A Transition Metal Modified Pyridine Nitrogen Conjugated Microporous Polymer Composite Photocatalyst

A composite catalyst, conjugated polymer technology, applied in organic compound/hydride/coordination complex catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problem of no universality, complex operation, preparation The problem of high cost, to achieve the effect of simple equipment, simple operation and good performance

Active Publication Date: 2022-01-11
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The technical problem to be solved by the present invention is to provide a transition metal-modified pyridine nitrogen-based conjugated microporous polymer composite photocatalyst, which overcomes the defects of the prior art such as complicated operation, high preparation cost, and no universality.

Method used

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  • A Transition Metal Modified Pyridine Nitrogen Conjugated Microporous Polymer Composite Photocatalyst
  • A Transition Metal Modified Pyridine Nitrogen Conjugated Microporous Polymer Composite Photocatalyst
  • A Transition Metal Modified Pyridine Nitrogen Conjugated Microporous Polymer Composite Photocatalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] (1) 0.636g of 2,2'-bipyridyl-5,5'-dicarbaldehyde, 0.973g of 1,3-diacetylbenzene and 6.9g of ammonium acetate were added to a 250mL round bottom flask;

[0046] (2) Add 150 mL of pyridine to the round bottom flask in step (1), and stir at room temperature for 20 min until the solid matter is completely dissolved;

[0047] (3) After the solid matter is dissolved, put the round-bottomed flask in step (2) into an oil bath at 115° C. to react for 24 hours, and wash with suction to obtain powder;

[0048] (4) Wash the obtained powder in deionized water and chloroform at 60° C. for 24 hours in sequence, filter with suction, and dry in a vacuum oven for 72 hours to obtain a pyridine nitrogen-based conjugated microporous polymer;

[0049] The polymer structural formula of the pyridine nitrogen-based conjugated microporous polymer prepared in step (4) is:

[0050]

[0051] (5) Nickelocene and the obtained pyridyl nitrogen-based conjugated microporous polymer are put into the tu...

Embodiment 2

[0059] (1) 0.636g of 2,2'-bipyridyl-5,5'-dicarbaldehyde, 0.973g of 1,3-diacetylbenzene and 6.9g of ammonium acetate were added to a 250mL round bottom flask;

[0060] (2) Add 150 mL of pyridine to the round bottom flask in step (1), and stir at room temperature for 20 min until the solid matter is completely dissolved;

[0061] (3) After the solid matter is dissolved, put the round-bottomed flask in step (2) into an oil bath at 115° C. to react for 24 hours, and wash with suction to obtain powder;

[0062] (4) Wash the obtained powder in deionized water and chloroform at 60° C. for 24 hours in sequence, filter with suction, and dry in a vacuum oven for 72 hours to obtain a pyridine nitrogen-based conjugated microporous polymer;

[0063] (5) Put the ferrocene and the obtained pyridine nitrogen-based conjugated microporous polymer into the tube furnace according to the mass percentage of 30wt%, and in the high-purity nitrogen (99.999%) atmosphere, at 2 ℃ / minn The heating rate i...

Embodiment 3

[0066] (1) 0.636g of 2,2'-bipyridyl-5,5'-dicarbaldehyde, 0.973g of 1,3-diacetylbenzene and 6.9g of ammonium acetate were added to a 250mL round bottom flask;

[0067] (2) Add 150 mL of pyridine to the round bottom flask in step (1), and stir at room temperature for 20 min until the solid matter is completely dissolved;

[0068] (3) After the solid matter is dissolved, put the round-bottomed flask in step (2) into an oil bath at 115° C. to react for 24 hours, and wash with suction to obtain powder;

[0069] (4) Wash the obtained powder in deionized water and chloroform at 60° C. for 24 hours in sequence, filter with suction, and dry in a vacuum oven for 72 hours to obtain a pyridine nitrogen-based conjugated microporous polymer;

[0070] (5) Put the cobaltocene and the obtained pyridine nitrogen-based conjugated microporous polymer into the tube furnace according to the mass percentage of 30wt%. The heating rate is to raise the temperature to 150° C., keep the temperature for ...

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Abstract

The invention relates to a transition metal-modified pyridine nitrogen-based conjugated microporous polymer composite photocatalyst. Synthesis and ring amination reaction, and then the transition metal-modified pyridine nitrogen-based conjugated microporous polymer composite photocatalyst was prepared by vapor phase deposition, so that it has a good application in the photo-splitting of water for hydrogen production. The photocatalyst obtained by the invention has good photocatalytic hydrogen production performance and high hydrogen production rate; the invention adopts a vapor phase deposition method, and has simple process, simple equipment and simple operation.

Description

technical field [0001] The invention belongs to the field of photocatalysts, in particular to a transition metal-modified pyridine nitrogen-based conjugated microporous polymer composite photocatalyst. Background technique [0002] Energy and the environment are two core issues facing the world today. Human life and technological development are closely related to energy. The burning of traditional fossil fuels emits a large amount of greenhouse gases and causes serious damage to the environment. Therefore, it is urgent to find new clean energy sources. Hydrogen energy helps to solve global environmental pollution and energy security issues, so it becomes an ideal substitute for traditional energy. Among them, photocatalytic water splitting is the main path for hydrogen production, and photocatalytic technology will become an effective means to solve energy and environmental problems in the future. [0003] Conjugated microporous polymers are rigid macromolecules composed ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G61/12B01J31/06
CPCC08G61/122B01J35/004B01J31/063B01J31/06C08G2261/12C08G2261/18C08G2261/3221C08G2261/312C08G2261/70C08G2261/72
Inventor 廖耀祖杨晨何颜程中桦
Owner DONGHUA UNIV
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