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72results about How to "Improve hydrophobic properties" patented technology

Method for preparing sulfonic acid group-modified mesoporous material-loaded heteropolyacid catalyst and application thereof during esterification reaction

The present invention discloses a method for preparing a sulfonic acid group-modified mesoporous material-loaded heteropolyacid catalyst and the application thereof during the esterification reaction. 3-mercapto propyl trimethoxy silane is adopted as an organic silicon source, and tetraethoxysilane is adopted as an inorganic silicon source. A tri-block copolymer is adopted as a template agent, and H2O2 solution is adopted as an oxidant. Phosphotungstic acid is added as an active ingredient and the sulfonic acid group-modified mesoporous material-loaded heteropolyacid catalyst is obtained through the one-step hydro-thermal synthesis process based on the copolycondensation method in the acidic condition. According to the technical scheme of the invention, the catalyst has the advantage of strong acidity, and the specific surface area thereof is 300-600 m2/g. The pore volume of the catalyst is 0.4-1.4 cm3/g, and the pore diameter of the catalyst is 3-7 nm. When the catalyst is used for catalyzing the esterification reaction of cyclohexene and formic acid, the catalyst exhibits good catalytic activity. The conversion rate of cyclohexene can reach 87% and the selectivity of cyclohexyl formate is up to 99%. Moreover, even after the catalyst is recycled, the catalyst is still good in activity. Therefore, the catalyst can be recycled and used repeatedly, and has a considerable industrial application prospect.
Owner:XIANGTAN UNIV

Method for preparing super-hydrophobic flame retardant fabric through one pot method

The invention discloses a method for preparing super-hydrophobic flame retardant fabric through a one pot method. The method comprises the steps that oxygen plasma corona is adopted for treating the fabric; at 25-50 DEG C, organic solvent, tetraethoxysilane, hydroxyl-terminated polydimethylsiloxane and ammonium polyphosphate are mixed, mixed liquid is obtained, the fabric is added, stirring is conducted, and ammonium polyphosphate is deposited on the surface of the fabric through hydrogen-bond interaction; the pH value of the mixed liquid is adjusted to be 8-9; stirring continues to be conducted, tetraethoxysilane and hydroxyl-terminated polydimethylsiloxane are subjected to a dehydration condensation reaction, a generated polysiloxane-silicon dioxide hybrid and ammonium polyphosphate forma composite coating with a micro-nano structure, and the surface of the fabric is wrapped by the composite coating; rinsing and drying are conducted, and the obtained fabric has excellent super-hydrophobic property and flame retardant property. Accordingly, the simple one pot method is adopted, the technology is simple, the condition is mild, the source of raw materials are wide, the price is low, and large-scale industrial production is facilitated.
Owner:SOUTH CHINA UNIV OF TECH

Super-hydrophobic oleophilic sponge material and preparing method and oil-water separation application thereof

The invention discloses a super-hydrophobic oleophilic sponge material and a preparing method and oil-water separation application thereof, and belongs to the preparation of high-performance oil-waterseparation composites. The preparing method includes the steps of cleaning a sponge to remove impurities, putting the sponge in roughening liquid for surface roughening treatment, and adding a fattyacid solution for hydrophobic modification treatment to obtain the super-hydrophobic oleophilic sponge material. The super-hydrophobic oleophilic sponge material is a sponge material obtained after anon-polarity long-chain alkane group conducts hydrophobic modification on the surface of a substrate with a polyurethane or melamine sponge as the substrate. The preparing process is simple, the priceis low, and the oil absorption performance is excellent and stable. The material can be widely applied for leaking oil recovery, oil-containing wastewater treatment and oil-water mixture separation;the super-hydrophobic oleophilic sponge material solves the problem that an oil-water separation porous material is low in mechanical strength, low in separation efficiency, poor in repeatability andthe like in the current stage.
Owner:SHENYANG JIANZHU UNIVERSITY

Preparation method of modified polyvinylidene fluoride-polyvinyl alcohol binary composite ultrafiltration membrane

The invention relates to a preparation method of a modified polyvinylidene fluoride-polyvinyl alcohol binary composite ultrafiltration membrane. The preparation method comprises the following steps of preparing membrane casting solution, wherein the membrane casting solution is prepared by polyvinylidene fluoride powder, polyvinyl alcohol powder, carboxylation multiwalled carbon nanotubes and dimethyl sulfoxide solvent; fully dispersing the carboxylation multiwalled carbon nanotube in the dimethyl sulfoxide solvent, then sequentially adding binary membrane materials prepared by the polyvinylidene fluoride powder and the polyvinyl alcohol powder, controlling the temperature to be 95 to 105 DEG C, mechanically stirring and dissolving, and obtaining uniform membrane casting solution; then after fully defoaming the obtained membrane casting solution at the temperature of 40 to 60 DEG C, scraping the membrane on a glass plate; immersing the glass plate with a membrane casting solution thin layer into coagulation bath with the temperature of 25 to 35 DEG C to split phases to form the membrane, taking out after soaking in deionized water for 5 to 7 days, naturally drying, and storing. According to the binary composite ultrafiltration membrane provided by the invention, the flux recovery rate can achieve 81.2 percent, and the binary composite ultrafiltration membrane has good hydrophilic and antifouling property.
Owner:SHANGHAI APPLIED TECHNOLOGIES COLLEGE

Preparation method of multifunctional super-hydrophobic coating with mechanical stability

The invention discloses a preparation method of a multifunctional super-hydrophobic coating with mechanical stability, and belongs to the field of multifunctional application coatings. The method comprises the following steps: respectively dissolving zinc nitrate and potassium hydroxide in deionized water, slowly dropwise adding the zinc nitrate solution into the potassium hydroxide solution under magnetic stirring, transferring the obtained solution into a high-pressure kettle, reacting for 5 hours under mild conditions, centrifuging and drying to obtain zinc oxide with special morphology, and performing hydrophobic modification on the zinc oxide particles obtained by the method by using tridecafluorooctyltriethoxysilane, adding n-hexane, polydimethylsiloxane and absolute ethyl alcohol into a beaker according to a certain proportion, fully stirring, adding modified zinc oxide into the mixed solution, carrying out ultrasonic treatment for half an hour, and finally spraying by using a spray gun to obtain the super-hydrophobic coating. The contact angle of the prepared super-hydrophobic coating reaches 157 degrees, the rolling angle is 4 degrees, and the super-hydrophobic coating has good mechanical stability, photocatalysis and antibacterial ability.
Owner:HEILONGJIANG UNIV

Preparation method of high-temperature-resistant high-humidity-resistant binder for packaging

The invention discloses a preparation method of a high-temperature-resistant high-humidity-resistant binder for packaging, belonging to the technical field of preparation of binders. According to thepreparation method, the soybean oil is oxidized under acidic conditions to obtain epoxidized soybean oil, the silicon hydroxyl of asbestos fiber is exposed by acid etching, the asbestos fiber is grafted by maleic anhydride, and the asbestos fiber is subjected to surface modification through the epoxidized soybean oil, high temperature, high humidity resistance and toughness are improved, and the water droplets formed by liquefaction of the surface of the film in high temperature and high humidity air will be quickly dried. According to the invention, the modified epoxy resin is toughened by polybutadiene rubber powder, the toughened modified epoxy resin is composed of epoxy resin and rubber particles, the rubber particles are of a core-shell structure, and the rubber particles of the core-shell structure are evenly distributed. The improvement effect on the toughness and strength is remarkable, the activation energy per unit volume of the epoxy glue is reduced, and the maleic anhydridecan be cured and crosslinked with the epoxy resin at a low temperature, so that the binder can be cured at a lower temperature. Therefore, the preparation method has a broad prospect.
Owner:FOSHAN GAOMING DISTRICT ZHUAHE NEW MATERIAL TECH CO LTD

Solar photovoltaic panel with self-cleaning function

The invention discloses a solar photovoltaic panel with a self-cleaning function. The surface of the photovoltaic panel is coated with a layer of a self-cleaning coating, and through the performance of the self-cleaning coating, the self-cleaning effect of the solar photovoltaic panel is achieved. The self-cleaning coating is prepared through the specific steps of adding a certain amount of butyltitanate into an ethyl alcohol solution, then adding hydrochloric acid into the ethyl alcohol solution to adjust the PH to be 3, adding distilled water into the mixture after a stirring reaction is conducted for 8-10 minutes, and then conducting stirring and mixing for 2-3 minutes to obtain a colloidal solution; adding a fluorosiloxane resin gel solution and a film-forming auxiliary agent into thecolloidal solution, and conducting stirring and mixing for 3-5 minutes to obtain the coating. According to the solar photovoltaic panel, the surface of the photovoltaic panel is coated with the self-cleaning coating, the self-cleaning coating is prepared by compounding resin containing a large quantity of siloxane bonds and fluorine element and titania gel, has high hydrophobicity and fouling resistance, and can achieve the self-cleaning effect.
Owner:安徽三优光电科技有限公司

Preparation method for anticorrosive antibacterial wood fiber composite

PendingCN109731747AImprove flame retardant and smoke suppressionImprove hydrophobic propertiesSpecial surfacesCoatingsTitanium dioxideOxide
The invention discloses a preparation method for an anticorrosive antibacterial wood fiber composite. The preparation method for the anticorrosive antibacterial wood fiber composite comprises the steps that a layer of nanometer oxide suspension liquid is sprayed onto the surface of the wood fiber composite and dried; then a layer of poly-dimethyl siloxane treatment fluid is sprayed onto the surface of the wood fiber composite and dried; and finally, a layer of nanometer oxide suspension liquid is sprayed onto the surface of the wood fiber composite again and dried, and the anticorrosive antibacterial wood fiber composite is prepared. The nanometer oxide suspension liquid is one or several of nanometer aluminum oxide suspension liquid, nanometer titanium dioxide suspension liquid and nanometer zinc oxide suspension liquid. According to the preparation method for the anticorrosive antibacterial wood fiber composite, the surface of the wood fiber composite is subjected to spraying treatment; the inflaming-retarding, smoke-suppressive, anticorrosive and antibacterial properties of the composite are improved, and meanwhile, the hydrophobic property of the surface of the composite is strengthened significantly; and moisture is prevented from entering the interior of the composite and destroying the living environment of microorganism, and the service life and the anticorrosive antibacterial durability of wood are improved significantly.
Owner:贵州省林业科学研究院 +1

Polypeptide fishy-smell-removing method

The invention discloses a polypeptide fishy-smell-removing method. The polypeptide fishy-smell-removing method comprises the steps of dialysis, ultra-filtration fishy smell removing, shielding fishy smell removing and alcohol-soluble fishy smell removing. Firstly, a chlamys farreri enzymatic hydrolysate is dialysed to remove ash content; then the enzymatic hydrolysate is subjected to ultra-filtration fishy smell removing through a polysulfone hollow fiber ultra-filtration membrane; then ethyl maltol, beta-cyclodextrin and pantolactone are added into a peptide solution subjected to ultra-filtration for shielding fishy smell removing; and finally, an ethanol solution is added for centrifuging to take sediment, and then polypeptides from chlamys farreri are obtained. The polypeptide fishy-smell-removing method has the beneficial effects that the polypeptide fishy-smell-removing method is easy to operate, fishy smell substances of amine, aldehyde, ketone and the like in a polypeptide solution are removed thoroughly, adsorption and wrapping of the beta-cyclodextrin for the aldehyde, ketone and amine type substances can be greatly improved through the pantolactone, 3-hydroxy-5-methyl-2,4-imidazolone in alcohol-soluble fishy smell removing facilitates acceleration separating of the aldehyde and amine type substances, and meanwhile degradation of the polypeptides and proteins can be lowered.
Owner:金华市铁骑士生物科技有限公司
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