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Antistatic explosion-proof polyurea material as well as preparation method and application thereof

An antistatic and polyurea technology, applied in polyurea/polyurethane coatings, anti-corrosion coatings, conductive coatings, etc., can solve the problems of polyurea material strength decline

Active Publication Date: 2020-10-23
QINGDAO AIR NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in polyurea materials, adding a large amount of antistatic materials will cause a decrease in the strength of polyurea materials

Method used

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  • Antistatic explosion-proof polyurea material as well as preparation method and application thereof
  • Antistatic explosion-proof polyurea material as well as preparation method and application thereof
  • Antistatic explosion-proof polyurea material as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A kind of antistatic explosion-proof polyurea material, comprises A component and B component, and described A component comprises following parts by weight

[0033] Raw materials: 474 parts of toluene diisocyanate, 521 parts of polyhexamethylene adipate diol (PHA-1000) and 5 parts of single-walled amino carbon nanotubes. The average diameter of the single-wall amino carbon nanotubes is 6nm, and the average length is 20μm. The aminated carbon nanotubes are based on carboxylated carbon nanotubes. obtained by decarboxylation.

[0034] The B component includes polyester polyols, amino-terminated chain extenders and auxiliary agents; wherein, the relative molecular weight of polyester polyols is 2000, and the average functionality is 2.0; specifically, polyester polyols include 305 parts by weight Parts of polyhexamethylene adipate diol (PHA-2000) and 280 parts of polyethylene adipate diol (PEA-2000); The terminal amino chain extender includes 320 parts by weight of 3 ,5 ...

Embodiment 2

[0042] A kind of antistatic explosion-proof polyurea material, comprises A component and B component, and described A component comprises following parts by weight

[0043] Raw materials: 483 parts of isophorone diisocyanate, 505 parts of polycaprolactone polyol (PCL-2000) and 12 parts of multi-wall amino carbon nanotubes; the average diameter of multi-wall amino carbon nanotubes is 8nm , with an average length of 30 μm;

[0044] The B component includes a polyester polyol, an amino-terminated chain extender and an auxiliary agent; specifically, the polyester polyol includes 577 parts by weight of polycaprolactone polyol (PCL-1000) and 10 parts of Polycaprolactone polyol (PCL-3031); amino-terminated chain extenders include 107 parts by weight of 3,5 diethyltoluenediamine, 197 parts of 4,4'-bis-sec-butylaminodiphenylmethane ; Auxiliaries include 4 parts of N,N-dimethylcyclohexylamine catalyst, 1 part of stannous octoate, 12 parts of 2-hydroxyl-4-n-octyloxybenzophenone UV absor...

Embodiment 3

[0053] A kind of antistatic explosion-proof polyurea material, comprises A component and B component, and described A component comprises following parts by weight

[0054] Raw materials: 599 parts of diphenylmethane diisocyanate, 381 parts of polyhexamethylene adipate diol (PHA-3000) and 20 parts of single-walled aminocarbon nanotubes; single-walled aminocarbon nanotubes The average diameter is 10nm, and the average length is 40μm;

[0055] The B component includes polyester polyols, amino-terminated chain extenders and auxiliary agents; specifically, the polyester polyols include 316 parts by weight of polyhexamethylene adipate diol (PHA-2000), 227 parts of polycaprolactone polyol (PCDL-2000); the amino-terminated chain extender includes 213 parts by weight of 3,5-dimethylthiotoluenediamine, 161 parts of 4,4'-bis-sec-butyl Aminodiphenylmethane; additives include 3 parts by weight of triethanolamine, 3 parts of lead catalyst of isooctanoate, 8 parts of 2-(2-hydroxyl-3,5 bis(...

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Abstract

The invention provides an antistatic explosion-proof polyurea material and a preparation method and application thereof. The antistatic explosion-proof polyurea material is prepared from a component Aand a component B. The component A is prepared from diisocyanate, polyester polyol and carbon nanotubes; the component B comprises the following raw materials: polyester polyol, an amino-terminated chain extender and an auxiliary agent. The antistatic explosion-proof polyurea material comprises carbon nanotubes, the carbon nanotubes have excellent mechanical properties, electrical properties, optical properties, adsorption properties and the like; a small amount of carbon nanotubes are added into the polyurea material, so that the tensile strength and tearing strength of the polyurea materialcan be improved, the mechanical properties of the material can be further improved to achieve explosion-proof and impact-resistant effects, and the surface resistivity of the polyurea material can beobviously reduced to achieve an antistatic effect.

Description

technical field [0001] The invention relates to the technical field of spraying polyurea materials, in particular to an antistatic explosion-proof polyurea material and a preparation method and application thereof. Background technique [0002] With the advancement of my country's oil reserve strategy, my country has entered a period of rapid growth in the construction of large-scale petrochemical equipment. Crude oil, especially light oil, generates electric charges due to friction during transportation, mixing, filtering, filling, and extraction. Charge accumulation occurs when the rate at which charges are exported is less than the rate at which charges are generated. When the concentration of volatile oil reaches the explosion limit, the accumulated electric charge is likely to generate static sparks and cause an explosion, resulting in huge economic and property losses. By coating the surface of the equipment with antistatic materials, the accumulation of charges can ...

Claims

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Application Information

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IPC IPC(8): C08G18/76C08G18/75C08G18/66C08G18/42C08G18/32C08K13/06C08K13/04C08K9/00C08K3/04C09D175/02C09D5/24C09D5/08
CPCC08G18/7614C08G18/4238C08K13/06C08K13/04C08K9/00C08K3/041C08G18/4202C08G18/324C08G18/6618C09D175/02C09D5/24C09D5/08C08G18/755C08G18/4277C08G18/7671C08G18/3857C08K2201/011C08K2201/003C08K2201/004C08K2201/017
Inventor 王宝柱李灿刚王伟邵春妍温喜梅
Owner QINGDAO AIR NEW MATERIALS
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