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Far-red light fluorescent powder and light-emitting device comprising fluorescent powder

A technology of red fluorescent powder and light-emitting device, which is applied in the direction of light-emitting materials, electrical components, circuits, etc., can solve the problems of poor water resistance, low luminous efficiency, and poor temperature resistance, and achieve broad application fields, high luminous efficiency, and strong The effect of far-red light emission

Active Publication Date: 2020-12-01
GRIREM ADVANCED MATERIALS CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Based on the above-mentioned situation in the prior art, the object of the present invention is to provide a far-red light phosphor with a light-emitting wavelength range of 680-720nm, which can be excited by blue light, ultraviolet light or near ultraviolet light, so as to solve the current problem. There are technical problems such as low luminous efficiency, poor temperature resistance, and poor water resistance of mid-to-far red phosphors
Another object of the present invention is to provide a light-emitting device containing the far-red light-emitting material, which can realize efficient emission of far-red light under the excitation of blue light, ultraviolet light or near-ultraviolet light, so as to solve the problems in the prior art. The problem of low luminous efficiency of COSCO red light emitting device

Method used

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  • Far-red light fluorescent powder and light-emitting device comprising fluorescent powder
  • Far-red light fluorescent powder and light-emitting device comprising fluorescent powder
  • Far-red light fluorescent powder and light-emitting device comprising fluorescent powder

Examples

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Effect test

Embodiment 1

[0038] The far-red fluorescent powder provided in this embodiment contains a compound formula of 12.6CaO·4.4Al 2 o 3 5ZnO 0.4MnO 2 0.2Na 2 O. According to the stoichiometric ratio of the chemical formula, the oxide raw materials taken symmetrically were ground and mixed to obtain a mixture; the mixture was ground and mixed and then calcined at 1300°C for 5 hours, and the roasted product was obtained after cooling down; the obtained roasted product was After crushing, grinding, grading, sieving and washing, etc., the far-red phosphor intermediate can be obtained.

[0039] Subsequently, the intermediate is coated with tetraethyl orthosilicate in a liquid phase, and the specific process is as follows: first, use alcohol and deionized water, according to the mass ratio of alcohol: deionized water = 1:1, to obtain a mixed solution; then use the above For the mixed solution and the far-red phosphor intermediate, according to the far-red phosphor intermediate: mixed solution = 1:...

Embodiment 21

[0056] The light-emitting device described in Example 21 uses a semiconductor chip with a wavelength of 460nm as the light source, and the light-emitting material is a far-red phosphor, and the chemical formula of the far-red phosphor is 13.8CaO·4.5Al 2 o 3 0.5Ga 2 o 3 · MgO · 5ZnO · 0.2MnO 2 0.1K 2 O, according to the stoichiometric ratio, accurately weigh the oxide raw materials, and grind and mix the obtained oxide raw materials to obtain a mixture; calcinate the mixture at 1300 ° C for 5 hours, and obtain a roasted product after cooling down; obtain the roasted product After crushing, grinding, grading, sieving and washing, the far-red luminescent intermediate is obtained. Subsequently, the intermediate is coated with tetraethyl orthosilicate in a liquid phase, and the specific process is as follows: first, use alcohol and deionized water, according to the mass ratio of alcohol: deionized water = 1:1, to obtain a mixed solution; then use the above For the mixed soluti...

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Abstract

The invention relates to a far-red light fluorescent powder with a light emitting waveband of 680-720nm. The far-red light fluorescent powder can be excited by blue light, ultraviolet light or near ultraviolet light so as to solve the technical problems of low light emitting efficiency, poor temperature resistance, poor water resistance and the like of the far-red light fluorescent powder in the prior art. The far-infrared fluorescent powder can be used for preparing a light-emitting device, has the advantage of high light-emitting efficiency, and can be widely applied to various traditional or novel fields such as full-spectrum healthy lighting, plant lighting, ultrahigh-color-gamut liquid crystal display backlights, calibration light sources and security monitoring fields. And in the light-emitting device, on the basis of being matched with the far-red light fluorescent powder, the visible light fluorescent powder with the emission wavelength range of 450-680 nm and the near-infraredfluorescent powder with the emission wavelength range of 720-1600 nm are used, so that the light-emitting device has stronger far-red light emission and unique application, and the application fieldof the light emitting device is further widened.

Description

technical field [0001] The invention relates to the technical field of luminescent materials, in particular to a far-red phosphor and a luminescent device containing the phosphor. Background technique [0002] White light-emitting diode (Light Emitting Diode, LED), as a new generation of light source products, has the advantages of high light efficiency, low energy consumption, long life, and no pollution. It has been widely used in lighting and display fields, and is a strategic emerging industry that my country focuses on. . With the continuous development of semiconductor lighting technology and the accelerated penetration of market applications, the market's performance requirements for white LED light sources have shifted from simply pursuing "high color rendering and high brightness" to considering the safety and health of the light source, color reproduction, and saturation. , Spectral continuity and other performance parameters of "high quality", the pursuit of full-...

Claims

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Application Information

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IPC IPC(8): C09K11/64C09K11/80C09K11/79C09K11/02H01L33/50
CPCC09K11/7706C09K11/7774C09K11/643C09K11/7739C09K11/7734C09K11/0883C09K11/025C09K11/02H01L33/504
Inventor 刘元红刘荣辉高彤宇陈晓霞薛原马小乐陈观通
Owner GRIREM ADVANCED MATERIALS CO LTD