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Compatilizer and glass fiber reinforced polypropylene composite material

A technology of glass fiber and composite materials, which is applied in the field of glass fiber reinforced polypropylene composite materials and compatibilizers. It can solve the problems of affecting the mechanical properties of products, the inability to apply dark-colored products, and precipitation and stickiness.

Inactive Publication Date: 2020-10-27
KINGFA SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In many current studies, some scholars use anti-floating fiber masterbatches, such as CN108912514, which uses glass fiber and PB-1 as anti-floating fiber masterbatches and then adds them to the finished product, so that the glass fiber in the masterbatch has undergone a second pass and the retention length will be reduced. reduce, affecting the mechanical properties of the product; such as CN 103756014B uses zinc oxide as anti-floating fiber masterbatch, this anti-floating fiber masterbatch is white, and cannot be applied to dark-colored products
In addition, some scholars add anti-floating fiber agent in the product, and the type of anti-floating fiber agent is also various, such as CN 107254104A using high-melting index PP (MFR>500g / 10min), ethylene bisstearic acid amide dispersant It is used in combination with TAF lubricant, but ethylene bis stearic acid amide dispersant and TAF are small molecules, which may cause stickiness.

Method used

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  • Compatilizer and glass fiber reinforced polypropylene composite material
  • Compatilizer and glass fiber reinforced polypropylene composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0068] An embodiment of the glass fiber reinforced polypropylene composite material of the present invention, the glass fiber reinforced polypropylene composite material described in this embodiment is prepared by the following method:

[0069] Step 1: Preparation of purified PB-1-g-GMA

[0070] a-First weigh 3 parts of monomer glycidyl methacrylate (referred to as GMA), 0.05 part of initiator 2,5-dimethyl-2,5-bis(tert-butyl peroxide)hexane (abbreviated as DHBP) , 0.5 parts of comonomer divinylbenzene (DVB) was dissolved in 30 parts of acetone at 30° C. to obtain a mixed solution A for use.

[0071] b-Add the above mixed solution A to 50 parts of PB-1M8510M and mix and stir evenly at room temperature. After the acetone is completely volatilized, add it to a twin-screw extruder for melt extrusion grafting reaction to obtain PB-1-g-GMA crude compounds. Wherein, the temperature of the twin-screw extruder is 130-150°C.

[0072] c- Take 1 part of PB-1-g-GMA crude product and add...

Embodiment 2

[0076] An embodiment of the glass fiber reinforced polypropylene composite material of the present invention, the glass fiber reinforced polypropylene composite material described in this embodiment is prepared by the following method:

[0077] Step 1: Preparation of purified PB-1-g-GMA

[0078] a-First weigh 6 parts of glycidyl methacrylate monomer (GMA for short), 0.35 parts of initiator 2,5-dimethyl-2,5-bis(tert-butyl peroxide)hexane (DHBP for short) 2 parts of comonomer divinylbenzene (DVB) were dissolved in 50 parts of acetone at 50°C to obtain a mixed solution A for use;

[0079] b- Add the above mixed solution A to 70 parts of PB-1M1500M and mix and stir evenly at room temperature. After the acetone is completely volatilized, add it to a twin-screw extruder for melt extrusion grafting reaction to obtain PB-1-g-GMA crude compounds. Wherein, the temperature of the twin-screw extruder is 130-150°C;

[0080] c- Take 1 part of PB-1-g-GMA crude product and add it to 50 par...

Embodiment 3

[0084] An embodiment of the glass fiber reinforced polypropylene composite material of the present invention, the glass fiber reinforced polypropylene composite material described in this embodiment is prepared by the following method:

[0085] Step 1: Preparation of purified PB-1-g-GMA

[0086] a-First weigh 4 parts of monomer glycidyl methacrylate (referred to as GMA), 0.15 parts of initiator 2,5-dimethyl-2,5-bis(tert-butyl peroxide)hexane (abbreviated as DHBP) 1. Dissolve 1 part of comonomer divinylbenzene (DVB) in 37 parts of acetone at 37° C. to obtain mixed solution A for use.

[0087] b-Add the above mixed solution A to 55 parts of PB-1M1200M, mix and stir evenly at room temperature, and after the acetone is completely volatilized, add it to a twin-screw extruder for melt extrusion grafting reaction to obtain PB-1-g-GMA crude compounds. Wherein, the temperature of the twin-screw extruder is 130-150°C.

[0088] c- Take 1 part of PB-1-g-GMA crude product and add it to ...

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Abstract

The invention discloses a compatilizer and a preparation method thereof. Meanwhile, the invention further discloses a glass fiber reinforced polypropylene composite material. The polypropylene composite material comprises the following components by weight: 35-90 parts of polypropylene, 20-50 parts of glass fiber, 5-15 parts of a compatilizer and 0.2-0.6 part of an antioxidant, wherein the polypropylene contains polypropylene A, and the melt flow rate of the polypropylene A under the condition of 230DEG C and 2.16kg is 800-1800g / 10min. By using the polypropylene A and the specific compatilizer, the glass fiber can be better wrapped and infiltrated, so that the appearance anti-floating fiber effect is good; meanwhile, the invention further discloses a preparation method of the glass fiber reinforced polypropylene composite material.

Description

technical field [0001] The invention relates to the field of polymer material modification, in particular to a compatibilizer and a glass fiber reinforced polypropylene composite material. Background technique [0002] Glass fiber reinforced polypropylene (GFRPP) has the advantages of high rigidity, high impact, good fatigue creep resistance, short molding cycle, and recyclability, which largely solves a series of shortcomings such as low rigidity and poor fatigue creep of pure PP. After being put into use in the 1970s, it has been widely used in many fields such as home appliances, electronic appliances, construction industry, aerospace, ships and automobiles. However, in terms of engineering applications, the phenomenon of glass fiber exposure greatly limits the use of GFRPP materials. [0003] In recent years, with the improvement of the use environment and aesthetic requirements of polymer materials, people have put forward higher requirements for the floating fiber con...

Claims

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Application Information

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IPC IPC(8): C08F255/10C08F220/32C08F212/36C08L23/12C08L51/06C08K13/04C08K7/14C08J5/04B29C48/92
CPCC08F255/10C08J5/043B29C48/92C08J2323/12C08J2423/12C08K13/04C08K7/14B29C2948/92704C08F220/325C08F212/36
Inventor 俞飞罗睿叶南飚黄险波吴国峰赖昂丁正亚杨波罗忠富
Owner KINGFA SCI & TECH CO LTD
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