Brine refining scale inhibition and dispersion agent as well as preparation method and application thereof

A technology of scale inhibitor dispersant and brine, which is applied in the field of scale inhibitor, can solve the problems of high removal cost, limited use range of removal means, and low removal rate, so as to achieve guaranteed scale inhibition effect, excellent scale inhibition dispersion effect, and simple formula Effect

Active Publication Date: 2020-08-07
四川鸿康科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The object of the present invention is to: the CaSO2 that exists in the process of refining brine when making salt in the prior art is low to the removal rate of calcium, magnesium, sulfate radical etc., waste residue is many and forms 4 , CaCO 3 Such technical problems as extremely easy to accumulate and form scale, high removal cost, and limited application range of removal means, the present invention provides a scale inhibitor dispersant and its preparation method and application. The scale inhibitor dispersant is used in the brine refining process, Can effectively prevent CaSO 4 , CaCO 3 Crystals are naturally formed on the surface of equipment pipes to form scales, but after they are dispersed, they are discharged in a controlled manner at the subsequent settlement site, avoiding CaSO 4 , CaCO 3 Such substances continue to accumulate and scale, causing equipment and pipeline blockage, greatly reducing the volume of the vacuum tank, low heat transfer efficiency, and high energy consumption. At the same time, the scale inhibitor dispersant has the advantages of low cost, easy industrial application, and environmental friendliness.

Method used

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  • Brine refining scale inhibition and dispersion agent as well as preparation method and application thereof
  • Brine refining scale inhibition and dispersion agent as well as preparation method and application thereof
  • Brine refining scale inhibition and dispersion agent as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Scale inhibitor dispersant, composition is as follows (mass percentage):

[0045]

[0046] The aforementioned itaconic acid-acrylic acid copolymer solution is an aqueous solution with a mass fraction of 30%, the maleic anhydride-acrylic acid copolymer solution is an aqueous solution with a mass fraction of 50%, and the polyaspartic acid solution is a 40% aqueous solution with a mass fraction. The succinic acid solution has a mass fraction content of 40%, and the stabilizer is Na 2 SO 3 .

[0047] Preparation process: First, add 100% of the water consumption in the reactor, and add stabilizer (Na 2 SO 3 ), stirred for 15min, added itaconic acid-acrylic acid copolymer solution, maleic anhydride-acrylic acid copolymer solution, polyaspartic acid solution, polyepoxysuccinic acid solution in proportion, and stirred for 15min to obtain the refined scale-inhibiting solution of the brine Dispersant. All manipulations were performed at room temperature.

[0048] Experim...

Embodiment 2-6

[0132] Based on the research of the four raw material ratios in test 2.9, it was found that the itaconic acid-acrylic acid copolymer solution, the maleic anhydride-acrylic acid copolymer, the polyaspartic acid solution, and the polyepoxysuccinic acid solution When the mass ratio is 4:2:1:0.5~1.5, the scale inhibition rate reaches over 77%, and when the raw material ratio is 4:2:1:1, the maximum scale inhibition rate is 81.98. Example 2-6 has studied the impact of other ratios on the performance of the scale inhibition rate of the product. The preparation process of the scale inhibition dispersant in Example 2-6 is the same as the total mass of the scale inhibition dispersant, the mass content of the stabilizer, and the quality of the water. The content is the same as in Test 2.9, only the mass ratio, mass ratio and scale inhibition of itaconic acid-acrylic acid copolymer solution, maleic anhydride-acrylic acid copolymer solution, polyaspartic acid solution, and polyepoxysuccini...

Embodiment 7

[0137] Refined scale inhibitor dispersant with brine, the composition is as follows (mass percentage):

[0138]

[0139]

[0140] The aforementioned itaconic acid-acrylic acid copolymer solution is an aqueous solution with a content of 33%, the maleic anhydride-acrylic acid copolymer is an aqueous solution with a content of 48%, the polyaspartic acid solution is an aqueous solution with a content of 41%, and the polyepoxysuccinic acid solution content is 40%, the stabilizer is Na 2 SO 3 .

[0141]Preparation process: First, add 100% of the water consumption in the reactor, and add stabilizer (Na 2 SO 3 ), stirred for 12min, added itaconic acid-acrylic acid copolymer solution, maleic anhydride-acrylic acid copolymer, polyaspartic acid solution, polyepoxysuccinic acid solution in proportion, and stirred for 15min to obtain the refined scale-inhibiting dispersion of brine agent. All manipulations were performed at room temperature.

[0142] Measure 0.032ml of the test...

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Abstract

The invention relates to a brine refining scale inhibition and dispersion agent as well as a preparation method and application thereof. The brine refining scale inhibition and dispersion agent is mainly prepared from the following raw materials in percentage by mass: 20-60% of an itaconic acid-acrylic acid copolymer solution; 5%-30% of a maleic anhydride-acrylic acid copolymer solution; 5%-20% ofa polyaspartic acid solution; 5%-20% of a polyepoxysuccinic acid solution; 0.5%-2% of a stabilizer; and 5%-25% of water; the preparation method comprises the following steps: selecting an itaconic acid-acrylic acid copolymer solution, a maleic anhydride-acrylic acid copolymer solution, a polyaspartic acid solution, a polyepoxysuccinic acid solution, a stabilizer and water as raw materials of thescale inhibition and dispersion agent; and screening the proportions of all the components, so that excellent scale inhibition and dispersion effects can be achieved on substances such as CaSO4 and CaCO3 generated in the process of refining and separating calcium, magnesium and sulfate ions from brine, and CaSO4 and CaCO3 crystals are effectively prevented from naturally forming on the surface ofan equipment pipeline to form scales.

Description

technical field [0001] The invention belongs to the technical field of scale inhibitors, and in particular relates to a refined brine scale inhibitor dispersant and its preparation method and application. Background technique [0002] The scientific name of brine is brine, which is a mixture of sodium chloride, calcium chloride, magnesium sulfate, etc., and often contains Na + , Ca 2+ , Mg 2+ , Cl - , SO 4 2- , CO 3 2- 、HCO 3 - Plasma, as far as vacuum salt production is concerned, the existence of calcium, magnesium, and sulfate radicals will not only affect product quality, but also calcium sulfate, magnesium sulfate, sodium sulfate, calcium carbonate and other substances will be formed in the production process Such crystallized form adheres to the surface of system equipment and pipelines, causing fouling and blockage, greatly reducing the volume of vacuum tanks, low heat transfer efficiency, high energy consumption and a series of problems. [0003] Therefore,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/12
CPCC02F5/12
Inventor 殷捷郑文强李平杨慧林龙红梅贺飞燕
Owner 四川鸿康科技股份有限公司
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