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Compound brazing filler metal used for hard alloy tool brazing and preparation method thereof

A technology of composite solder and hard alloy, which is applied in welding equipment, metal processing equipment, welding/cutting media/materials, etc., can solve the problem of restricting the use and production of clad materials, high requirements on the plasticity and bonding surface of ingots, and extrusion problems. The quality of laminated materials is difficult to achieve the effect of stable and reliable product quality, improved fluidity and filling ability, and increased yield

Active Publication Date: 2020-11-06
YUNNAN PRECIOUS METALS LAB CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the brazing material described in this patent can improve the wear resistance and working strength of the brazed joint, the method requires high technology, cumbersome process and low production efficiency.
For this reason, Publication No. CN 110076474 A discloses a cemented carbide clad welding material and its preparation method that can improve the performance of brazed joints and can be produced on a large scale. And high requirements on the joint surface, hot extrusion process and difficult control of the quality of the extruded clad material limit the application and production of the clad material

Method used

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  • Compound brazing filler metal used for hard alloy tool brazing and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A kind of composite solder used for hard alloy tool brazing of the present invention, each component is by mass percent: 25% Ag, 37% Cu, 3.0% Mn, 2.0% Ni, 1.5% In, 0.5% nano-SiCp, 0.15% Si, 0.1% B, 0.05% Co, 0.01% Fe, 0.01% La, Ce, Y mixed rare earth, and the balance is Zn.

[0033] A kind of composite silver filler metal preparation method step that is used for cemented carbide tool brazing of the present invention is as follows:

[0034] (1) Pour nano-SiCp and Cu powder into the ball mill tank, and conduct segmented dry high-energy ball milling according to the ball-to-material ratio of 3:1 to obtain Cu / nano-SiCp particles: the first stage of 120rpm ball milling for 3h, the second stage of 200rpm ball milling 4h, the second stage of 300rpm ball milling for 5h, with an interval of 1h between each stage;

[0035](3) Rapidly heat and melt Cu ingots, Ag, Zn, Mn, Ni, Si, Co, and Fe in an intermediate frequency induction furnace under atmospheric atmosphere, and then rapid...

Embodiment 2

[0040] The components of the composite solder described in this implementation are: 25.5% Ag, 37.5% Cu, 3.0% Mn, 2.0% Ni, 1.5% In, 0.5% nano-SiCp, 0.15% Si, 0.1% of B, 0.05% of Co, 0.01% of Fe, 0.01% of La, Ce, Y mixed rare earth, and the balance is Zn. The preparation method of the composite solder described in this embodiment is the same as that in Embodiment 1.

[0041] In this embodiment, the melting temperature of the solder is 691-772° C., and the shear strength of the brazing joint is 361 MPa.

Embodiment 3

[0043] The components of the composite solder described in this implementation are by mass percentage: 25.5% Ag, 37.5% Cu, 3.5% Mn, 2.5% Ni, 1.5% In, 0.5% nano-SiCp, 0.15% Si, 0.1% of B, 0.05% of Co, 0.02% of Fe, 0.01% of La, Ce, Y mixed rare earth, and the balance is Zn. The preparation method of the composite solder described in this embodiment is the same as that in Embodiment 1.

[0044] In this embodiment, the melting temperature of the solder is 692-771° C., and the shear strength of the brazing joint is 364 MPa.

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Abstract

The invention relates to compound brazing filler metal used for hard alloy tool brazing. The compound brazing filler metal is composed of 25%-27% of Ag, 37%-39% of Cu, 3.0%-5.0% of Mn, 2.0-4.0% of Ni,1.5%-2.5% of In, 0.5%-1.0% of nano-SiCp, 0.15%-0.3% of Si, 0.1%-0.2% of B, 0.05%-0.1% of Co, 0.01%-0.05% of Fe, 0.01%-0.1% of La, Ce and Y mixed rare earth and the balance Zn, wherein the mixed rareearth includes at least two of La, Ce and Y. A preparation method includes the steps that firstly, raw materials are weighed according to the ratio; secondly, segmented variable-speed high-energy ballmilling is conducted on Cu powder and nano-SiCp to obtain Cu / nano-SiCp particles; thirdly, the Ag, Cu ingots, the Zn, the Mn, the Ni, the Si, the Co and the Fe are placed in a medium-frequency induction smelting furnace to be heated and molten, and then the In, the B, the Cu foil wrapped mixed raw earth and the Cu / nano-SiCp particles are sequentially added in a crucible; fourthly, the mixture ismoved into a well type resistance furnace to be subjected to ultrasonic vibration and squeeze casting forming; and fifthly, hot rolling and cold rolling are conducted on cast ingots to form the foil sheet brazing filler metal. By means of segmented variable-speed ball milling and ultrasonic vibration, uniform dispersion of the nano-SiCp is ensured, the brazing filler metal is good in wettability and joint filling capacity, the brazing manufacturability is good, the preparation method is simple, and the finished product rate is high.

Description

technical field [0001] The invention belongs to the technical field of brazing materials, and in particular relates to a composite brazing material used for brazing of cemented carbide tools and a preparation method thereof. Background technique [0002] Cemented carbide has excellent properties such as high hardness, high strength, wear resistance and good red hardness. It is often used to make knives and various parts with wear resistance as the main performance. It is widely used in mechanical processing, geological exploration, mining, etc. fields such as mining. [0003] In recent years, the number of carbide cutting tools has been increasing, and now accounts for more than 60% of all cutting tools. Since hard alloys are difficult to prepare large-scale and complex-shaped tools, most hard alloys are embedded in steel substrates by brazing. [0004] Welded carbide tools have the advantages of high hardness, good wear resistance, good heat resistance, high cutting perfo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K35/30B23K35/40
CPCB23K35/0233B23K35/3006B23K35/40
Inventor 赵上强谢明方继恒张吉明杨有才李爱坤马洪伟段云昭
Owner YUNNAN PRECIOUS METALS LAB CO LTD
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