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Hydrogen-sensitive discoloration detection adhesive tape, and preparation method and application thereof

A technology of adhesive tape and color-changing materials, which is applied in the direction of detecting the appearance of fluid, adhesives, and measuring devices at the leakage point, can solve the problems of limited positioning ability, affecting the detection sensitivity of sensors, and limited, etc., to achieve a simple and intuitive way of expression, high Promote the use value and improve the effect of rescue speed

Inactive Publication Date: 2020-09-15
BEIJING INST OF AEROSPACE TESTING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method cannot locate the leakage point; in some large-volume and high-flow hydrogen storage equipment, local hydrogen leakage is difficult to cause significant changes in the pressure consumption in the system, making this method impossible to locate the hydrogen leakage. effective monitoring of
The hydrogen concentration gas sensor uses hydrogen to act on the sensing element to generate an electrical signal to indicate the presence of hydrogen, but its installation and maintenance costs are high
The hydrogen concentration gas sensor has a certain ability to locate the leak point, but the location ability is limited by factors such as the layout location, density, and the mobility of the carrier.
In addition, the easy diffusion of hydrogen will cause the concentration of hydrogen around the leakage point to drop rapidly, which will affect the detection sensitivity of the sensor.
[0004] Various problems exist in the application scope and effect of the existing hydrogen leak detection methods, making it unable to meet the industry's demand for the safety of hydrogen resource utilization

Method used

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  • Hydrogen-sensitive discoloration detection adhesive tape, and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Weigh 100 parts by weight of hydroxyl-terminated polysiloxane, add 32 parts by weight of fumed silica reinforcing agent to a kneader, and stir evenly at room temperature to obtain a tape matrix. Then add 1.5 parts by weight of tungsten oxide and 0.005 parts by weight of platinum nanoparticles to make the adhesive tape have a color-changing function. 3 parts by weight of tetraethyl orthosilicate crosslinking agent and 0.5 part by weight of dioctyltin dilaurate are added to make the adhesive tape have self-adhesive function. Then use a kneader to knead and mix. Immediately after mixing, make a strip-shaped sheet with a width of 5 cm and a thickness of 0.5 mm by mechanical external force, attach a plastic backing paper, and make a tape roll or tape strip semi-finished product. Then put the semi-finished product at room temperature for about 12 hours to cure, and the cured adhesive tape is the hydrogen-sensitive discoloration detection adhesive tape.

[0057] When in use, ...

Embodiment 2

[0060] Weigh 100 parts by weight of hydroxyl-terminated polysiloxane, and add 25 parts by weight of fumed silica reinforcing agent to a kneader. Then 2.5 parts by weight of palladium oxide, 0.01 part by weight of nickel nanoparticles, 5 parts by weight of methyltributylketoximosilane crosslinking agent, and 0.5 parts by weight of tetrabutyl titanate were added. Then use a kneader to knead and mix at room temperature. Immediately after mixing, make a strip-shaped sheet with a width of 2 cm and a thickness of 0.2 mm, attach a plastic backing paper, and make a tape roll or tape strip semi-finished product. Then put the semi-finished product at room temperature for about 12 hours to cure, and the cured adhesive tape is the hydrogen-sensitive discoloration detection adhesive tape.

[0061] When in use, tear off the backing paper of the tape, wrap the tape around the leak point of the pre-made pipeline, and use the self-adhesive property of the tape to fix the tape. If a mixture of...

Embodiment 3

[0063] Weigh 100 parts by weight of hydroxyl-terminated polysiloxane, and add 15 parts by weight of fumed silica reinforcing agent to a kneader. Then add 1 weight part of molybdenum oxide and 0.008 weight part of nickel nanoparticles to make the adhesive tape have a color-changing function. 10 parts by weight of methyl tributylketoxime silane crosslinking agent and 0.8 parts by weight of dibutyl tin dioctoate were added. Use a kneader to knead and mix. Immediately after mixing, make a strip-shaped sheet with a width of 10cm and a thickness of 0.2mm by mechanical external force, attach a plastic backing paper, and make a tape roll or tape strip semi-finished product. Then put the semi-finished product at room temperature for about 10 hours to cure, and the cured adhesive tape is the hydrogen-sensitive discoloration detection adhesive tape.

[0064] When in use, tear off the backing paper of the tape, wrap the tape around the leak point of the pre-made pipeline, and use the sel...

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PUM

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Abstract

The invention relates to a hydrogen-sensitive discoloration detection adhesive tape, and a preparation method and application thereof, concretely relates to a self-adhesive tape, concretely relates toa self-adhesive tape capable of generating color change under hydrogen contact, and further relates to a preparation method and an application method of the self-adhesive tape. The self-adhesive tapeis intrinsically safe, simple and convenient to fix, and simple and visual in a visual representation mode, the position of a leakage point can be indicated through local discoloration, the defects that the positioning capability of a pressure loss hydrogen leakage detection leakage detection point is limited and tiny leakage is difficult to find are overcome, the defect that electronic hydrogendetection equipment is high in layout cost is overcome, a common hydrogen leakage detection method is supplemented, the time cost for finding the leakage position after leakage occurs is greatly reduced, the emergency response is improved, and extremely high application and popularization value is achieved.

Description

technical field [0001] The invention relates to a hydrogen-sensitive color-changing detection tape and its preparation method and application, in particular to a self-adhesive tape, in particular to a self-adhesive tape that can change color when exposed to hydrogen, and to a self-adhesive tape The preparation method of the adhesive tape and the method of use. Background technique [0002] With the development of hydrogen production and hydrogen storage technology, hydrogen energy has developed into the most potential clean energy in the 21st century. The product of its high combustion calorific value is water, the cleanest energy. Widely sourced and renewable. However, the explosion limit of hydrogen is wide, ranging from 4% to 75%, and a strong explosion can occur when it encounters an open flame. At the same time, the hydrogen molecule is very small, and it is very easy to leak during production, transportation and storage. Therefore, in the storage and transportation...

Claims

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Application Information

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IPC IPC(8): C09J7/30C09J7/10C09J183/04C09J11/04C09J11/06C09J11/08G01N21/78G01M3/04
CPCC08K2003/0862C08K2003/2255C08K2003/2258C08K2201/005C08K2201/011C08K2201/014C08L2205/025C08L2312/00C09J11/04C09J11/06C09J11/08C09J183/04C09J2483/00C09J7/10C09J7/30G01M3/04G01N21/783C08K13/04C08K7/26C08K3/22C08K3/08C08K5/5415C08K5/57C08K5/10C08K5/5465C08L83/04C08K3/24
Inventor 徐林楠孟醒李俊张学军钟秋毛亚南赵坦张旭方涛
Owner BEIJING INST OF AEROSPACE TESTING TECH
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