Nickel hydroxide/cobalt disulfide composite material and preparation method and application thereof
A technology of cobalt disulfide and nickel hydroxide, which is applied in the manufacture of hybrid/electric double layer capacitors and electrodes of hybrid capacitors, can solve the problems of unsatisfactory electrochemical properties and flexible comprehensive effects of electrode materials, and achieve excellent electrochemical properties, Good application value, high conductivity effect
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[0022] On the one hand, the embodiment of the present invention provides a kind of preparation method of nickel hydroxide / cobalt disulfide composite material, and this preparation method comprises the following steps:
[0023] S01: providing carbon cloth, and growing cobalt-based metal-organic framework materials on the surface of the carbon cloth;
[0024] S02: placing the carbon grown with the cobalt-based metal-organic framework material in an alcohol solution containing a sulfur source, and performing heat treatment to generate cobalt disulfide nanorods on the surface of the carbon cloth;
[0025] S03: Deposit nickel hydroxide on the surface of the cobalt disulfide nanorods to obtain the nickel hydroxide / cobalt disulfide composite material.
[0026] The preparation method of the nickel hydroxide / cobalt disulfide composite material provided by the embodiment of the present invention uses carbon cloth as a carrier, first grows a cobalt-based metal-organic framework material ...
Embodiment 1
[0043] (1) Materials and reagents
[0044] Carbon cloth (WOS1009) was purchased from Taiwan Carbon Energy Co., Ltd., 2-methylimidazole, cobalt nitrate hexahydrate, thioacetamide (TAA), ethanol, etc. were of analytical grade and purchased from Aladdin Reagents.
[0045] (2) Instruments and equipment
[0046] S-4800 field emission scanning electron microscope, Hitachi, Japan; KO-600BD CNC ultrasonic cleaner, Kunshan Ultrasonic Instrument Co., Ltd.; CHI 760E electrochemical workstation, Shanghai Chenhua Co., Ltd. DZF-6051 vacuum drying oven, Shanghai Jinghong Test Equipment Co., Ltd.
[0047] (3) Nickel hydroxide / cobalt disulfide composite (CoS 2 @Ni(OH) 2 )Synthesis
[0048] 1. Dissolve 0.4mol of 2-methylimidazole aqueous solution in 40mL of deionized water, dissolve 0.25mol of cobalt nitrate hexahydrate in 40ml of deionized water, mix the two evenly to obtain a mixed solution, and put a piece of clean carbon Put the cloth (1cm*2cm) in the above mixed solution, let it stand...
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