Rapid low-cost activation method for membrane electrode of proton exchange membrane fuel cell

A proton exchange membrane and fuel cell membrane technology, which is applied in the field of fast and low-cost activation of membrane electrodes of proton exchange membrane fuel cells, can solve the problems of high activation cost, use of a large amount of hydrogen, and energy consumption, so as to reduce activation cost, reduce consumption, The effect of increasing utilization

Active Publication Date: 2020-09-29
WUXI WEIFU HIGH TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Traditional pre-activation methods such as boiling MEA in boiling water, PEMFC water injection and soaking and wetting cannot be used alone. It is necessary to combine the discharge activation method to further activate PEMFC, which only speeds up the activation speed to a certain extent, and still requires the use of electronic loads and other power-consuming equipment, and need to use a large amount of hydrogen, energy consumption, resulting in high activation costs

Method used

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  • Rapid low-cost activation method for membrane electrode of proton exchange membrane fuel cell
  • Rapid low-cost activation method for membrane electrode of proton exchange membrane fuel cell
  • Rapid low-cost activation method for membrane electrode of proton exchange membrane fuel cell

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Embodiment 1

[0026] Embodiment 1 (non-discharge wet hydrogen method)

[0027] The research object of this embodiment is a fuel cell, and the effective active area of ​​the membrane electrode is 25cm 2 , using the non-discharge wet hydrogen method to activate the battery, including the following steps:

[0028] (1) Put the newly assembled 25cm 2 The single cell of the proton exchange membrane fuel cell is installed on the fuel cell test bench, and the dry nitrogen gas of 0.3 NL / min is passed through the positive and negative poles of the single cell for 10 minutes to remove the air and impurities in the fuel cell;

[0029] (2) Turn on the heating device and set the temperature of the single battery to 55°C;

[0030] (3) Pass hydrogen with a relative humidity of 80% to the anode, and pass hydrogen with a relative humidity of 80% to the cathode, and the flow rate of hydrogen at the cathode and anode is 0.3 NL / min;

[0031] (4) Keep the flow rate of hydrogen in step (3) for 2 minutes;

[0...

Embodiment 2

[0045] Embodiment 2 (non-discharge wet hydrogen method)

[0046] The research object of this embodiment is a fuel cell, and the effective active area of ​​the membrane electrode is 300cm 2 , using the non-discharge wet hydrogen method to activate the battery, including the following steps:

[0047] (1) Put the newly assembled 300cm2 The proton exchange membrane fuel cell single cell is installed on the fuel cell test bench, and 2.2 NL / min of dry nitrogen is safely purged to the positive and negative poles of the single cell for 10 minutes to remove the air and impurities in the fuel cell;

[0048] (2) Turn on the heating device and set the temperature of the single battery to 55°C;

[0049] (3) Pass hydrogen gas with a relative humidity of 80% to the anode, and pass hydrogen gas with a relative humidity of 80% to the cathode, and the hydrogen flow rate at the cathode and anode is 3.6 NL / min;

[0050] (4) Keep the flow rate of hydrogen in step (3) for 5 minutes;

[0051] (5)...

Embodiment 3

[0064] Embodiment 3 (non-discharge wet hydrogen method)

[0065] The research object of this embodiment is a stack assembled with 8 membrane electrodes, and the effective active area of ​​the membrane electrodes is 300cm 2 , using the non-discharge wet hydrogen method to activate the stack, including the following steps:

[0066] (1) Install the newly assembled 8-cell stack on the fuel cell test bench, and safely purge 17.5 NL / min of dry nitrogen to the positive and negative poles of the stack for 15 minutes to remove the air and impurities in the fuel cell;

[0067] (2) Turn on the heating device and set the stack temperature to 65°C;

[0068] (3) Pass hydrogen with a relative humidity of 90% to the anode, and pass hydrogen with a relative humidity of 90% to the cathode, and the hydrogen flow rate at the two poles is 28.8 NL / min;

[0069] (4) Keep the flow rate of hydrogen in step (3) for 15 minutes;

[0070] (5) Close the solenoid valve at the outlet end of the two poles ...

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Abstract

The invention belongs to the technical field of fuel cells, and particularly relates to a rapid low-cost activation method for a membrane electrode of a proton exchange membrane fuel cell. The activation method comprises the following steps: introducing dry nitrogen into two poles of a single cell or an electric pile for safe purging and removing air and impurities in the fuel cell; heating the single cell or electric pile; introducing humidified hydrogen into an anode and a cathode of the cell respectively, keeping the hydrogen in the cell, and carrying out discharge-free wet hydrogen treatment on the single cell or the electric pile of the fuel cell; and stopping hydrogen supply, discharging residual gas and the like. The non-discharge wet hydrogen activation method is adopted, so that the catalyst activity of the proton exchange membrane fuel cell can be improved, the activation time can be greatly shortened, the gas fuel consumption is reduced, and the activation cost is greatly reduced. According to the activation method, MEA can be rapidly activated without using an electronic load and consuming a large amount of hydrogen, the energy is saved, the cost is reduced, and the defects of a pre-activation (non-discharge) method and a discharge activation method are overcome.

Description

technical field [0001] The invention belongs to the technical field of fuel cells, in particular to a fast and low-cost activation method for membrane electrodes of proton exchange membrane fuel cells. Background technique [0002] The core component of the proton exchange membrane fuel cell (PEMFC) is the membrane electrode MEA (Membrane Electrode Assembly), and its performance largely determines the performance of the PEMFC. The performance of several main components of MEA (electrocatalyst, proton exchange membrane and diffusion layer) and the preparation process of MEA have a great influence on its performance, but in order to make PEMFC quickly reach its best state and In terms of working performance, before the MEA is prepared and assembled into a fuel cell for normal test operation, the MEA is usually activated. In addition, for the performance attenuation caused by the long-term storage of the PEMFC, it can also be activated by the MEA. recover the performance of PE...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/04223H01M8/04119H01M8/1007
CPCH01M8/04223H01M8/04126H01M8/1007H01M2008/1095Y02E60/50
Inventor 张义煌刘凯刘敏许笑目
Owner WUXI WEIFU HIGH TECH CO LTD
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