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A TPU non -slip cushion and its preparation method

A technology of anti-slip gaskets and oligomer polyols, which is applied in the field of polyurethane materials, can solve the problems that it is difficult to fully meet the high-shear working environment requirements of anti-slip gaskets, and the low strength and wear resistance of pure TPU materials.

Active Publication Date: 2021-09-24
DONGGUAN XIONGLIN NEW MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the strength and wear resistance of pure TPU materials are relatively low, and it is difficult to fully meet the high-shear working environment requirements of anti-skid gaskets.

Method used

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  • A TPU non -slip cushion and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] The present embodiment provides a kind of TPU non-slip pad, comprises the raw material component of following parts by weight:

[0050] 30 parts of diisocyanate, 100 parts of oligomer polyol, 20 parts of melamine formaldehyde resin (515# of Hangzhou Zhuoli Chemical), 20 parts of basalt fiber, 5 parts of quartz sand, 6 parts of aminosilane coupling agent and 0.2 part of catalyst;

[0051] Among them, the diisocyanate is 4,4'-diphenylmethane diisocyanate; the oligomer polyol is polycarbonate polyol with a number average molecular weight of 2000 and a hydroxyl value of 55 mg KOH / g; the average diameter of basalt fibers is 3 μm , the average length is 8mm; the D50 particle size of quartz sand is 10μm; the aminosilane coupling agent is γ-aminopropyltrimethoxysilane; the catalyst is dibutyltin dilaurate.

[0052] The preparation method of above-mentioned TPU antiskid gasket is as follows:

[0053] (1) Add basalt fiber, quartz sand and aminosilane coupling agent into a high-s...

Embodiment 2

[0059] The present embodiment provides a kind of TPU non-slip pad, comprises the raw material component of following parts by weight:

[0060] 40 parts of diisocyanate, 80 parts of oligomer polyol, 30 parts of melamine formaldehyde resin (515# of Hangzhou Zhuoli Chemical Industry), 10 parts of basalt fiber, 10 parts of quartz sand, 3 parts of aminosilane coupling agent and 1 part of catalyst;

[0061] Among them, the diisocyanate is 2,6-toluene diisocyanate; the oligomer polyol is polycaprolactone polyol, the number average molecular weight is 1500, and the hydroxyl value is 50 mg KOH / g; the average diameter of basalt fibers is 3 μm, and the average length The D50 particle size of quartz sand is 10 μm; the aminosilane coupling agent is γ-aminopropyltriethoxysilane; the catalyst is dibutyltin dilaurate.

[0062] The preparation method of above-mentioned TPU antiskid gasket is as follows:

[0063] (1) Add basalt fiber, quartz sand and aminosilane coupling agent into a high-spee...

Embodiment 3

[0069] The present embodiment provides a kind of TPU non-slip pad, comprises the raw material component of following parts by weight:

[0070] 32 parts of diisocyanate, 90 parts of oligomer polyol, 23 parts of melamine formaldehyde resin (515# of Hangzhou Zhuoli Chemical), 15 parts of basalt fiber, 8 parts of quartz sand, 4 parts of aminosilane coupling agent and 0.5 part of catalyst;

[0071] Among them, the diisocyanate is p-phenylene diisocyanate; the oligomer polyol is polycarbonate polyol, the number average molecular weight is 2000, and the hydroxyl value is 55 mg KOH / g; the average diameter of basalt fiber is 3 μm, and the average length is 8 mm; The D50 particle size of the sand is 10 μm; the aminosilane coupling agent is γ-aminopropyltrimethoxysilane; the catalyst is dibutyltin dilaurate.

[0072] The preparation method of above-mentioned TPU antiskid gasket is as follows:

[0073] (1) Add basalt fiber, quartz sand and aminosilane coupling agent into a high-speed mix...

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Abstract

The invention provides a TPU anti-skid gasket and a preparation method thereof. The TPU anti-skid gasket includes the following raw material components in parts by weight: 30-40 parts of diisocyanate, 80-100 parts of oligomer polyol, 20-30 parts of melamine formaldehyde resin, 10-20 parts of basalt fiber, quartz sand 5‑10 parts, 3‑6 parts of aminosilane coupling agent and 0.2‑1 part of catalyst. The TPU anti-slip gasket is prepared by mixing and reacting the components, then laminating and punching to shape. The TPU anti-slip gasket provided by the invention has high tensile strength, tear strength, friction coefficient and wear resistance, can be used for connection and fixation between workpieces, and plays the role of anti-slip buffer.

Description

technical field [0001] The invention belongs to the technical field of polyurethane materials, and in particular relates to a TPU anti-skid gasket and a preparation method thereof. Background technique [0002] Thermoplastic polyurethane elastomer (TPU) is a block-type polymer material polymerized with oligomer diol, diisocyanate and small molecule chain extender as basic raw materials. It has both thermoplasticity and mechanical strength of plastics, It also has the elasticity of rubber, and has the advantages of high mechanical strength, wide hardness range, and good flexibility. Moreover, its raw materials are diverse, its molecular structure is highly adjustable, and its product performance can be designed according to needs. This makes TPU widely used in elastomers, foam plastics, coatings, adhesives, shoe materials, sports equipment and other fields. [0003] The connection between mechanical workpieces is usually fixed with bolts and nuts. At this time, anti-skid ga...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L75/04C08L75/06C08L61/28C08K7/10C08K3/36C08K5/544C08J5/18C08G18/76C08G18/44C08G18/42
CPCC08J5/18C08G18/7671C08G18/7614C08G18/44C08G18/4277C08J2375/04C08J2375/06C08J2461/28C08K7/10C08K3/36C08K5/544C08K2201/003C08K2201/004
Inventor 何建雄杨博
Owner DONGGUAN XIONGLIN NEW MATERIAL TECH