Waste oil-based mud treatment fluid, preparation method thereof and method for treating oil-based mud
A technology of oil-based mud and treatment fluid, applied in sludge treatment, water/sludge/sewage treatment, chemical instruments and methods, etc., can solve the problems of resource waste, climate sensitivity, and long time for biological domestication of bacteria, etc., to achieve Realize the effect of recycling
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[0028] In the present invention, the nonionic surfactant is preferably a polyetheramine modified silicone nonionic surfactant. In the present invention, the preparation method of the polyetheramine modified silicone nonionic surfactant preferably comprises the following steps:
[0029] Mix polyether amine, catalyst and silicone for chemical grafting reaction to obtain reaction solution;
[0030] The reaction solution was added into dichloromethane, allowed to stand for stratification, and the obtained lower layer liquid was subjected to vacuum distillation to obtain a polyetheramine-modified organosilicon nonionic surfactant.
[0031] In the present invention, the polyetheramine, the catalyst and the organic silicon are preferably mixed to perform a chemical grafting reaction to obtain a reaction liquid. In the present invention, the number average molecular weight of the polyetheramine is preferably 200-3000, more preferably 230-2000, even more preferably 600. In the presen...
Embodiment 1
[0059] Select 100g of polyetheramine, which is D230 with a molecular weight of 230 as the main chain, use chloroplatinic acid as a catalyst, and add a catalyst dosage of 1.0g. When the temperature is 80°C, add 30g of methyl silicone oil drop by drop (the dropping speed is 45 drops / min), after the addition is complete, continue to stir and react at 80°C for 120min; cool to room temperature, adjust the pH to 7 with 1wt.% dilute hydrochloric acid at room temperature, and pour the resulting reaction solution into 100g of dichloromethane solution after adjustment, Pour the lower layer liquid after standing and stratifying into a rotary evaporator, and distill under reduced pressure (temperature is 25°C, pressure is 3.15kPa, time is 120min) to remove unreacted impurities to obtain polyetheramine modified silicone Ionic surfactants, counted as silicon-containing D230;
[0060] At room temperature, the silicon-containing D230 and sodium lauryl sulfate were mixed according to a mass r...
Embodiment 2
[0064] Select 100g of polyetheramine, the polyetheramine with a molecular weight of 2000 as the main chain, take chloroplatinic acid as the catalyst, add the catalyst in an amount of 1.0g, and when the temperature is 120°C, add 30g of methyl silicone oil dropwise (the dropping speed is 60 drops / min), after the addition is complete, continue to stir and react at 100°C for 120min; cool to room temperature, adjust the pH to 7 with 1wt.% dilute hydrochloric acid at room temperature, and pour the resulting reaction solution into 100g of dichloromethane after adjustment In the solution, pour the lower layer liquid after standing and stratifying into a rotary evaporator, and distill under reduced pressure (temperature is 25°C, pressure is 3.05kPa, time is 120min60s) to remove unreacted impurities to obtain polyetheramine modified Silicone nonionic surfactants are counted as silicon-containing D2000;
[0065] At room temperature, the silicon-containing D2000 and sodium lauryl sulfate ...
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