Flame-retardant polyurethane material and preparation method thereof
A polyurethane material and a flame-retardant technology, applied in the field of flame-retardant polyurethane materials and their preparation, can solve the problems of polyurethane water absorption defects that cannot be improved, single phosphorus-containing flame retardant, low flame retardant efficiency, etc., and achieve reduced performance. The effect of reducing, improving hydrophobicity and improving flame retardant performance
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[0038]Example 1
[0039](1) Put 40g of polytetrahydrofuran, 10g of 6-heptene-2,4-diol, and 0.1g of hydroquinone into the reactor, and heat to 80r / min while stirring.oC. Vacuum to -0.04Mpa, keep it for 3h, remove the moisture in the alcohol, then pass nitrogen to normal pressure, cool down, add 20g of hexamethylene diisocyanate, 0.01g of bis(dodecylthio) two Tin tin, heat to 50oC, react for 4h, lower the temperature to obtain the prepolymer;
[0040](2) Add 1g 1,4-butanediol, 5g spirodihydroindene monomer, 5g methacryloyl ethoxy phosphate, 0.1g free radical initiator to the prepolymer, and heat while stirring at 200r / min. To 50oC, react for 3h, vacuum to -0.04, hold for 3h, remove bubbles, then pour the reaction liquid into the mold, 100oC continues to react for 8h, and the temperature is reduced to 50oC cured for 48h to obtain a flame-retardant polyurethane material.
[0041]Further, the preparation method of the spirodihydroindene monomer is:
[0042]Under the protection of nitrogen, mix 19g o...
Example Embodiment
[0044]Example 2
[0045](1) Add 45.7g of polypropylene glycol, 11.6g of androstene glycol, and 0.3g of 1,4-diquinone to the reactor, and heat to 89.6 while stirring at 200r / min.oC, evacuate to -0.06Mpa, keep for 2.4h, remove the moisture in the alcohol, then blow in nitrogen to normal pressure, cool down, add 21.2g of biuret triisocyanate, 0.03g of tetramethylguanidine, and heat to 57.4oC, react for 3.5h, lower the temperature to obtain the prepolymer;
[0046](2) Add 1.7g 1,4-bishydroxyethoxybenzene, 5.9g spirodihydroindene monomer, 6.1g ethylene glycol methacrylate phosphate, 0.3g free radical initiator to the prepolymer, 200r / min while stirring and heat to 54.6oC, react for 2.6h, vacuum to -0.06, hold for 2.3h, remove bubbles, and then pour the reaction liquid into the mold, 105.2oC continues to react for 6.9h, and the temperature drops to 47.4oC cured for 42.1h to obtain a flame-retardant polyurethane material.
[0047]Further, the preparation method of the spirodihydroindene monomer is...
Example Embodiment
[0050]Example 3
[0051](1) Add 48.7g of polycarbonate diol, 13.9g of 6-heptene-2,4-diol, and 0.5g of 2-tert-butyl hydroquinone to the reactor, and stir at 200r / min. While heating to 102oC, vacuumize to -0.08Mpa, keep for 2h, remove the moisture in the alcohol, then blow in nitrogen to normal pressure, cool down, add 23.6g 1,5-naphthalene diisocyanate, 0.05g stannous oxalate, and heat to 64.4oC, react for 2.8h, and lower the temperature to obtain the prepolymer;
[0052](2) Add 2.4g glycerol, 6.6g spiroindene monomer, 6.8g SPMA, 0.4g free radical initiator to the prepolymer, and heat to 57.9 while stirring at 200r / minoC, react for 2.1h, vacuum to -0.08, hold for 1.7h, remove bubbles, then pour the reaction liquid into the mold, 109.5oC continues to react for 5.8h, and the temperature drops to 44.7oC curing for 36.7h to obtain a flame-retardant polyurethane material.
[0053]Further, the preparation method of the spirodihydroindene monomer is:
[0054]Under the protection of nitrogen, mix 22g of...
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