High-conductivity inorganic solid electrolyte slurry and preparation method thereof, diaphragm and lithium battery
A solid electrolyte, high conductivity technology, applied in the direction of electrolyte immobilization/gelation, secondary batteries, circuits, etc., can solve problems such as explosion, poor electrolyte wettability, fire, etc., to avoid potential safety hazards and improve Effects of interface compatibility, fire prevention, etc.
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[0019] In order to improve the safety and service life of lithium batteries and avoid potential safety hazards caused by the use of liquid electrolytes, the invention provides a method for preparing a high-conductivity inorganic solid-state electrolyte slurry, which includes the following steps: The electrolyte is organically modified; to prepare a high-conductivity inorganic solid electrolyte solution, add the organically modified high-conductivity inorganic solid electrolyte to the dispersant solution for stirring; high-speed dispersion, that is, to the high-conductivity inorganic solid electrolyte solution Add a thickener solution and perform high-speed dispersion; uniform dispersion, that is, add a binder to the high-conductivity inorganic solid electrolyte solution after high-speed dispersion and make it uniformly dispersed.
[0020] Wherein, the high-conductivity inorganic solid-state electrolyte is LiT 2 (PO 4 ) 3 , wherein T is one or more of Ti, Cr, Zr; the LiT 2 (...
Embodiment 1
[0045] (1) Organic modification of high-conductivity inorganic solid-state electrolytes
[0046] 40kg of LiTi with a particle size D50 of 0.6 μm 2 (PO 4 ) 3 Powder and 0.05kg of PEO were added to 60kg of water to prepare a high-conductivity inorganic solid electrolyte aqueous solution, and 0.2kg of vinyltriethoxysilane was added to the prepared high-conductivity inorganic solid electrolyte aqueous solution, and stirred for 30 minutes.
[0047] (2) Preparation of high conductivity inorganic solid electrolyte solution
[0048] Add 0.24 kg of sodium dodecylbenzenesulfonate to the organically modified high-conductivity inorganic solid-state electrolyte solution, and continue stirring.
[0049] (3) High-speed dispersion
[0050] Add 3.3 kg of sodium carboxymethyl cellulose to the solution in (2), and disperse at a high speed by means of dual planetary agitation.
[0051] (4) uniform dispersion
[0052] Add 1.8 kg of acrylic binder to the solution in (3), and stir for 50 min f...
Embodiment 2
[0060] (1) Organic modification of high-conductivity inorganic solid-state electrolytes
[0061] 40kg of LiCr with a particle size D50 of 0.6 μm 2 (PO 4 ) 3 Powder and 0.05kg of PEO were added to 60kg of water to prepare a high-conductivity inorganic solid electrolyte aqueous solution, and 0.2kg of vinyltriethoxysilane was added to the prepared high-conductivity inorganic solid electrolyte aqueous solution, and stirred for 30 minutes.
[0062] (2) Preparation of high conductivity inorganic solid electrolyte solution
[0063] Add 0.24 kg of sodium dodecylbenzenesulfonate to the organically modified high-conductivity inorganic solid-state electrolyte solution, and continue stirring.
[0064] (3) High-speed dispersion
[0065] Add 1.44 kg of sodium carboxymethylcellulose to the solution in (2), and disperse at high speed by means of dual planetary agitation.
[0066] (4) uniform dispersion
[0067] Add 3.99 kg of acrylic binder to the solution in (3), and stir for 50 min fo...
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