the cobalt disulfide nanorod, and obtaining the nickelhydroxide / cobalt disulfide composite material. The nickel hydroxide / cobalt disulfide composite material obtained by the preparation method has very good electrochemical performance and flexibility, and has relatively high energy density, long cycle performance and very good flexibility when being used as an electrode material in a flexible supercapacitor, so that the nickel hydroxide / cobalt disulfide composite material has very good application value.

Description

technical field [0001] The invention belongs to the technical field of capacitor materials, and in particular relates to a nickel hydroxide / cobalt disulfide composite material and a preparation method and application thereof. Background technique [0002] The rapid development of portable electronic products and the increasing demand for energy systems mean that energy storage systems play more and more roles in human life. In recent years, as an emerging energy storage device, supercapacitors have the advantages of high power density, fast charge and discharge time, and long cycle life. However, their low energy density restricts their further development. [0003] Traditional electric double layer capacitors and pseudocapacitors have low specific capacity. Hybrid capacitors are supercapacitors that integrate battery-like electrode materials with electric double layer electrodes to expand the voltage window, and have high energy density and long cycle life. . However, the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/26H01G11/30H01G11/86
CPCH01G11/26H01G11/30H01G11/86Y02E60/13
Inventor 赵维巍罗旋李康何鹏
Owner HARBIN INSTITUTE OF TECHNOLOGY SHENZHEN (INSTITUTE OF SCIENCE AND TECHNOLOGY INNOVATION HARBIN INSTITUTE OF TECHNOLOGY SHENZHEN)
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