Method for preparing silver-nickel-tin-oxide-doped electric contact material on basis of ball-milling method

An electrical contact material, tin oxide technology, applied in circuits, electrical switches, electrical components and other directions, can solve the problems of poor electrical conductivity of electrical contact materials, long material preparation period, difficult to achieve industrialization, etc. Wear properties and anti-welding properties, control of growth and the effect of agglomeration

Inactive Publication Date: 2020-11-20
XI'AN POLYTECHNIC UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Traditional preparation of Ag-Ni-SnO 2 The method of electrical contact materials has the advantage of making the oxides in the contact materials evenly distributed, which can effectively avoid the poor oxidation area caused by the internal oxidation method. However, most of the traditional processes exist to make Ag-Ni-SnO 2 The electrical conductivity of the electrical contact material is poor, and the material preparation cycle is long, and the powder is easily polluted
[0005] In recent years, many new powder preparation methods and alloy preparation processes have emerged, such as sol-gel method, plasma spraying method, etc., which have effectively improved the Ag-Ni-SnO 2 The performance of electrical contact materials; but in the current preparation process, the high temperature sintering part will lead to Ag-Ni-SnO 2 Oxidation-reduction reactions occur between elements in electrical contact materials, resulting in by-products, and these processes generally have problems such as high cost, complicated preparation process, and difficulty in industrialization.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] Step 1. Weigh tin oxide powder, other oxide powders and grinding balls respectively, and process the mixed powder symmetrically taken by high-energy ball milling technology to obtain preliminary mixed oxide powder A. The specific steps are:

[0064] 1.1) Weigh nano tin oxide powder, La 2 o 3 And stainless steel grinding balls, nano tin oxide powder, La 2 o 3 The mass ratio to the grinding ball is 5:1:100;

[0065] 1.2) Add the oxide powder weighed in step 1.1) together with stainless steel balls into the ball milling jar, then add absolute ethanol to the ball milling jar, add 3ml of absolute ethanol to each gram of oxide powder, start the ball mill for ball milling Treatment, ball milling time 2h;

[0066] In order to ensure the ball milling effect, during the ball milling process, the total volume of nano-oxide powder, absolute ethanol and stainless steel balls accounts for 40% of the ball milling tank volume;

[0067] 1.3) Place the mixed oxide powder obtained af...

Embodiment 2

[0084] Step 1. Weigh tin oxide powder, other oxide powders and bearing steel grinding balls respectively, and process the mixed powder symmetrically taken by high-energy ball milling technology to obtain preliminary mixed oxide powder A. Specifically, follow the steps below:

[0085] 1.1) Weigh nano tin oxide powder, CuO powder and bearing steel grinding ball respectively, the mass ratio of nano tin oxide powder, CuO powder and grinding ball is 6:2:103;

[0086] 1.2) Add the oxide powder weighed in step 1.1) together with the bearing steel grinding balls into the ball milling jar, then add absolute ethanol to the ball milling jar, add 4ml of absolute ethanol to each gram of oxide powder, start the ball mill Ball milling treatment, ball milling time 3h;

[0087] In order to ensure the ball milling effect, during the ball milling process, the total volume of nano-oxide powder, absolute ethanol and bearing steel balls accounts for 50% of the ball milling tank volume;

[0088] 1....

Embodiment 3

[0105] Step 1, weigh tin oxide powder, La 2 o 3 The powder and zirconia grinding balls are treated with the mixed powder symmetrically taken by high-energy ball milling technology to obtain the preliminary mixed oxide powder A, which is specifically implemented according to the following steps:

[0106] 1.1) Weigh nano tin oxide powder, La 2 o 3 powder and zirconia grinding balls, nano tin oxide powder, La 2 o 3 The mass ratio of powder to zirconia balls is 8:5:110;

[0107] 1.2) Add the oxide powder weighed in step 1.1) together with the zirconia balls into the ball milling jar, then add absolute ethanol to the ball milling jar, add 5ml of absolute ethanol for each gram of oxide powder, start the ball mill Ball milling treatment, ball milling time 4h;

[0108] In order to ensure the ball milling effect, during the ball milling process, the total volume of nano-oxide powder, absolute ethanol and zirconia balls accounts for 60% of the ball milling tank volume;

[0109] 1...

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Abstract

The invention discloses a method for preparing a silver-nickel-tin-oxide-doped electric contact material on the basis of a ball-milling method. The method includes the steps of 1, weighing tin oxide powder, other oxide powder and milling balls respectively, and processing the weighed mixed powder to obtain a primarily-mixed oxide powder body A; 2, mixing silver powder, nickel powder and tin powderwith the primarily-mixed oxide powder body prepared in step 1 to form a mixed powder body B, and performing mechanical alloying surface treatment on the mixed powder body B to obtain a mixed powder body C; and 3, sequentially performing annealing, primary press-forming, sintering, re-pressing and re-sintering treatment on the mixed powder body C obtained in step 2 to finally prepare the silver-nickel-tin-oxide-doped electric contact material. The preparation method solves the problems of high cost, long production cycle and complex process in existing silver-nickel-tin-oxide-doped electric contact material and effectively improves the electrical property of the silver-nickel-tin-oxide-doped electric contact material.

Description

technical field [0001] The invention belongs to the technical field of electrical contact materials, and relates to a method for preparing silver-nickel-tin oxide-doped electrical contact materials based on a ball milling method. [0002] technical background [0003] The existing preparation methods of silver-based electrical contact materials are mainly divided into traditional processes and new processes that are beneficial to improve electrical contact performance. [0004] Traditional preparation of Ag-Ni-SnO 2 The method of electrical contact materials has the advantage of making the oxides in the contact materials evenly distributed, which can effectively avoid the poor oxidation area caused by the internal oxidation method. However, most of the traditional processes exist to make Ag-Ni-SnO 2 The electrical conductivity of the electrical contact material is poor, and the material preparation cycle is long, and the powder is easily polluted. [0005] In recent years, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F9/04B22F3/16B22F3/04B22F3/10B22F1/00C22C5/06C22C32/00C22C1/05H01H11/04
CPCB22F9/04B22F3/16B22F3/04B22F3/1007C22C5/06C22C32/0021C22C1/05H01H11/048B22F2009/041B22F2009/043B22F2998/10B22F1/142
Inventor 王俊勃游义博刘松涛思芳姜凤阳杨敏鸽郭敏
Owner XI'AN POLYTECHNIC UNIVERSITY
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