Preparation method and application of sulfur-doped g-C3N4/alpha-ZrP-carbonized ZIF-8 positive electrode material
A technology of ZIF-8 and positive electrode materials, applied in the direction of positive electrodes, battery electrodes, electrochemical generators, etc., can solve the problems of large volume expansion, low actual capacity, long-chain polysulfide shuttle effect, etc., to promote transformation, Improvement of low capacity, improvement of coulombic efficiency and lifetime
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0021] Step 1: Add 1.68g of melamine, 12g of urea and 4g of SBA-15 molecular sieve into 50ml of deionized water, stir in a water bath at 60°C for 60min, then dry and grind in a vacuum oven at 70°C, then mix the ground The powder was placed in a tube furnace at N 2 Under the protection of the atmosphere, the temperature was raised to 560°C at a rate of 2°C / min, calcined for 4h, and after cooling to room temperature, the sample was ground again and soaked in a mixed solution of 44.5ml of 5% hydrofluoric acid and 5.5ml of ethanol for 24h. The samples were then lyophilized to obtain mesoporous g-C 3 N 4 powder.
[0022] Step 2: Dissolve 2.74g of zinc nitrate and 6.18g of 2-methylimidazole in 40mL of methanol respectively, and then add the two solutions simultaneously to the solution containing 12.3g of mesoporous g-C 3 N 4 In 50ml methanol of the powder, the mixture was sonicated at room temperature for 4h and then sealed and aged for 30h, then the solution was centrifuged and...
Embodiment 2
[0026] Step 1: Add 2.52g of melamine, 18g of urea and 4.5g of SBA-15 molecular sieve into 50ml of deionized water, stir in a water bath at 70°C for 40min, then dry and grind in a vacuum oven at 80°C, and then put the ground The mixed powders were placed in a tube furnace at N 2Under the protection of the atmosphere, the temperature was raised to 560°C at a rate of 2°C / min, calcined for 6h, and after cooling to room temperature, the sample was ground again and soaked in a mixed solution of 46.2ml of 5% hydrofluoric acid and 3.8ml of ethanol for 18h. The samples were then lyophilized to obtain mesoporous g-C 3 N 4 powder.
[0027] Step 2: Dissolve 2.65g of zinc nitrate and 5.8g of 2-methylimidazole in 40mL of methanol respectively, and then add the two solutions simultaneously to the solution containing 16.4g of mesoporous g-C 3 N 4 In 50ml methanol of the powder, the mixture was sonicated at room temperature for 3h and then sealed and aged for 24h, then the solution was cen...
Embodiment 3
[0031] Step 1: Add 2.85g of melamine, 15g of urea and 4.2g of SBA-15 molecular sieve into 50ml of deionized water, stir in a water bath at 68°C for 45min, then dry and grind in a vacuum oven at 75°C, then put the ground The mixed powders were placed in a tube furnace at N 2 Under the protection of the atmosphere, the temperature was raised to 560°C at a rate of 2°C / min, and calcined for 5.5 hours. After cooling to room temperature, the sample was ground again and soaked in 45ml of 5% hydrofluoric acid and 5ml ethanol mixed solution for 20h. After soaking The samples were lyophilized to obtain mesoporous g-C 3 N 4 powder.
[0032] Step 2: 3.21g of zinc nitrate and 7.39g of 2-methylimidazole were dissolved in 40mL of methanol, and then the two solutions were simultaneously added to the solution containing 16.1g of mesoporous g-C 3 N 4 In 50ml of methanol powder, the mixture was sonicated at room temperature for 3.2h, sealed and aged for 28h, then the solution was centrifuged...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com