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A rare earth permanent magnet material added with yttrium and its preparation method

A rare-earth permanent magnet and rare-earth element technology, which is applied in the fields of magnetic materials, metal processing equipment, inductors/transformers/magnets, etc., can solve the problems of reducing the saturation magnetization of alloys, fast consumption of dysprosium metal, and constant magnetic polarization. , to achieve the effect of reducing viscosity, filling the gap in magnet performance, and improving magnetic performance

Active Publication Date: 2021-11-05
GRIREM ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Since the discovery of NdFeB rare earth permanent magnet materials, it has been widely used in electronic products, medical equipment, automobile industry, energy transportation and other fields due to its superior comprehensive magnetic properties, and with the production and consumption of NdFeB The amount of metal neodymium and dysprosium used as raw materials is increasing year by year, and the consumption rate of metal neodymium and common additive metal dysprosium is also getting faster and faster, resulting in an increase in the cost of materials; on the other hand, with the further promotion and application of permanent magnet motors in the fields of electric vehicles and smart home appliances, The demand for permanent magnet motors in the motor market is increasing, so the search for magnetic materials to replace NdFeB has been put on the agenda
[0003] At present, the Fe site is mainly replaced by the addition of the third element Ti, Nb, Al, and Si to stabilize TbCu. 7 type metastable phase, reducing the wheel speed, but the addition of a certain amount of the above elements will reduce the saturation magnetization of the alloy; and the rare earth Y element with a smaller atomic radius can play a role in stabilizing the metastable phase, and the magnetic pole The chemical strength is basically unchanged

Method used

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  • A rare earth permanent magnet material added with yttrium and its preparation method
  • A rare earth permanent magnet material added with yttrium and its preparation method
  • A rare earth permanent magnet material added with yttrium and its preparation method

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preparation example Construction

[0062] Another aspect of the present invention provides a kind of preparation method of the rare earth permanent magnet material that adds yttrium as described above, comprises the steps:

[0063] (1) Melting an alloy containing Sm, Y and Fe as main components and adding Co and / or Nb elements into an ingot, melting at a high temperature, casting to a rotating roller, and rotating and quenching to obtain a quenched thin strip;

[0064] (2) The ingot is melted at a high temperature and cast to a rotating roller, and then rotated for rapid quenching and cooling to obtain a rapid quenching thin strip;

[0065] (3) quenching the quick-quenched strip obtained in step (2) after crystallization treatment, and then pulverizing into alloy powder;

[0066] (4) Nitriding the alloy powder obtained in step (3) in a tube furnace to obtain the yttrium-added rare earth permanent magnet material.

[0067] The rare earth required for the prepared raw material adopts a single rare earth metal. ...

Embodiment 1

[0103] The permanent magnetic material prepared in this embodiment has the following alloy composition (Sm 0.95 Y 0.05 ) 8.5 Fe 79 N 12.5 (at%) permanent magnet, concrete steps are as follows:

[0104] (1) A master alloy equipped with the above alloy components, wherein the Sm, Y, and Fe elements in the raw materials are all added in the form of pure metals, and then the following steps are used to prepare the SmFeN rare earth permanent magnet material.

[0105] (2) Put the prepared raw materials into a vacuum electric arc furnace to melt evenly, turn off the current and wait for the alloy liquid to cool to obtain a master alloy ingot. Put the prepared ingot into the high-vacuum single-roll spin quenching equipment. 6 Cooling at ℃ / s cooling rate. Among them, the rapid cooling and quick quenching process is carried out under a protective atmosphere, and the alloy liquid is sprayed onto the roller rotating at a wheel speed of 35m / s to obtain a quick quenched thin strip.

...

Embodiment 2

[0113] The permanent magnetic material prepared in this embodiment has the following alloy composition (Sm 0.8 Y 0.2 ) 8.5 Fe 79 N 12.5 (at%) permanent magnet, concrete steps are as follows:

[0114] (1) A master alloy equipped with the above alloy components, wherein the Sm, Y, and Fe elements in the raw materials are all added in the form of pure metals, and then the following steps are used to prepare the SmFeN rare earth permanent magnet material.

[0115](2) Put the prepared raw materials into a vacuum electric arc furnace to melt evenly, turn off the current and wait for the alloy liquid to cool to obtain a master alloy ingot. Put the prepared ingot into the high-vacuum single-roll spin quenching equipment. 5 Cooling at ℃ / s cooling rate. Among them, the rapid cooling and quick quenching process is carried out under a protective atmosphere, and the alloy liquid is sprayed on the roller rotating at a wheel speed of 30m / s to obtain a quick quenched thin strip.

[011...

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Abstract

A rare-earth permanent magnet material added with yttrium and a preparation method thereof, the chemical formula of the material is expressed as (Y x RE 1‑x ) a Fe bal m b N c , where, 0.05≤x≤0.4, 7≤a≤13, 0≤b≤3, 5≤c≤20, the balance is Fe, that is, bal=100‑a‑b‑c; RE is the rare earth element Sm or A combination of rare earth element Sm and any one of Zr, Nd and Pr or more, M is Co and / or Nb, and N is nitrogen. The preparation method uses the rare earth Y element to replace the Sm element of the samarium-iron-nitrogen material, and by regulating the ratio of the Sm element to the Y element, the viscosity of the alloy liquid can be reduced, the amorphous forming ability of the material can be enhanced, and the magnetic properties can be improved. The disadvantages of high coercive force and low residual magnetism are improved, and the magnetic properties of the prepared magnetic powder are more suitable for the performance requirements of motor manufacturing for magnets, filling the gap in the performance of magnets for motor applications.

Description

technical field [0001] The invention relates to the field of rare earth permanent magnet materials, in particular to a rare earth permanent magnet material added with yttrium and a preparation method thereof. Background technique [0002] Since the discovery of NdFeB rare earth permanent magnet materials, it has been widely used in electronic products, medical equipment, automobile industry, energy transportation and other fields due to its superior comprehensive magnetic properties, and with the production and consumption of NdFeB The amount of metal neodymium and dysprosium used as raw materials is increasing year by year, and the consumption rate of metal neodymium and common additive metal dysprosium is also getting faster and faster, resulting in an increase in the cost of materials; on the other hand, with the further promotion and application of permanent magnet motors in the fields of electric vehicles and smart home appliances, The demand for permanent magnet motors...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C38/10C22C38/12C22C38/14B22F9/04B22F1/00H01F1/059B22F1/07B22F1/145
CPCC22C38/005C22C38/001C22C38/10C22C38/12C22C38/14B22F9/04H01F1/059B22F2009/048B22F1/145B22F1/07B22F2998/10C22C33/0264B22F9/007B22F1/00B22F1/068B22F2999/00B22F2201/02B22F3/1007H01F1/0596C22C2202/02C22C2200/02H01F1/053H01F41/0293B22D11/0611B22D11/0682H01F41/0266B22F2304/10B22F2301/355
Inventor 罗阳林笑吴桂勇谢佳君王子龙闫文龙王仲凯于敦波
Owner GRIREM ADVANCED MATERIALS CO LTD
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