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Antifriction agent containing modified nanometer hexagonal boron nitride, preparation method of antifriction agent, and lubricating oil

A technology of hexagonal boron nitride and friction reducing agent, applied in chemical instruments and methods, nanotechnology, nanotechnology, etc., can solve the problems of hindering the development of nano-lubricating additives, small size, etc., to increase the difficulty of dispersion and improve extreme pressure resistance. Wear and friction reduction, the effect of increasing the friction reduction performance

Inactive Publication Date: 2020-12-01
安徽省路驰环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nano-sized h-BN spherical particles have many obvious advantages and broad prospects as a lubricant additive, but nanoparticles will show a tendency to aggregate because of their small size, high surface energy, and electrostatic force. Top Questions for Lubricant Additive Development

Method used

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  • Antifriction agent containing modified nanometer hexagonal boron nitride, preparation method of antifriction agent, and lubricating oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] This embodiment provides a kind of friction reducing agent containing modified nano-hexagonal boron nitride, and its preparation method comprises the following steps:

[0027] S1. Add nano-hexagonal boron nitride with a particle size of 80nm and a purity of ≥99.9% to a mixed solution of 10mmol / L Tris buffer (pH=8.5) and absolute ethanol for 30 minutes of ultrasonic dispersion to obtain a dispersion.

[0028] S2. Add dopamine hydrochloride to the above dispersion liquid, carry out stirring reaction in an air atmosphere at 60°C for 6 hours with a constant temperature magnetic stirrer, set the rotation speed to 1000r / min, and then use a rotation speed of 10000r / min to perform centrifugation for solid-liquid separation, and then Washing with alcohol and deionized water in sequence, and finally vacuum-drying at 60° C. to obtain polydopamine-modified nano hexagonal boron nitride.

[0029] S3. Put the above-mentioned polydopamine-modified nano-hexagonal boron nitride in absolu...

Embodiment 2

[0033] This embodiment provides a kind of friction reducing agent containing modified nano-hexagonal boron nitride, and its preparation method comprises the following steps:

[0034] S1. Add nano-hexagonal boron nitride with a particle size of 80nm and a purity of ≥99.9% to a mixed solution of 10mmol / L Tris buffer (pH=8.5) and absolute ethanol for 30 minutes of ultrasonic dispersion to obtain a dispersion.

[0035] S2. Add dopamine hydrochloride to the above dispersion liquid, carry out stirring reaction in an air atmosphere at 60°C for 6 hours with a constant temperature magnetic stirrer, set the rotation speed to 1000r / min, and then use a rotation speed of 10000r / min to perform centrifugation for solid-liquid separation, and then Washing with alcohol and deionized water in sequence, and finally vacuum-drying at 60° C. to obtain polydopamine-modified nano hexagonal boron nitride.

[0036] S3. Put the above-mentioned polydopamine-modified nano-hexagonal boron nitride in absolu...

Embodiment 3

[0040] This embodiment provides a kind of friction reducing agent containing modified nano-hexagonal boron nitride, and its preparation method comprises the following steps:

[0041] S1. Add nano-hexagonal boron nitride with a particle size of 80nm and a purity of ≥99.9% to a mixed solution of 10mmol / L Tris buffer (pH=8.5) and absolute ethanol for 30 minutes of ultrasonic dispersion to obtain a dispersion.

[0042] S2. Add dopamine hydrochloride to the above-mentioned dispersion liquid, carry out the stirring reaction in an air atmosphere at 60°C with a constant temperature magnetic stirrer for 7 hours, set the rotation speed to 1000r / min, and then use a rotation speed of 10000r / min to perform centrifugation for solid-liquid separation, and then Washing with alcohol and deionized water in sequence, and finally vacuum-drying at 60° C. to obtain polydopamine-modified nano hexagonal boron nitride.

[0043] S3. Put the above-mentioned polydopamine-modified nano-hexagonal boron nitri...

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Abstract

The invention is applicable to the field of nanometer lubricating additives, and provides an antifriction agent containing modified nanometer hexagonal boron nitride, a preparation method of the antifriction agent, and lubricating oil. The antifriction agent comprises the following components: the modified nanometer hexagonal boron nitride, a cleaning agent, a stabilizing agent and nitrogen-containing borate, wherein the modified nanometer hexagonal boron nitride is nanometer hexagonal boron nitride modified by polydopamine and long-chain alkylamine. The multifunctional non-toxic nitrogen-containing borate is selected as a basic friction reducer, has excellent extreme-pressure anti-wear and anti-friction properties, very good oxidation stability and excellent sealing adaptability, is non-toxic and odorless, is beneficial for environmental protection, and has better performance than phosphorus-based and sulfur-based additives; and in addition, the modified nanometer hexagonal boron nitride having been subjected to mussel bionic surface modification is selected as a nanometer lubricating additive, and the antifriction performance of nitrogen-containing borate is improved by utilizingthe ball effect and the self-repairing effect of nanometer particles.

Description

technical field [0001] The invention belongs to the field of nano lubricating additives, in particular to a friction reducer containing modified nano hexagonal boron nitride, a preparation method thereof and a lubricating oil. Background technique [0002] Engineering materials are damaged from the free surface of the material due to friction, wear and corrosion. Statistics show that one-third or even half of the world's energy is consumed to overcome friction. Reducing friction and reducing wear is of great significance to the development of the national economy. As a nano-lubricating additive, nanoparticles can greatly improve the performance of lubricating oil. This is because it can realize the "ball" effect, film-forming effect and self-repairing effect on the friction contact surface, thereby reducing friction, reducing wear, and improving oil quality. Energy utilization efficiency and service life of parts. Nanoparticles have broad prospects as a new type of lubrican...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M125/20C10M167/00C01B21/064B82Y30/00C10N30/06
CPCC10M125/20C10M167/00C01B21/0648B82Y30/00C10M2201/061C10M2201/14C10M2215/28C10M2207/027C10M2227/061
Inventor 宛新东
Owner 安徽省路驰环保科技有限公司
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