Antiskid insulating leather shoes
A leather shoes and anti-skid technology, applied in the field of clothing manufacturing, can solve problems such as affecting the use experience, and achieve the effects of improving insulation performance and anti-skid performance, improving anti-skid performance and improving friction coefficient.
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Embodiment 1
[0020] A non-slip insulating leather shoe, comprising a sole material and a vamp material, the vamp material is cowhide; the sole material is made of the following components in parts by weight: 50 parts of modified styrene-butadiene rubber, ethylene-tetrafluoroethylene 40 parts of copolymers, 15 parts of hollow glass microspheres, 6 parts of vulcanizing agent DCBP, 6 parts of diphenylmethane diisocyanate, 12 parts of blowing agent; The preparation method of the modified styrene-butadiene rubber is as follows: in the polymerization kettle, Add the cyclohexane-hexane mixed glue solution of 3L solution polystyrene butadiene rubber, 23g dibenzoyl peroxide and 90g sebacic anhydride, pass into N 2 Gas, stirred at 180 rpm for 15 minutes, and reacted at 65°C for 3 hours; after the reaction was completed, the product was precipitated with absolute ethanol, then dried in a vacuum oven for 6 hours, and finally the product was extracted with absolute ethanol for 12 hours. Put it in a dry...
Embodiment 2
[0026] A non-slip insulating leather shoe, comprising a sole material and a vamp material, the vamp material is sheepskin; the sole material is made of the following components in parts by weight: 42 parts of modified styrene-butadiene rubber, ethylene-tetrafluoroethylene 32 parts of copolymers, 12 parts of barium stearate, 4 parts of sulfur, 3 parts of formaldehyde condensates of sulfonated acetone, and 8 parts of foaming agent; the preparation method of the modified styrene-butadiene rubber is as follows: in the polymerization kettle, add The cyclohexane-hexane mixed glue solution of 3L solution polystyrene butadiene rubber, 23g dibenzoyl peroxide and 90g sebacic anhydride, pass into N 2 Gas, stirring at 150 rpm for 20 minutes, and reacting at 65°C for 4 hours; after the reaction was completed, the product was precipitated with absolute ethanol, then dried in a vacuum oven for 5 hours, and finally the product was extracted with absolute ethanol for 11 hours. Put it in a dryi...
Embodiment 3
[0032] A kind of non-slip insulating leather shoes, comprising a sole material and a vamp material, the vamp material is crocodile leather; the sole material is made of the following components in parts by weight: 60 parts of modified styrene-butadiene rubber, ethylene-tetrafluoroethylene 50 parts of ethylene copolymers, 20 parts of calcium carbonate, 9 parts of vulcanizing agent VA-7, 8 parts of nonylphenol polyoxyethylene ethers, 15 parts of blowing agents; The preparation method of described modified styrene-butadiene rubber is as follows: In, add the cyclohexane-hexane mixed glue solution of 3L solution-polymerized styrene-butadiene rubber, 23g dibenzoyl peroxide and 90g sebacic anhydride, pass into N 2 Gas, stirred at 200 rpm for 20 minutes, and reacted at 65°C for 2 hours; after the reaction was completed, the product was precipitated with absolute ethanol, then dried in a vacuum oven for 4 hours, and finally the product was extracted with absolute ethanol for 16 hours. ...
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