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High-conductivity inorganic solid electrolyte slurry and preparation method thereof, diaphragm and lithium battery

A solid electrolyte, high conductivity technology, applied in the direction of electrolyte immobilization/gelation, secondary batteries, circuits, etc., can solve problems such as explosion, poor electrolyte wettability, fire, etc., to avoid potential safety hazards and improve Effects of interface compatibility, fire prevention, etc.

Inactive Publication Date: 2021-01-08
JIANGSU HORIZON NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, commercial lithium battery separators are mainly polyolefin porous membranes. Although this type of separator has the advantages of good chemical inertness, easy processing, and low cost, the current mainstream lithium batteries often use liquid electrolytes, and the low surface energy of polyolefins and The stretching pore-forming process makes this type of separator have the disadvantage of poor electrolyte wettability. At the same time, the liquid electrolyte lithium battery contains flammable liquid organic substances, which have potential safety hazards such as fire and explosion.

Method used

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  • High-conductivity inorganic solid electrolyte slurry and preparation method thereof, diaphragm and lithium battery
  • High-conductivity inorganic solid electrolyte slurry and preparation method thereof, diaphragm and lithium battery
  • High-conductivity inorganic solid electrolyte slurry and preparation method thereof, diaphragm and lithium battery

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preparation example Construction

[0019] In order to improve the safety and service life of lithium batteries and avoid potential safety hazards caused by the use of liquid electrolytes, the invention provides a method for preparing a high-conductivity inorganic solid-state electrolyte slurry, which includes the following steps: The electrolyte is organically modified; to prepare a high-conductivity inorganic solid electrolyte solution, add the organically modified high-conductivity inorganic solid electrolyte to the dispersant solution for stirring; high-speed dispersion, that is, to the high-conductivity inorganic solid electrolyte solution Add a thickener solution and perform high-speed dispersion; uniform dispersion, that is, add a binder to the high-conductivity inorganic solid electrolyte solution after high-speed dispersion and make it uniformly dispersed.

[0020] Wherein, the high-conductivity inorganic solid-state electrolyte is LiT 2 (PO 4 ) 3 , wherein T is one or more of Ti, Cr, Zr; the LiT 2 (...

Embodiment 1

[0045] (1) Organic modification of high-conductivity inorganic solid-state electrolytes

[0046] 40kg of LiTi with a particle size D50 of 0.6 μm 2 (PO 4 ) 3 Powder and 0.05kg of PEO were added to 60kg of water to prepare a high-conductivity inorganic solid electrolyte aqueous solution, and 0.2kg of vinyltriethoxysilane was added to the prepared high-conductivity inorganic solid electrolyte aqueous solution, and stirred for 30 minutes.

[0047] (2) Preparation of high conductivity inorganic solid electrolyte solution

[0048] Add 0.24 kg of sodium dodecylbenzenesulfonate to the organically modified high-conductivity inorganic solid-state electrolyte solution, and continue stirring.

[0049] (3) High-speed dispersion

[0050] Add 3.3 kg of sodium carboxymethyl cellulose to the solution in (2), and disperse at a high speed by means of dual planetary agitation.

[0051] (4) uniform dispersion

[0052] Add 1.8 kg of acrylic binder to the solution in (3), and stir for 50 min f...

Embodiment 2

[0060] (1) Organic modification of high-conductivity inorganic solid-state electrolytes

[0061] 40kg of LiCr with a particle size D50 of 0.6 μm 2 (PO 4 ) 3 Powder and 0.05kg of PEO were added to 60kg of water to prepare a high-conductivity inorganic solid electrolyte aqueous solution, and 0.2kg of vinyltriethoxysilane was added to the prepared high-conductivity inorganic solid electrolyte aqueous solution, and stirred for 30 minutes.

[0062] (2) Preparation of high conductivity inorganic solid electrolyte solution

[0063] Add 0.24 kg of sodium dodecylbenzenesulfonate to the organically modified high-conductivity inorganic solid-state electrolyte solution, and continue stirring.

[0064] (3) High-speed dispersion

[0065] Add 1.44 kg of sodium carboxymethylcellulose to the solution in (2), and disperse at high speed by means of dual planetary agitation.

[0066] (4) uniform dispersion

[0067] Add 3.99 kg of acrylic binder to the solution in (3), and stir for 50 min fo...

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Abstract

The invention belongs to the technical field of lithium battery manufacturing, and particularly relates to high-conductivity inorganic solid electrolyte slurry, a preparation method of the high-conductivity inorganic solid electrolyte slurry, a diaphragm and a lithium battery. The method comprises the following steps: preparing ahigh-conductivity inorganic solid electrolyte solution, namely addinga high-conductivity inorganic solid electrolyte into a dispersing agent solution, carrying out stirring, and adding a silane coupling agent; performing high-speed dispersion, namely adding a thickener solution into the high-conductivity inorganic solid electrolyte solution and performing high-speed dispersion; and uniformly dispersing, namely adding a binding agent into the high-conductivity inorganic solid electrolyte solution subjected to high-speed dispersion, and uniformly dispersing the binding agent. According to the high-conductivity inorganic solid electrolyte slurry disclosed by theinvention, the silane coupling agent and the binding agent are added into the high-conductivity inorganic solid electrolyte solution, so that the prepared high-conductivity inorganic solid electrolyteslurry has relatively high conductivity.

Description

technical field [0001] The invention belongs to the technical field of lithium battery manufacturing, and in particular relates to a high-conductivity inorganic solid-state electrolyte slurry, a preparation method, a separator, and a lithium battery. Background technique [0002] Lithium batteries are widely used in energy storage power systems such as hydraulic power, fire power, wind power and solar power stations, uninterruptible power supplies for post and telecommunications, as well as power tools, electric bicycles, electric motorcycles, electric vehicles, military equipment, aerospace and other fields. [0003] As a key part of the lithium-ion battery, the separator mainly plays the role of isolating the positive and negative electrodes, preventing the battery from short circuiting, retaining the electrolyte, and allowing lithium ions to pass through. At present, commercial lithium battery separators are mainly polyolefin porous membranes. Although this type of separa...

Claims

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Application Information

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IPC IPC(8): H01M10/0562H01M10/0525
CPCH01M10/0525H01M10/0562H01M2300/0085Y02E60/10
Inventor 王成豪李正林翁星星陈朝晖贡晶晶
Owner JIANGSU HORIZON NEW ENERGY TECH CO LTD
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